Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

Selective Magnesiation or Zincation of Highly Functionalized Alkenes and Cycloalkenes Using 2,2,6,6-Tetramethylpiperidyl Bases

(2011) Tomke Bresser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethylpiperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective and Multiple Functionalization of Pyridines and AlkaloidsviaMg- and Zn-Organometallic Intermediates

(2011) Milica Jaric et al.   ORGANIC LETTERS

Pd-Catalyzed α-Arylation of Nitriles and Esters and γ-Arylation of Unsaturated Nitriles with TMPZnCl·LiCl

(2011) Stéphanie Duez et al.   ORGANIC LETTERS

Corrigendum: Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn⋅2 MgCl2⋅4 LiCl

(2010) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

tmp4Zr: An Atom-Economical Base for the Metalation of Functionalized Arenes and Heteroarenes

(2010) Masilamani Jeganmohan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective Metalations of Pyridines and Related Heterocycles Using New Frustrated Lewis Pairs or tmp-Zinc and tmp-Magnesium Bases with BF3⋅OEt2

(2010) Milica Jaric et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Dibenzothiophenes and Related Classes of Heterocycles by Using Functionalized Dithiocarbamates

(2010) Marcel Kienle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

MgCl2-Accelerated Addition of Functionalized Organozinc Reagents to Aldehydes, Ketones, and Carbon Dioxide

(2010) Albrecht Metzger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deprotonative metallation of ferrocenes using mixed lithium–zinc and lithium–cadmium combinations

(2010) Gandrath Dayaker et al.   CHEMICAL COMMUNICATIONS

Selective Multiple Magnesiations of the Thieno[3,2-b]thiophene Scaffold

(2010) Thomas Kunz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Atom-Economical Preparation of Aryl- and Heteroaryl-Lanthanum Reagents by Directedortho-Metalation by Using tmp3[La]

(2010) Stefan H. Wunderlich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Chemoselective Zincation of Sensitive and Moderately Activated Aromatics and Heteroaromatics Using TMPZnCl·LiCl

(2010) Tomke Bresser et al.   JOURNAL OF ORGANIC CHEMISTRY

Preparation of Functionalized Cyclic Enol Phosphates by Halogen−Magnesium Exchange and Directed Deprotonation Reactions

(2010) Fabian M. Piller et al.   JOURNAL OF ORGANIC CHEMISTRY

Lithium Cadmate-Mediated Deprotonative Metalation of Anisole: Experimental and Computational Study

(2010) Katia Snégaroff et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids

(2010) Ian B. Seiple et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of functionalized organoaluminiums by direct insertion of aluminium to unsaturated halides

(2010) Tobias Blümke et al.   Nature Chemistry

Phosphorodiamidate-Directed Metalation ofN-Heterocycles using Mg- and Zn-TMP Bases

(2010) Christoph J. Rohbogner et al.   ORGANIC LETTERS

Scaleable Preparation of Sensitive Functionalized Aromatics and Heteroaromatics via Directed Metalation Using tmpZnCl·LiCl

(2010) Tomke Bresser et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Scaleable Preparation of Functionalized OrganometallicsviaDirected Ortho Metalation Using Mg- and Zn-Amide Bases

(2010) Stefan H. Wunderlich et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Nine Times Fluoride can be Good for your Syntheses.Not just Cheaper: Nonafluorobutanesulfonates as Intermediates for Transition Metal-Catalyzed Reactions

(2009) Jens Högermeier et al.   ADVANCED SYNTHESIS & CATALYSIS

Preparation of Functionalized Aryl Iron(II) Compounds and a Nickel-Catalyzed Cross-Coupling with Alkyl Halides

(2009) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitro-Substituted Aryl Lithium Compounds in Microreactor Synthesis: Switch between Kinetic and Thermodynamic Control

(2009) Aiichiro Nagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn⋅2 MgCl2⋅4 LiCl

(2009) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct CH Metalation with Chromium(II) and Iron(II): Transition-Metal Host / Benzenediide Guest Magnetic Inverse-Crown Complexes

(2009) Pablo Alborés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

LiCl-Mediated Preparation of Functionalized Benzylic Indium(III) Halides and Highly Chemoselective Palladium-Catalyzed Cross-Coupling in a Protic Cosolvent

(2009) Yi-Hung Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in the Chemistry and Biology of Naturally Occurring Antibiotics

(2009) K. C. Nicolaou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling

(2009) Gary A. Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aluminum Bases for the Highly Chemoselective Preparation of Aryl and Heteroaryl Aluminum Compounds

(2009) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High temperature zincation of functionalized aromatics and heteroaromatics using TMPZnCl·LiCl and microwave irradiation

(2009) Marc Mosrin et al.   CHEMICAL COMMUNICATIONS

2,3-Functionalization of furans, benzofurans and thiophenes via magnesiation and sulfoxide–magnesium exchange

(2009) Laurin Melzig et al.   CHEMICAL COMMUNICATIONS

Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R=Et,iPr,tBu, Ph, and Me2N) by Using Dialkyl-TMP-Zincate Bases

(2009) William Clegg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metallation versus Indirect Nonsynergic Lateral Metallation

(2009) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Chemoselective Metalation of Chloropyrimidine Derivatives with TMPMgCl⋅LiCl and TMP2Zn⋅2 MgCl2⋅2 LiCl

(2009) Marc Mosrin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Negishi Cross-Couplings Compatible with Unprotected Amide Functions

(2009) Georg Manolikakes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Polyfunctional Arylmagnesium, Arylzinc, and Benzylic Zinc Reagents by Using Magnesium in the Presence of LiCl

(2009) Fabian M. Piller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Deprotonative Metalation of Functionalized Aromatics Using Mixed Lithium-Cadmium, Lithium-Indium, and Lithium-Zinc Species

(2009) Katia Snégaroff et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Mixed Li/Mg and Li/Mg/Zn Amides for the Chemoselective Metallation of Arenes and Heteroarenes

(2009) Christoph J. Rohbogner et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Metalation of Heteroaromatic Esters and Nitriles Using a Mixed Lithium−Cadmium Base. Subsequent Conversion to Dipyridopyrimidinones

(2009) Ghenia Bentabed-Ababsa et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Direct Arylation of Azine and AzoleN-Oxides: Reaction Development, Scope and Applications in Synthesis

(2009) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

All-Carbon Quaternary Centers via Ruthenium-Catalyzed Hydroxymethylation of 2-Substituted Butadienes Mediated by Formaldehyde: Beyond Hydroformylation

(2009) Tomas Smejkal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Amination of Heteroaromatic Zinc Reagents Mediated by PhI(OAc)2

(2009) Marcel Kienle et al.   ORGANIC LETTERS

Synthesis of Fully Substituted Pyrazoles via Regio- and Chemoselective Metalations

(2009) Christina Despotopoulou et al.   ORGANIC LETTERS

TMPZnCl·LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics

(2009) Marc Mosrin et al.   ORGANIC LETTERS

Regio- and Chemoselective Multiple Functionalization of Chloropyrazine Derivatives. Application to the Synthesis of Coelenterazine

(2009) Marc Mosrin et al.   ORGANIC LETTERS

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

(2009) Ben Conway et al.   ORGANOMETALLICS

New Gilman-type lithium cuprate from a copper(II) salt: synthesis and deprotonative cupration of aromatics

(2009) Tan Tai Nguyen et al.   TETRAHEDRON LETTERS

Advances in Molecular Design and Synthesis of Regioregular Polythiophenes

(2008) Itaru Osaka et al.   ACCOUNTS OF CHEMICAL RESEARCH

Complete Switch of Migratory Aptitude in Aluminum‐Catalyzed 1,2‐Rearrangement of Differently α,α‐Disubstituted α‐Siloxy Aldehydes

(2008) Kohsuke Ohmatsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Method formeta andpara Functionalization of Arenes Using TMP2Mg⋅2 LiCl

(2008) Christoph J. Rohbogner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbamoyl Translocations by an Anionicortho-Fries and Cumulenolate α-Acylation Pathway: Regioselective Synthesis of Polysubstituted Chromone 3- and 8-Carboxamides

(2008) Todd K. Macklin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Aryl and Heteroaryl Indium(III) Reagents by the Direct Insertion of Indium in the Presence of LiCl

(2008) Yi-Hung Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient Preparation of Polyfunctional Aryl Magnesium Reagents by a Direct Magnesium Insertion in the Presence of LiCl

(2008) Fabian M. Piller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General and Efficient Method for the Suzuki–Miyaura Coupling of 2-Pyridyl Nucleophiles

(2008) Kelvin L. Billingsley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Study of BF3-Promotedortho Lithiation of Anilines and DFT Calculations on the Role of Fluorine–Lithium Interactions

(2008) Satinder V. Kessar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

(2008) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient mono- and bis-functionalization of 3,6-dichloropyridazine using (tmp)2Zn·2MgCl2·2LiCl

(2008) Stefan Wunderlich et al.   CHEMICAL COMMUNICATIONS

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

(2008) Ben Conway et al.   CHEMICAL COMMUNICATIONS

Polyfunctional benzylic zinc chlorides by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl2

(2008) Albrecht Metzger et al.   CHEMICAL COMMUNICATIONS

Transient absorption spectroscopy of charge photogeneration yields and lifetimes in a low bandgap polymer/fullerenefilm

(2008) Tracey Clarke et al.   CHEMICAL COMMUNICATIONS

Deprotonative cadmation of functionalized aromatics

(2008) Jean-Martial L’Helgoual’ch et al.   CHEMICAL COMMUNICATIONS

Direct Zincation of Functionalized Aromatics and Heterocycles by Using a Magnesium Base in the Presence of ZnCl2

(2008) Zhibing Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Improved Regioselectivity in Pyrazole Formation through the Use of Fluorinated Alcohols as Solvents: Synthesis and Biological Activity of Fluorinated Tebufenpyrad Analogs

(2008) Santos Fustero et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of New Fluorinated Tebufenpyrad Analogs with Acaricidal Activity Through Regioselective Pyrazole Formation

(2008) Santos Fustero et al.   JOURNAL OF ORGANIC CHEMISTRY

Deprotonative Magnesation and Cadmation of [1,2,3]Triazolo[1,5-a]pyridines

(2008) Ghenia Bentabed-Ababsa et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Pudovik Reaction of Aldehydes and Aldimines with Tethered Bis(8-quinolinato) (TBOx) Aluminum Complex

(2008) Joshua P. Abell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mixed Alkylamido Aluminate as a Kinetically Controlled Base

(2008) Hiroshi Naka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

(2008) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Imaging in the era of molecular oncology

(2008) Ralph Weissleder et al.   NATURE

Regio- and chemoselective magnesiation of protected uracils and thiouracils using TMPMgCl·LiCl and TMP2Mg·2LiCl

(2008) Marc Mosrin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regio- and Chemoselective Multiple Functionalization of Pyrimidine Derivatives by Selective Magnesiations using TMPMgCl·LiCl

(2008) Marc Mosrin et al.   ORGANIC LETTERS

Meta- andPara-Difunctionalization of Arenes via a Sulfoxide−Magnesium Exchange Reaction

(2008) Christian B. Rauhut et al.   ORGANIC LETTERS

Oxidative Amination of Cuprated Pyrimidine and Purine Derivatives

(2008) Nadège Boudet et al.   ORGANIC LETTERS

Diastereoselective Synthesis of Enantiopure Acyclic β,β′-Disubstituted Vinylsulfoxides

(2008) Franck Brebion et al.   ORGANIC LETTERS

Negishi Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents

(2008) Georg Manolikakes et al.   ORGANIC LETTERS

High Temperature Metalation of Functionalized Aromatics and Heteroaromatics using (tmp)2Zn·2MgCl2·2LiCl and Microwave Irradiation

(2008) Stefan Wunderlich et al.   ORGANIC LETTERS

Regio- and Chemoselective Synthesis of Fully Substituted Thiophenes

(2008) Fabian M. Piller et al.   ORGANIC LETTERS

Highly Enantioselective Hydrophosphonylation of Aldehydes Catalyzed by Tridentate Schiff Base Aluminum(III) Complexes

(2007) Xin Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt-Like Sodium Sodiumdizincate and Other Unexpected Ion-Pair Products

(2007) William Clegg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functionalization of diazines and benzo derivatives through deprotonated intermediates

(2007) Floris Chevallier et al.   CHEMICAL SOCIETY REVIEWS

Generation and Suppression of 3-/4-Functionalized Benzynes Using Zinc Ate Base (TMP−Zn−ate):  New Approaches to Multisubstituted Benzenes

(2007) Masanobu Uchiyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Fully Substituted Anilines for the Synthesis of Functionalized Indoles

(2007) Armin H. Stoll et al.   ORGANIC LETTERS