Catalytic Enantioselective Intramolecular Aza-Diels-Alder Reactions

Catalytic Asymmetric Synthesis of [2,3]-Fused Indoline Heterocycles through Inverse-Electron-Demand Aza-Diels-Alder Reaction of Indoles with Azoalkenes

(2014) Min-Chao Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Enantioselective Inverse-Electron-Demand Imino Diels-Alder Reaction

(2014) Vincent Eschenbrenner-Lux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Hydrogenation of Unprotected NH Imines Assisted by a Thiourea

(2014) Qingyang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Asymmetric Hetero-Diels-Alder Reaction in the Syntheses of Biologically Relevant Compounds

(2014) Vincent Eschenbrenner-Lux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

One-Pot Organocatalytic Enantioselective Michael/Povarov Domino Strategy for the Construction of Spirooctahydroacridine-3,3′-oxindole Scaffolds

(2014) Hao Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Helical Oligotriazoles: New Class of Anion-Binding Catalysts for the Asymmetric Dearomatization of Electron-Deficient N-Heteroarenes

(2014) Mercedes Zurro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conjugate-Base-Stabilized Brønsted Acids: Catalytic Enantioselective Pictet–Spengler Reactions with Unmodified Tryptamine

(2014) Nisha Mittal et al.   ORGANIC LETTERS

The Anion-Binding Approach to Catalytic Enantioselective Acyl Transfer

(2014) Daniel Seidel   SYNLETT

Intramolecular Diels–Alder reaction as a key step in tandem or sequential processes: a versatile tool for the synthesis of fused and bridged bicyclic or polycyclic compounds

(2014) Prakash T. Parvatkar et al.   TETRAHEDRON

Complex Bioactive Alkaloid-Type Polycycles through Efficient Catalytic Asymmetric Multicomponent Aza-Diels-Alder Reaction of Indoles with Oxetane as Directing Group

(2013) Zhilong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Aza-Diels-Alder Reaction of 1-Azadienes with Enecarbamates Catalyzed by Chiral Phosphoric Acids

(2013) Long He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugate-Base-Stabilized Brønsted Acids as Asymmetric Catalysts: Enantioselective Povarov Reactions with Secondary Aromatic Amines

(2013) Chang Min et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis in Glycosidation Reactions withO-Glycosyl Trichloroacetimidates as Glycosyl Donors

(2013) Yiqun Geng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thiophosphoramide-Based Cooperative Catalysts for Brønsted Acid Promoted Ionic Diels-Alder Reactions

(2013) Alina Borovika et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine-Promoted Asymmetric (4+2) Annulations for the Enantioselective Synthesis of Tetrahydropyridines: A Traceless and Recoverable Auxiliary Strategy

(2013) Pengfei Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Silanediols in Anion-Binding Catalysis

(2013) Andrew G. Schafer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trienamines Derived from Interrupted Cyclic 2,5-Dienones: Remote δ,ε-CC Bond Activation for Asymmetric Inverse-Electron-Demand Aza-Diels-Alder Reaction

(2013) Xin Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Developments in Catalytic Asymmetric Inverse-Electron-Demand Diels–Alder Reaction

(2013) Xianxing Jiang et al.   CHEMICAL REVIEWS

A Highly Diastereo- and Enantioselective Synthesis of Tetrahydroquinolines: Quaternary Stereogenic Center Inversion and Functionalization

(2013) Chaosheng Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Formal Aza-Diels–Alder Reactions of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas

(2013) Mathieu P. Lalonde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

In Situ Assembled Boronate Ester Assisted Chiral Carboxylic Acid Catalyzed Asymmetric Trans-Aziridinations

(2013) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Aza-Diels–Alder Reactions: The Povarov Cycloaddition Reaction

(2013) Mariafrancesca Fochi et al.   SYNTHESIS-STUTTGART

Hydrogen-Bond-Mediated Supramolecular Iminium Ion Catalysis

(2012) Yao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Assistance in Bifunctional Organocatalysis: Enantioselective Mannich Reactions with Aliphatic and Aromatic Imines

(2012) Nicolas Probst et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Catalytic Asymmetric Ugi-type Reaction With Acyclic Azomethine Imines

(2012) Takuya Hashimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

H-Donor Anion Acceptor Organocatalysis-The Ionic Electrophile Activation Approach

(2012) Stephan Beckendorf et al.   ChemCatChem

A dual-catalysis approach to the kinetic resolution of 1,2-diaryl-1,2-diaminoethanes

(2012) Chang Min et al.   CHEMICAL COMMUNICATIONS

Catalytic highly enantioselective vinylogous Povarov reaction

(2012) Lorenzo Caruana et al.   CHEMICAL COMMUNICATIONS

Internal Lewis acid assisted ureas: tunable hydrogen bond donor catalysts

(2012) David M. Nickerson et al.   CHEMICAL COMMUNICATIONS

Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles

(2012) Géraldine Masson et al.   CHEMICAL SOCIETY REVIEWS

Active Conformation in Amine-Thiourea Bifunctional Organocatalysis Preformed by Catalyst Aggregation

(2012) Gábor Tárkányi et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Asymmetric Synthesis of 1,2,4-Trioxane Anticancer Agents via Desymmetrization of Peroxyquinols through a Brønsted Acid Catalysis Cascade

(2012) David M. Rubush et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Thiourea-catalysed ring opening of episulfonium ions with indole derivatives by means of stabilizing non-covalent interactions

(2012) Song Lin et al.   Nature Chemistry

Kinetic Resolution of Amines via Dual Catalysis: Remarkable Dependence of Selectivity on the Achiral Cocatalyst

(2012) Nisha Mittal et al.   ORGANIC LETTERS

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Modulating the Acidity: Highly Acidic Brønsted Acids in Asymmetric Catalysis

(2011) Magnus Rueping et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Asymmetric Organocatalytic One-Pot Strategy to Octahydroacridines

(2011) Gustav Dickmeiss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multiple Catalysis with Two Chiral Units: An Additional Dimension for Asymmetric Synthesis

(2011) Susy Piovesana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Super Brønsted acid catalysis

(2011) Cheol Hong Cheon et al.   CHEMICAL COMMUNICATIONS

Recent advances in cooperative ion pairing in asymmetric organocatalysis

(2011) Jean-François Brière et al.   CHEMICAL SOCIETY REVIEWS

Enhanced Efficiency of Thiourea Catalysts by External Brønsted Acids in the Friedel-Crafts Alkylation of Indoles

(2011) Eugenia Marqués-López et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cooperative Thiourea–Brønsted Acid Organocatalysis: Enantioselective Cyanosilylation of Aldehydes with TMSCN

(2011) Zhiguo Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

A Dual-Catalysis Approach to the Asymmetric Steglich Rearrangement and Catalytic Enantioselective Addition ofO-Acylated Azlactones to Isoquinolines

(2011) Chandra Kanta De et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Desymmetrization ofmeso-Diamines: A Dual Small-Molecule Catalysis Approach

(2011) Chandra Kanta De et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalysis in Enantioselective Oxidopyrylium-Based [5 + 2] Cycloadditions

(2011) Noah Z. Burns et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acid-Catalyzed Enantioselective Three-Component Povarov Reaction Using Enecarbamates as Dienophiles: Highly Diastereo- and Enantioselective Synthesis of Substituted 4-Aminotetrahydroquinolines

(2011) Guillaume Dagousset et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis

(2011) James A. Birrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation and exploitation of acyclic azomethine imines in chiral Brønsted acid catalysis

(2011) Takuya Hashimoto et al.   Nature Chemistry

Intramolecular Povarov reactions involving 3-aminocoumarins

(2011) Amit A. Kudale et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Dual-Catalysis/Anion-Binding Approach to the Kinetic Resolution of Allylic Amines

(2011) Eric G. Klauber et al.   ORGANIC LETTERS

Tertiary Aminourea-Catalyzed Enantioselective Iodolactonization

(2010) Gemma E. Veitch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Three-Component Inverse Electron-Demand Aza-Diels-Alder Reaction: Efficient Synthesis of Ring-Fused Tetrahydroquinolines

(2010) Mingsheng Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of new cis-fused tetrahydrochromeno[4,3-b]quinolines and their antiproliferative activity studies against MDA-MB-231 and MCF-7 breast cancer cell lines

(2010) K. Nagaiah et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Catalytic α-Alkylation of Aldehydes via an SN1 Pathway

(2010) Adam R. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Vinylogous Aldol Reaction of Silyloxy Furans with a Chiral Organic Salt

(2010) Ravi P. Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Nucleophilic and Hydrogen Bonding Catalysis: An Anion Binding Approach to the Kinetic Resolution of Propargylic Amines

(2010) Eric G. Klauber et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Ruthenium Lewis Acid Catalyzed Intramolecular Diels−Alder Reactions

(2010) Sirinporn Thamapipol et al.   ORGANIC LETTERS

Asymmetric Cooperative Catalysis of Strong Bronsted Acid-Promoted Reactions Using Chiral Ureas

(2010) H. Xu et al.   SCIENCE

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Enantioselective aza-Friedel–Crafts reaction catalyzed by a water inclusion complex of O,O′-diacyl tartaric acid

(2010) Hitoshi Ube et al.   TETRAHEDRON-ASYMMETRY

Palladium-Catalyzed Intramolecular Carboesterification of Olefins

(2009) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Plagiarizing Proteins: Enhancing Efficiency in Asymmetric Hydrogen-Bonding Catalysis through Positive Cooperativity

(2009) Christopher R. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral anion-mediated asymmetric ion pairing chemistry

(2009) Jérôme Lacour et al.   CHEMICAL COMMUNICATIONS

Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis

(2009) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Recent applications of intramolecular Diels–Alder reactions to natural product synthesis

(2009) Martin Juhl et al.   CHEMICAL SOCIETY REVIEWS

(Thio)urea organocatalysis—What can be learnt from anion recognition?

(2009) Zhiguo Zhang et al.   CHEMICAL SOCIETY REVIEWS

Mechanism of Amido-Thiourea Catalyzed Enantioselective Imine Hydrocyanation: Transition State Stabilization via Multiple Non-Covalent Interactions

(2009) Stephan J. Zuend et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction

(2009) Hua Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Nucleophilic and Hydrogen Bonding Catalysis: An Anion Binding Approach to the Kinetic Resolution of Amines

(2009) Chandra Kanta De et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Weak Brønsted Acid−Thiourea Co-catalysis: Enantioselective, Catalytic Protio-Pictet−Spengler Reactions

(2009) Rebekka S. Klausen et al.   ORGANIC LETTERS

Enantioselective Thiourea-Catalyzed Additions to Oxocarbenium Ions

(2008) Sarah E. Reisman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Additions of Indoles to Nitroalkenes

(2008) Madhu Ganesh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Imino Aza-enamine Reaction Catalyzed by Axially Chiral Dicarboxylic Acid: Use of ArylaldehydeN,N-Dialkylhydrazones as Acyl Anion Equivalent

(2008) Takuya Hashimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient, One-Pot Synthesis of Isomeric Ellipticine Derivatives through Intramolecular Imino-Diels−Alder Reaction

(2008) Vikram Gaddam et al.   ORGANIC LETTERS

Cooperative Brønsted Acid-Type Organocatalysis:  Alcoholysis of Styrene Oxides

(2008) Torsten Weil et al.   ORGANIC LETTERS

Synthesis of substituted 1,2,3,4-tetrahydroquinones by the Povarov reaction. New potentials of the classical reaction

(2008) V A Glushkov et al.   RUSSIAN CHEMICAL REVIEWS

Recent synthetic developments in a powerful imino Diels–Alder reaction (Povarov reaction): application to the synthesis of N-polyheterocycles and related alkaloids

(2008) Vladimir V. Kouznetsov   TETRAHEDRON