Journal
ORGANIC LETTERS
Volume 14, Issue 9, Pages 2406-2409Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol300832f
Keywords
-
Categories
Funding
- Deutsche Forschungsgemeinschaft [Oe 249/3-2]
- Fonds der Chemischen Industrie
Ask authors/readers for more resources
The two-directional desymmetrization of prochiral precursors with alpha,beta-unsaturated branches by catalyst-controlled 1,4-addition of silicon and likewise boron nucleophiles allows for a general enantioselective access to syn,anti-triols with 1,n + 1,2n + 1 (n = 2 and 3) substitution patterns. The utility is demonstrated in the synthesis of the C17-C25 fragment of dermostatin A.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available