期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 1, 页码 236-239出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509537
关键词
decarboxylation; radical reactions; silanes; silylation; synthetic methods
资金
- National Science Foundation of China [21272096, 21472080]
A stereospecific decarboxylative silylation of acrylic and propiolic acids with silanes was developed. This reaction represents the first example of decarboxylative C-Si bond formation and provides an efficient and convenient approach to various synthetically useful alkenyl and alkynyl organo-silicon compounds through the reaction of alpha,beta-unsaturated acids with silanes. Spin-trapping and EPR experiments support a radical addition/elimination process.
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