Dative Bonds in Main-Group Compounds: A Case for Fewer Arrows!

A Carbone-Stabilized Two-Coordinate Phosphorus(III)-Centered Dication

(2013) Madelyn Qin Yi Tay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen as Double Lewis Acid: Structure and Bonding of Triphenylphosphinazine N2(PPh3)2

(2013) Nicole Holzmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structure of Carbene-Stabilized N-Centered Cations [L2N]+, [L2NR]2+, [LNR3]2+, and [L3N]3+

(2013) Ágnes Kozma et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination Chemistry at Carbon: The Patchwork Family Comprising (Ph3P)2C, (Ph3P)C(C2H4), and (C2H4)2C

(2012) Hubert Schmidbaur et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Stabilized [P4]2+Cations

(2012) Maximilian Donath et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Seven Sins in Academic Behavior in the Natural Sciences

(2012) Wilfred F. van Gunsteren   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Facile Reduction of Carbon Dioxide to Carbon Monoxide with an Amido-Digermyne

(2012) Jiaye Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis base mediated dismutation of trichlorosilane

(2012) Amit Pratap Singh et al.   CHEMICAL COMMUNICATIONS

Synthesis, structure and reactivity of cyclopropenyl-1-ylidene stabilized S(ii), Se(ii) and Te(ii) mono- and dications

(2012) Ágnes Kozma et al.   CHEMICAL COMMUNICATIONS

Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2

(2012) Mehmet Ali Celik et al.   CHEMISTRY-A EUROPEAN JOURNAL

Homoleptic Pnictogen–Chalcogen Coordination Complexes

(2012) Jonathan W. Dube et al.   INORGANIC CHEMISTRY

A Germanium Isocyanide Complex Featuring (n → π*) Back-Bonding and Its Conversion to a Hydride/Cyanide Product via C–H Bond Activation under Mild Conditions

(2012) Zachary D. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Reactivity of a Stable Zwitterionic N-Heterocyclic Silylene and Its Carbene Complex Probed with Muonium

(2012) Paul W. Percival et al.   ORGANOMETALLICS

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

A Boron-Boron Triple Bond

(2012) G. Frenking et al.   SCIENCE

Chemistry: A Panoply of Arrows

(2011) Santiago Alvarez   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature

(2011) S. M. Ibrahim Al-Rafia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structures and Stabilities of Group 13 Adducts [(NHC)(EX3)] and [(NHC)2(E2Xn)] (E=B to In; X=H, Cl; n=4, 2, 0; NHC=N-Heterocyclic Carbene) and the Search for Hydrogen Storage Systems: A Theoretical Study

(2011) Nicole Holzmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Multiple Boron−Boron Bonds in Neutral Molecules: An Insight from the Extended Transition State Method and the Natural Orbitals for Chemical Valence Scheme

(2011) Mariusz P. Mitoraj et al.   INORGANIC CHEMISTRY

Silicon Analogues of Carboxylic Acids: Synthesis of Isolable Silanoic Acids by Donor-Acceptor Stabilization

(2010) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a Stable Disilyne Bisphosphine Adduct and Its Non-Metal-Mediated CO2 Reduction to CO

(2010) David Gau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

AnN-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2

(2010) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy

(2009) Mariham Y. Abraham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Carbon(0) Chemistry, Part 1: Parent Compounds

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene-Stabilized Diphosphorus

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CHEMISTRY: Soluble Allotropes of Main-Group Elements

(2008) C. A. Dyker et al.   SCIENCE

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE

Structural Alternatives for the Formation of Halogenophosphine-Phosphenium Complexes

(2007) Sebastian Burck et al.   INORGANIC CHEMISTRY