NHC-coordinated silagermenylidene functionalized in allylic position and its behaviour as a ligand

Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si-Pb): From Elusive Species to Isolable Building Blocks

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

(2013) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dative Bonds in Main-Group Compounds: A Case for Fewer Arrows!

(2013) Daniel Himmel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structural Characterization of Base-Stabilized Oligomeric Heterovinylidenes

(2013) Wing-Por Leung et al.   INORGANIC CHEMISTRY

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene

(2013) Michael J. Cowley et al.   Nature Chemistry

Direct Synthesis of Iron(0) N-Heterocyclic Carbene Complexes by Using Fe3(CO)12 and Their Application in Reduction of Carbonyl Groups

(2013) Svenja Warratz et al.   ORGANOMETALLICS

Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block

(2012) Rajendra S. Ghadwal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(GeRR′)]+

(2012) Meg E. Fasulo et al.   CHEMICAL COMMUNICATIONS

A stable germanone as the first isolated heavy ketone with a terminal oxygen atom

(2012) Liangchun Li et al.   Nature Chemistry

Stable N-Heterocyclic Carbene Complexes of Hypermetallyl Germanium(II) and Tin(II) Compounds

(2011) Nadia Katir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A blue digermene (t-Bu2MeSi)2GeGe(SiMet-Bu2)2

(2011) Vladimir Ya. Lee et al.   CHEMICAL COMMUNICATIONS

Preparation, Characterization, and Theoretical Analysis of Group 14 Element(I) Dimers: A Case Study of Magnesium(I) Compounds as Reducing Agents in Inorganic Synthesis

(2011) Cameron Jones et al.   INORGANIC CHEMISTRY

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State

(2011) Jiaye Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Based Olefin Metathesis Catalysts Derived from Alkynes

(2010) Ana M. Lozano-Vila et al.   CHEMICAL REVIEWS

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Stable N-Heterocyclic Carbene Adducts of Arylchlorosilylenes and Their Germanium Homologues

(2010) Alexander C. Filippou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of iron carbonyl complexes of germanium(II) and tin(II) each with a terminal fluorine atom

(2010) Anukul Jana et al.   JOURNAL OF FLUORINE CHEMISTRY

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From NHC→germylenes to stable NHC→germanone complexes

(2009) Shenglai Yao et al.   CHEMICAL COMMUNICATIONS

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

A stable silagermene (tBu3Si)2Si=Ge(mes)2(mes = 2,4,6-trimethylphenyl): Synthesis, X-ray crystal structure, and thermal isomerization

(2009) Masayasu Igarashi et al.   HETEROATOM CHEMISTRY

Shuttling Germanium Atoms into Branched Polysilanes

(2009) Harald Wagner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium

(2009) Paul G. Hayes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RGe(I)Ge(I)R Compound (R = PhC(NtBu)2) with a Ge−Ge Single Bond and a Comparison with the Gauche Conformation of Hydrazine†

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE