A Free-Radical-Promoted Stereospecific Decarboxylative Silylation of α,β-Unsaturated Acids with Silanes

Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes

(2015) Ivan Buslov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Decarboxylative Cross-Coupling of Aryl Chlorides and Benzoates without ActivatingorthoSubstituents

(2015) Jie Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room-Temperature Decarboxylative Alkynylation of Carboxylic Acids Using Photoredox Catalysis and EBX Reagents

(2015) Franck Le Vaillant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Targeted Fluorination with the Fluoride Ion by Manganese-Catalyzed Decarboxylation

(2015) Xiongyi Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative Alkynylation and Carbonylative Alkynylation of Carboxylic Acids Enabled by Visible-Light Photoredox Catalysis

(2015) Quan-Quan Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation

(2015) Chao Shen et al.   CHEMICAL SOCIETY REVIEWS

User-Friendly Platinum Catalysts for the Highly Stereoselective Hydrosilylation of Alkynes and Alkenes

(2015) Steve Dierick et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Facilitated Oxidative Radical Decarboxylative Cross-Coupling between α-Oxocarboxylic Acids and Acrylic Acids: An Approach to α,β-Unsaturated Carbonyls

(2015) Qing Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition Metal-Free Oxidative Radical Decarboxylation/Cyclization for the Construction of 6-Alkyl/Aryl Phenanthridines

(2015) Shichao Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis

(2015) Gerald Pratsch et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphoric Acid-Mediated Synthesis of Vinyl Sulfones through Decarboxylative Coupling Reactions of Sodium Sulfinates with Phenylpropiolic Acids

(2015) Guangwei Rong et al.   JOURNAL OF ORGANIC CHEMISTRY

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

(2015) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Radical Azidation of Aliphatic Carboxylic Acids in Aqueous Solution

(2015) Chao Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Decarboxylative functionalization of cinnamic acids

(2015) Arun Jyoti Borah et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Decarboxylative Alkylcarboxylation of α,β-Unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling

(2015) Bao Gao et al.   ORGANIC LETTERS

Silver-Catalyzed Decarboxylative Azidation of Aliphatic Carboxylic Acids

(2015) Yuchao Zhu et al.   ORGANIC LETTERS

Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis

(2015) Guang-Zu Wang et al.   ORGANIC LETTERS

Transition-Metal-Free Synthesis of Phenanthridinones from Biaryl-2-oxamic Acid under Radical Conditions

(2015) Ming Yuan et al.   ORGANIC LETTERS

Decarboxylative Alkynylation of α-Keto Acids and Oxamic Acids in Aqueous Media

(2015) Hua Wang et al.   ORGANIC LETTERS

A Free Radical Cascade Silylarylation of Activated Alkenes: Highly Selective Activation of the Si–H/C–H Bonds

(2015) Lizhi Zhang et al.   ORGANIC LETTERS

An I2O5-promoted decarboxylative trifluoromethylation of cinnamic acids

(2015) Xiao-Jie Shang et al.   TETRAHEDRON LETTERS

Hypervalent Iodine Reagents Enable Chemoselective Deboronative/Decarboxylative Alkenylation by Photoredox Catalysis

(2014) Hanchu Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Arylation of (Hetero)arenes by Oxidative Decarboxylation of Aromatic Carboxylic Acids

(2014) Jian Kan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TBHP-promoted sequential radical silylation and aromatisation of aryl isonitriles with silanes

(2014) Lei Wang et al.   CHEMICAL COMMUNICATIONS

Rational Design of a Second Generation Catalyst for Preparation of Allylsilanes Using the Silyl-Heck Reaction

(2014) Jesse R. McAtee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin

(2014) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Cu/Pd-Catalyzed Decarboxylative Cross-Couplings: A DFT Investigation

(2014) Andreas Fromm et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes

(2014) Zhenbo Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The electron is a catalyst

(2014) Armido Studer et al.   Nature Chemistry

Sterically Directed Iridium-Catalyzed Hydrosilylation of Alkenes in the Presence of Alkynes

(2014) Jill A. Muchnij et al.   ORGANIC LETTERS

9-Silafluorenes via Base-Promoted Homolytic Aromatic Substitution (BHAS) – The Electron as a Catalyst

(2014) Dirk Leifert et al.   ORGANIC LETTERS

Rapid Synthesis of Crowded Aromatic Architectures from Silyl Acetylenes

(2014) Samuel J. Hein et al.   ORGANIC LETTERS

Transition-Metal-Free Hunsdiecker Reaction of Electron-Rich Arenecarboxylic Acids and Aryl Aldehydes in Water

(2014) Zhong-Quan Liu et al.   SYNLETT

Preparation of Vinyl Silyl Ethers and Disiloxanes via the Silyl-Heck Reaction of Silyl Ditriflates

(2013) Sara E. S. Martin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation

(2013) Dongjie Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper- and Iron-Catalyzed Decarboxylative Tri- and Difluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na and (CF2HSO2)2Zn via a Radical Process

(2013) Zejiang Li et al.   ORGANIC LETTERS

Free-Radical Cascade Alkylarylation of Alkenes with Simple Alkanes: Highly Efficient Access to Oxindoles via Selective (sp3)C–H and (sp2)C–H Bond Functionalization

(2013) Zejiang Li et al.   ORGANIC LETTERS

Lewis-base silane activation: from reductive cleavage of aryl ethers to selective ortho-silylation

(2013) Alexey Fedorov et al.   Chemical Science

Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction

(2012) Jesse R. McAtee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Pd-Catalyzed Decarboxylative Cross-Coupling Reaction between Aryl Carboxylic Acids: Synthesis of Biaryl Compounds

(2012) Peng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Decarboxylative Alkynylation of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Xuesong Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Chlorination of Aliphatic Carboxylic Acids

(2012) Zhentao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative C–H Arylation of Benzoic Acids under Radical Conditions

(2012) Sangwon Seo et al.   ORGANIC LETTERS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Copper-catalyzed decarboxylative alkenylation of sp3 C–H bonds with cinnamic acids via a radical process

(2012) Zili Cui et al.   Chemical Science

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Carboxylic Acids as Traceless Directing Groups for Formal meta-Selective Direct Arylation

(2011) Josep Cornella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α-Aryl Nitriles through Palladium-Catalyzed Decarboxylative Coupling of Cyanoacetate Salts with Aryl Halides and Triflates

(2011) Rui Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

(2011) Nuria Rodríguez et al.   CHEMICAL SOCIETY REVIEWS

Transition metal-catalyzed decarboxylative cross-coupling reactions

(2011) Rui Shang et al.   Science China-Chemistry

Decarboxylative CH Cross-Coupling of Azoles

(2010) Fengzhi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Indole, Pyrrole, and Furan Arylation by Aryl Chlorides

(2010) Enrico T. Nadres et al.   JOURNAL OF ORGANIC CHEMISTRY

Decarboxylative Benzylations of Alkynes and Ketones

(2010) Robert R. P. Torregrosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature Palladium-Catalyzed Decarboxylativeortho-Acylation of Acetanilides with α-Oxocarboxylic Acids

(2010) Ping Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereocontrolled Synthesis and Photoisomerization Behavior of All-Cis and All-Trans Poly(m-phenylenevinylene)s

(2010) Masayuki Wakioka et al.   MACROMOLECULES

A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres

(2010) Jan Streuff et al.   Nature Chemistry

Copper-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Aryl Iodides and Bromides

(2009) Rui Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative Cross-Coupling of Aryl Tosylates with Aromatic Carboxylate Salts

(2009) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Alkenylation of Glyoxylate with Vinylsilane Catalyzed by Chiral Dicationic Palladium(II) Complexes

(2009) Kohsuke Aikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Analysis of Factors Controlling Pd-Catalyzed Decarboxylative Coupling of Carboxylic Acids with Olefins

(2009) Song-Lin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Decarboxylative Direct C-3 Arylation of Indoles with Benzoic Acids

(2009) Josep Cornella et al.   ORGANIC LETTERS

Synthesis of α,ω-Diarylbutadienes and -Hexatrienes via Decarboxylative Coupling of Cinnamic Acids with Vinyl Bromides under Palladium Catalysis

(2009) Mana Yamashita et al.   ORGANIC LETTERS

Carboxylic Acids as Substrates in Homogeneous Catalysis

(2008) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(Me3Si)3SiH: Twenty Years After Its Discovery as a Radical-Based Reducing Agent

(2007) Chryssostomos Chatgilialoglu   CHEMISTRY-A EUROPEAN JOURNAL