Catalytic Asymmetric Synthesis of Phosphine Boronates

Efficient Synthesis of (P-Chirogenic) o-Boronated Phosphines from sec-Phosphine Boranes

(2015) Jérôme Bayardon et al.   ORGANIC LETTERS

Asymmetric boron conjugate addition to α,β-unsaturated carbonyl compounds catalyzed by CuOTf/Josiphos under non-alkaline conditions

(2015) Jian-Bo Xie et al.   Organic Chemistry Frontiers

Lithiation–Borylation Methodology and Its Application in Synthesis

(2014) Daniele Leonori et al.   ACCOUNTS OF CHEMICAL RESEARCH

Frustrated Lewis Pairs: From Concept to Catalysis

(2014) Douglas W. Stephan   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration

(2014) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Boron-Substituted Quaternary Carbon Stereogenic Centers through NHC-Catalyzed Conjugate Additions of (Pinacolato)boron Units to Enones

(2014) Suttipol Radomkit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperation between Transition Metals and Lewis Acids: A Way To Activate H2and HE bonds

(2014) Marc Devillard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Directed CH Borylation Reactions: Facile and Selective Access to Ambiphilic Phosphine Boronate Esters

(2014) Kristina M. Crawford et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

(2014) Daniele Leonori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Phosphinoboration Reaction

(2014) Erika N. Daley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Modification by 1,1-Carboboration: Disclosure of a Phosphine Oxide Triggered Nitrogen Monoxide Addition to an Intramolecular P/B Frustrated Lewis Pair

(2014) René Liedtke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific sp2–sp3 coupling of secondary and tertiary boronic esters

(2014) Amadeu Bonet et al.   Nature Chemistry

Asymmetric catalysis as a method for the synthesis of chiral organophosphorus compounds

(2014) Oleg I. Kolodiazhnyi et al.   TETRAHEDRON-ASYMMETRY

A Highly Active Phosphine–Borane Organocatalyst for the Reduction of CO2 to Methanol Using Hydroboranes

(2013) Marc-André Courtemanche et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organophosphonates revealed: new insights into the microbial metabolism of ancient molecules

(2013) John W. McGrath et al.   NATURE REVIEWS MICROBIOLOGY

Asymmetric β-boration of α,β-unsaturated carbonyl compounds with chiral Rh[bis(oxazolinyl)phenyl] catalysts

(2013) Kenji Toribatake et al.   TETRAHEDRON

Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones

(2012) Alan R. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Copper(II)-Catalyzed Enantioselective Boron Conjugate Additions to α,β-Unsaturated Carbonyl Compounds in Water

(2012) Shū Kobayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel transformation of α,β-unsaturated aldehydes and ketones into γ-amino alcohols or 1,3-oxazines via a 4 or 5 step, one-pot sequence

(2012) Adam D. J. Calow et al.   CHEMICAL COMMUNICATIONS

Phosphine-boronates: efficient bifunctional organocatalysts for Michael addition

(2012) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

One-Pot Three-Component Highly Selective Synthesis of Homoallylboronates by Using Metal-Free Catalysis

(2012) Ismail Ibrahem et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric hydrogenation of imines with a recyclable chiral frustrated Lewis pair catalyst

(2012) Ghazi Ghattas et al.   DALTON TRANSACTIONS

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Chemoselective Metal-Free Reduction of Phosphine Oxides to Phosphines

(2012) Yuehui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic methodologies for the β-boration of conjugated electron deficient alkenes

(2012) Adam D. J. Calow et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric β-Boration of α,β-Unsaturated N-Acyloxazolidinones by [2.2]Paracyclophane-Based Bifunctional Catalyst

(2012) Lei Zhao et al.   ORGANIC LETTERS

Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles

(2012) Eduard Hartmann et al.   ORGANIC LETTERS

Reactions of phosphorus/boron frustrated Lewis pairs with SO2

(2012) Muhammad Sajid et al.   Chemical Science

A Boron-Based Synthesis of the Natural Product (+)-trans-Dihydrolycoricidine

(2011) Sarah L. Poe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis ofsynandanti1,4-Diols by Copper-Catalyzed Boration of Allylic Epoxides

(2011) Mariola Tortosa   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Frustrated Lewis Pairs with Conjugated Ynones-Selective Hydrogenation of the Carbon-Carbon Triple Bond

(2011) Bao-Hua Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric conjugate boration of α,β-unsaturated sulfones

(2011) Abraham L. Moure et al.   CHEMICAL COMMUNICATIONS

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Syntheses of homochiral 1,2-ferrocene-functionalized Lewis acids and acid/base pairs

(2011) Inke Siewert et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

(2011) Tomotsugu Awano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Conjugate Borylation

(2010) Julia A. Schiffner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric β-Boration of α,β-Unsaturated Carbonyl Derivatives

(2010) Luca Mantilli et al.   ChemCatChem

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters

(2010) Jack Chang Hung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)−Secondary Diamine Complex-Catalyzed Enantioselective Conjugate Boration of Linear β,β-Disubstituted Enones

(2010) I-Hon Chen et al.   ORGANIC LETTERS

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

(2009) Takushi Shiomi et al.   CHEMICAL COMMUNICATIONS

Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration

(2009) Daisuke Imao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the β-position

(2009) Vanesa Lillo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes

(2008) Patrick Spies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive Coupling of Carbon Monoxide in a Rhenium Carbonyl Complex with Pendant Lewis Acids

(2008) Alexander J. M. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Asymmetric Stetter Reaction Onto Vinylphosphine Oxides and Vinylphosphonates

(2008) Steven C. Cullen et al.   ORGANIC LETTERS

Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]

(2008) Jérôme Vergnaud et al.   ORGANOMETALLICS

β-Phosphinoethylboranes as Ambiphilic Ligands in Nickel−Methyl Complexes

(2008) Andreas Fischbach et al.   ORGANOMETALLICS

Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

(2008) Vanesa Lillo et al.   ORGANOMETALLICS

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION