Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All-Carbon Quaternary Stereogenic Centers in Acyclic Systems

Stereodefined trisubstituted enolates as a unique entry to all-carbon quaternary stereogenic centers in acyclic systems

(2013) Yury Minko et al.   Nature Protocols

SN2′ Alkylation of Cyclopropanols via Homoenolates

(2012) Pragna Pratic Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A general stereoselective enamine mediated alkylation of α-substituted aldehydes

(2012) Andrea Gualandi et al.   CHEMICAL COMMUNICATIONS

Noncovalent Bifunctional Organocatalysts: Powerful Tools for Contiguous Quaternary-Tertiary Stereogenic Carbon Formation, Scope, and Origin of Enantioselectivity

(2012) Thomas C. Nugent et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Mediated Cleavage and Activation of C-C Single Bonds

(2012) Klaus Ruhland   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Facially Selective Cu-Catalyzed Carbozincation of Cyclopropenes Using Arylzinc Reagents Formed by Sequential I/Mg/Zn Exchange

(2012) Vinod Tarwade et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes

(2012) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Forming all-carbon quaternary stereogenic centres in acyclic systems from alkynes

(2012) Yury Minko et al.   NATURE

Stereoarrays with an All-Carbon Quaternary Center: Diastereoselective Desymmetrization of Prochiral Malonaldehydes

(2011) Bruno Linclau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Takayuki Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclobutanes in Catalysis

(2011) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective organocatalytic formal allylation of α-branched aldehydes

(2011) Eduardo Rodrigo et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Recent developments of cyclopropene chemistry

(2011) Zhi-Bin Zhu et al.   CHEMICAL SOCIETY REVIEWS

Diastereodivergent Behavior of Alkyl versus Cyano Allenylcuprates toward Aldehydes: A Key Role for Lithium

(2011) Emmanuel Vrancken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis

(2011) Xin Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diasteroselective Preparation of Cyclopropanols Using Methylene Bis(iodozinc)

(2011) Kevin Cheng et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Rearrangements of Small Cycloalkanes: Regioselectivity Trends in β-Carbon Elimination Reactions

(2011) Christophe Aïssa   SYNTHESIS-STUTTGART

Rh2(S-PTAD)4-catalyzed asymmetric cyclopropenation of aryl alkynes

(2011) John F. Briones et al.   TETRAHEDRON

Chiral primary amine mediated conjugate addition of branched aldehydes to vinyl sulfone: asymmetric generation of quaternary carbon centers

(2010) Qiang Zhu et al.   CHEMICAL COMMUNICATIONS

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

Selectivity in Metal-Catalyzed CarbonCarbon Bond Cleavage of Alkylidenecyclopropanes

(2010) Ahmad Masarwa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereospecific Construction of Chiral Tertiary and Quaternary Carbon by Nucleophilic Cyclopropanation with Bis(iodozincio)methane

(2010) Kenichi Nomura et al.   Chemistry-An Asian Journal

Highly Enantioselective Rh2(S-DOSP)4-Catalyzed Cyclopropenation of Alkynes with Styryldiazoacetates

(2010) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A New Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons

(2010) Samah Simaan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioenriched Synthesis of Cyclopropenes with a Quaternary Stereocenter, Versatile Building Blocks

(2010) Misaki Uehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

(2009) Ahmad Masarwa et al.   CHEMICAL COMMUNICATIONS

Cyclopropenylcarbinol Derivatives as New Versatile Intermediates in Organic Synthesis: Application to the Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives

(2009) Samah Simaan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes: New Access to Building Blocks with an Acyclic Quaternary Stereogenic Center

(2009) Samah Simaan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nucleophilic Cyclopropanation Reaction with Bis(iodozincio)methane by 1,4-Addition to α,β-Unsaturated Carbonyl Compounds

(2009) Kenichi Nomura et al.   Chemistry-An Asian Journal

Directed Carbozincation Reactions of Cyclopropene Derivatives

(2009) Vinod Tarwade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective metal-catalyzed activation of strained rings

(2009) Tobias Seiser et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal−Organic Cooperative Catalysis in C−H and C−C Bond Activation and Its Concurrent Recovery

(2008) Young Jun Park et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Hydroformylation of Cyclopropenes

(2008) William M. Sherrill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY