Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 36, Pages 13330-13333Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja407748z
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Funding
- University of Delaware (UD)
- NSF [CAREER CHE1254360, CHE0421224, CHE1229234, CHE0840401]
- Research Corporation (Cottrell Scholars Program)
- NIH [5T32 GM 08550-16, P20 GM103541, S10 RR02692]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1254360] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1229234] Funding Source: National Science Foundation
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Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.
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