Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation

Iodine-Catalyzed Regioselective Sulfenylation of Indoles with Sodium Sulfinates

(2014) Fuhong Xiao et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold-Catalyzed Intermolecular CS Bond Formation: Efficient Synthesis of α-Substituted Vinyl Sulfones

(2014) Yumeng Xi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Thiolation of Aryl CH Bonds with Disulfides

(2014) Masayuki Iwasaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Double C–S Bonds Formation via Different Paths: Synthesis of Benzothiazoles from N-Benzyl-2-iodoaniline and Potassium Sulfide

(2014) Xiaoyun Zhang et al.   ORGANIC LETTERS

Palladium-Catalyzed Trifluoromethylthiolation of Aryl C–H Bonds

(2014) Chunfa Xu et al.   ORGANIC LETTERS

Copper Oxide Nanoparticle-Catalyzed Chalcogenation of the Carbon-Hydrogen Bond in Thiazoles: Synthesis of 2-(Organochalcogen)thiazoles

(2013) Alisson R. Rosario et al.   ADVANCED SYNTHESIS & CATALYSIS

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones

(2013) Qingquan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-Catalyzed Directed Sulfenylation of Arene CH Bonds

(2013) Yaxi Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

K2CO3 promoted direct sulfenylation of indoles: a facile approach towards 3-sulfenylindoles

(2013) Peng Sang et al.   GREEN CHEMISTRY

Iodine-catalyzed efficient 2-arylsulfanylphenol formation from thiols and cyclohexanones

(2013) Yunfeng Liao et al.   GREEN CHEMISTRY

Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Chalcogenides from Arenes and Diaryl Dichalcogenides

(2013) Ch Durga Prasad et al.   JOURNAL OF ORGANIC CHEMISTRY

Dioxygen-Triggered Oxidative Radical Reaction: Direct Aerobic Difunctionalization of Terminal Alkynes toward β-Keto Sulfones

(2013) Qingquan Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfonylation of Quinoline N-Oxides with Aryl Sulfonyl Chlorides via Copper-Catalyzed C–H Bonds Activation

(2013) Zhiyong Wu et al.   ORGANIC LETTERS

Metal-Free Oxidative C(sp3)–H Bond Thiolation of Ethers with Disulfides

(2013) Sheng-rong Guo et al.   ORGANIC LETTERS

Tetrahydrobiopterin Biosynthesis as an Off-Target of Sulfa Drugs

(2013) H. Haruki et al.   SCIENCE

A ligand free copper(II) catalyst is as effective as a ligand assisted Pd(II) catalyst towards intramolecular C–S bond formation via C–H functionalization

(2013) Arghya Banerjee et al.   TETRAHEDRON

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Pd-Catalyzed Decarboxylative Cross-Coupling Reaction between Aryl Carboxylic Acids: Synthesis of Biaryl Compounds

(2012) Peng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regioselective synthesis of aryl chalcogenides through C–H functionalization of arenes

(2012) Jun-Hao Cheng et al.   CHEMICAL COMMUNICATIONS

I2 promoted domino oxidative cyclization for one-pot synthesis of 2-acylbenzothiazoles via metal-free sp3 C–H functionalization

(2012) Yan-Ping Zhu et al.   CHEMICAL COMMUNICATIONS

Transition metal-free direct C–H bond thiolation of 1,3,4-oxadiazoles and related heteroarenes

(2012) Liang-Hua Zou et al.   CHEMICAL COMMUNICATIONS

Visible light-induced 3-sulfenylation of N-methylindoles with arylsulfonyl chlorides

(2012) Min Chen et al.   CHEMICAL COMMUNICATIONS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Cu-Catalyzed Three-Component Synthesis of Substituted Benzothiazoles in Water

(2012) Hang Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Direct Thiolation of Pentafluorobenzene with Diaryl Disulfides or Aryl Thiols by C-H and C-F Bond Activation

(2012) Chuanming Yu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iodine-catalyzed oxidative system for 3-sulfenylation of indoles with disulfides using DMSO as oxidant under ambient conditions in dimethyl carbonate

(2012) Wenlei Ge et al.   GREEN CHEMISTRY

Lewis Acid-Catalyzed, Copper(II)-Mediated Synthesis of Heteroaryl Thioethers under Base-Free Conditions

(2012) Chao Dai et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Substitution of Primary Allylic Amines with Sulfinate Salts

(2012) Xue-Song Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Promoted Sulfenylation of sp2 C–H Bonds

(2012) Ly Dieu Tran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Diels–Alder Reaction of α-(Acylthio)acroleins: A New Entry to Sulfur-Containing Chiral Quaternary Carbons

(2012) Akira Sakakura et al.   ORGANIC LETTERS

Catalytic C–H and C–S Bond Activation of Thiophenes

(2012) Jing Li et al.   ORGANIC LETTERS

Transition-Metal-Free Electrophilic Amination of Arylboroxines

(2012) Qing Xiao et al.   ORGANIC LETTERS

Efficient 2-Aryl Benzothiazole Formation from Aryl Ketones and 2-Aminobenzenethiols under Metal-Free Conditions

(2012) Yunfeng Liao et al.   ORGANIC LETTERS

A Multipathway Coupled Domino Strategy: Metal-free Oxidative Cyclization for One-Pot Synthesis of 2-Acylbenzothiazoles from Multiform Substrates

(2012) Yan-ping Zhu et al.   ORGANIC LETTERS

Carbon Dioxide Mediated Stereoselective Copper-Catalyzed Reductive Coupling of Alkynes and Thiols

(2012) Siti Nurhanna Riduan et al.   ORGANIC LETTERS

Gold-Catalyzed Direct Arylation

(2012) L. T. Ball et al.   SCIENCE

Palladium-Catalyzed C-H Cyclization in Water: A Milder Route to 2-Arylbenzothiazoles

(2012) Kiyofumi Inamoto et al.   SYNLETT

Copper-catalyzed sulfenylation of pyrroles with disulfides or thiols: directly synthesis of sulfenyl pyrroles

(2012) Diego Alves et al.   TETRAHEDRON LETTERS

Chiral ionic Brønsted acid–achiral Brønsted base synergistic catalysis for asymmetric sulfa-Michael addition to nitroolefins

(2012) Daisuke Uraguchi et al.   Chemical Science

A concise, efficient synthesis of sugar-based benzothiazoles through chemoselective intramolecular C–S coupling

(2012) Chao Shen et al.   Chemical Science

Regioselective Intramolecular Arylthiolations by Ligand Free Cu and Pd Catalyzed Reaction

(2012) Santosh K. Sahoo et al.   ACS Catalysis

Synthesis, Properties, and Applications of Oligonucleotides Containing an RNA Dinucleotide Phosphorothiolate Linkage

(2011) Nan-Sheng Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalysis and CH Activation Meet Radical- and Electron-Transfer Reactions

(2011) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Double CH Activation Directed by Sulfoxides in the Synthesis of Dibenzothiophenes

(2011) Rajarshi Samanta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

TBHP-mediated oxidative thiolation of an sp3 C–H bond adjacent to a nitrogen atom in an amide

(2011) Ri-Yuan Tang et al.   CHEMICAL COMMUNICATIONS

Synthesis of di(hetero)aryl sulfides by directly using arylsulfonyl chlorides as a sulfur source

(2011) Qian Wu et al.   CHEMICAL COMMUNICATIONS

Fe-catalysed oxidative C–H functionalization/C–S bond formation

(2011) Haibo Wang et al.   CHEMICAL COMMUNICATIONS

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

(2011) Wei Shi et al.   CHEMICAL SOCIETY REVIEWS

Pd nanoparticles for C–C coupling reactions

(2011) Angelica Balanta et al.   CHEMICAL SOCIETY REVIEWS

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

(2011) Nuria Rodríguez et al.   CHEMICAL SOCIETY REVIEWS

Copper-Mediated C–H Activation/C–S Cross-Coupling of Heterocycles with Thiols

(2011) Sadananda Ranjit et al.   JOURNAL OF ORGANIC CHEMISTRY

Formation of Carbon–Sulfur and Carbon–Selenium Bonds by Palladium-Catalyzed Decarboxylative Cross-Couplings of Hindered 2,6-Dialkoxybenzoic Acids

(2011) Jean-Michel Becht et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridines

(2011) Ourida Saidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed direct thiolation of azoles with aliphatic thiols

(2011) An-Xi Zhou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Regioselective C–S Bond Cleavage of Thiophenes

(2011) Huanan Huang et al.   ORGANIC LETTERS

Aerobic Visible-Light Photoredox Radical C–H Functionalization: Catalytic Synthesis of 2-Substituted Benzothiazoles

(2011) Yannan Cheng et al.   ORGANIC LETTERS

Rhodium-catalyzed phenylthiolation reaction of heteroaromatic compounds using α-(phenylthio)isobutyrophenone

(2011) Mieko Arisawa et al.   TETRAHEDRON LETTERS

Use of Molecular Oxygen as a Reoxidant in the Synthesis of 2-Substituted Benzothiazoles via Palladium-Catalyzed CH Functionalization/Intramolecular CS Bond Formation

(2010) Kiyofumi Inamoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Beyond the Pummerer Reaction: Recent Developments in Thionium Ion Chemistry

(2010) Laura H. S. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Activation of Disulfides as a Key Step in the Synthesis of Benzothiazole Moieties

(2010) Jakub Hyvl et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C−H Bond with Disulfides

(2010) Shouhui Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-FreeO-,S-, andN-Arylation of Alcohols, Thiols, Amides, Amines, and Related Heterocycles†

(2010) Rafael Cano et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

Cu-Catalyzed Oxidative Amidation of Propiolic Acids Under Air via Decarboxylative Coupling

(2010) Wei Jia et al.   ORGANIC LETTERS

A General and Straightforward Method for the Synthesis of 2-Trifluoromethylbenzothiazoles

(2010) Jiangtao Zhu et al.   ORGANIC LETTERS

Synthesis of Vinyl Sulfides by Copper-Catalyzed Decarboxylative C−S Cross-Coupling

(2010) Sadananda Ranjit et al.   ORGANIC LETTERS

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic insights into a copper–disulfide interaction in oxidation of imines by disulfides

(2009) Jiri Srogl et al.   CHEMICAL COMMUNICATIONS

Synthesis of Aryl Sulfides by Decarboxylative CS Cross-Couplings

(2009) Zhongyu Duan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides

(2009) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanocontact-induced catalytic activation in palladium nanoparticles

(2009) Changlong Jiang et al.   Nanoscale

Rhodium-Catalyzed Methylthio Transfer Reaction between Ketone α-Positions: Reversible Single-Bond Metathesis of C−S and C−H Bonds

(2009) Mieko Arisawa et al.   ORGANIC LETTERS

Heterocycle Formation via Palladium-Catalyzed Intramolecular Oxidative C−H Bond Functionalization: An Efficient Strategy for the Synthesis of 2-Aminobenzothiazoles

(2009) Laurie L. Joyce et al.   ORGANIC LETTERS

Copper-catalyzed direct thiolation of benzoxazole with diaryl disulfides and aryl thiols

(2009) Shin-ichi Fukuzawa et al.   TETRAHEDRON LETTERS

Palladium-catalysed direct synthesis of benzo[b]thiophenes from thioenols

(2008) Kiyofumi Inamoto et al.   CHEMICAL COMMUNICATIONS

Carbon−Nitrogen Bond Formation Involving Well-Defined Aryl−Copper(III) Complexes

(2008) Lauren M. Huffman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

Potassiumt-Butoxide Alone Can Promote the Biaryl Coupling of Electron-Deficient Nitrogen Heterocycles and Haloarenes

(2008) Shuichi Yanagisawa et al.   ORGANIC LETTERS

Palladium-Catalyzed Synthesis of 2-Substituted Benzothiazoles via a C−H Functionalization/Intramolecular C−S Bond Formation Process

(2008) Kiyofumi Inamoto et al.   ORGANIC LETTERS

The Chemical Versatility of Natural-Product Assembly Lines

(2007) Christopher T. Walsh   ACCOUNTS OF CHEMICAL RESEARCH