Synthesis of sulfonated naphthols via C–H bond functionalization with the insertion of sulfur dioxide

Remote site-selective C–H activation directed by a catalytic bifunctional template

(2017) Zhipeng Zhang et al.   NATURE

Synthesis of m-Alkylphenols via a Ruthenium-Catalyzed C–H Bond Functionalization of Phenol Derivatives

(2017) Gang Li et al.   ORGANIC LETTERS

Pd-Catalyzed Selective Synthesis of Cyclic Sulfonamides and Sulfinamides Using K2S2O5 as a Sulfur Dioxide Surrogate

(2017) Hideyuki Konishi et al.   ORGANIC LETTERS

Formation of α-chiral centers by asymmetric β-C(sp 3 )–H arylation, alkenylation, and alkynylation

(2017) Qing-Feng Wu et al.   SCIENCE

Recent Developments in Ruthenium-Catalyzed C–H Arylation: Array of Mechanistic Manifolds

(2017) Pradeep Nareddy et al.   ACS Catalysis

Beyond C2 and C3: Transition-Metal-Catalyzed C–H Functionalization of Indole

(2017) Jamie A. Leitch et al.   ACS Catalysis

Synthesis of 3-((arylsulfonyl)methyl)indolin-2-ones via insertion of sulfur dioxide using anilines as the aryl source

(2017) Tong Liu et al.   Organic Chemistry Frontiers

Generation of benzosultams via a radical process with the insertion of sulfur dioxide

(2017) Kaida Zhou et al.   Organic Chemistry Frontiers

Reductive insertion of sulfur dioxide for the synthesis of trifluoromethyl thiolsulphonates through a one-pot reaction of aniline and trifluoromethanesulfanylamide

(2017) Jie Sheng et al.   Organic Chemistry Frontiers

Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

(2017) Yang Wang et al.   Organic Chemistry Frontiers

Synthesis of β-keto sulfones via a multicomponent reaction through sulfonylation and decarboxylation

(2017) Jiyao Yu et al.   Organic Chemistry Frontiers

Iron-Catalyzed Direct Alkylamination of Phenols withO-Benzoyl-N-alkylhydroxylamines under Mild Conditions

(2016) Lei Jia et al.   ADVANCED SYNTHESIS & CATALYSIS

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3-Sulfonated Coumarins

(2016) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed synthesis of arylsulfinates through radical coupling reaction

(2016) Weixi Zhang et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Vicinal Difluoroalkylation and Aminosulfonylation of Alkynes under Photoinduced Conditions

(2016) Yuanchao Xiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemoselective cross-coupling reaction of sodium sulfinates with phenols under aqueous conditions

(2016) Fuhong Xiao et al.   GREEN CHEMISTRY

Charge-transfer-directed radical substitution enables para-selective C–H functionalization

(2016) Gregory B. Boursalian et al.   Nature Chemistry

Enantioselective amine α-functionalization via palladium-catalysed C–H arylation of thioamides

(2016) Pankaj Jain et al.   Nature Chemistry

Functionalization of C(sp3)-H bonds using a transient directing group

(2016) F.-L. Zhang et al.   SCIENCE

Ligand-accelerated enantioselective methylene C(sp3)–H bond activation

(2016) Gang Chen et al.   SCIENCE

Origins of unique gold-catalysed chemo- and site-selective C–H functionalization of phenols with diazo compounds

(2016) Yuan Liu et al.   Chemical Science

Copper(i)-catalyzed sulfonylation of (2-alkynylaryl)boronic acids with DABSO

(2016) Runyu Mao et al.   Organic Chemistry Frontiers

Generation of N-aminosulfonamides via a photo-induced fixation of sulfur dioxide into aryl/alkyl halides

(2016) Yuewen Li et al.   Organic Chemistry Frontiers

A copper(i)-catalyzed three-component reaction of triethoxysilanes, sulfur dioxide, and alkyl halides

(2016) Danqing Zheng et al.   Organic Chemistry Frontiers

Generation of (2-oxoindolin-3-yl)methanesulfonohydrazides via a photo-induced reaction of N-(2-iodoaryl)acrylamide, DABSO, and hydrazine

(2016) Kaida Zhou et al.   Organic Chemistry Frontiers

Palladium(II)-Catalyzed Synthesis of Sulfinates from Boronic Acids and DABSO: A Redox-Neutral, Phosphine-Free Transformation

(2015) Alex S. Deeming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Synthesis of (Hetero)Aryl Alkyl Sulfones from (Hetero)Aryl Boronic Acids, Unactivated Alkyl Halides, and Potassium Metabisulfite

(2015) Andre Shavnya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical Organocatalytic Synthesis of Functionalized Non-C 2 -Symmetrical Atropisomeric Biaryls

(2015) Hongyin Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

O2-mediated dehydrogenative amination of phenols

(2015) Marie-Laure Louillat-Habermeyer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Domino Oxidation/Arylation/Protodecarboxylation Reaction of Salicylaldehydes: Expanded Access tometa-Arylphenols

(2015) Junfei Luo et al.   Chemistry-An Asian Journal

Ligand-Enabled Meta-C–H Alkylation and Arylation Using a Modified Norbornene

(2015) Peng-Xiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Fixation of sulfur dioxide into small molecules

(2015) Gang Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Sequential O–H/C–H Bond Insertion of Phenols Initiated by the Gold(I)-Catalyzed Cyclization of 1-Bromo-1,5-enynes

(2015) Klaus Speck et al.   ORGANIC LETTERS

One-Pot, Three-Component Arylalkynyl Sulfone Synthesis

(2015) C. Chun Chen et al.   ORGANIC LETTERS

Selective C–H Bond Fluorination of Phenols with a Removable Directing Group: Late-Stage Fluorination of 2-Phenoxyl Nicotinate Derivatives

(2015) Shao-Jie Lou et al.   ACS Catalysis

Direct Functionalization with Complete and Switchable Positional Control: Free Phenol as a Role Model

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2and Hydrazines

(2014) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Synthesis of Ammonium Sulfinates from Aryl Halides and a Sulfur Dioxide Surrogate: A Gas- and Reductant-Free Process

(2014) Edward J. Emmett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives

(2014) Miles W. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining Organometallic Reagents, the Sulfur Dioxide Surrogate DABSO, and Amines: A One-Pot Preparation of Sulfonamides, Amenable to Array Synthesis

(2014) Alex S. Deeming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic conversion of aryl triazenes into aryl sulfonamides using sulfur dioxide as the sulfonyl source

(2014) Wanfang Li et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Aminosulfonylation of Aryl Iodides by using Na2SO3as the SO2Source

(2014) Wanfang Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxidative Olefination of Phenols Bearing Removable Directing Groups under Molecular Oxygen

(2014) Bin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Overriding Ortho–Para Selectivity via a Traceless Directing Group Relay Strategy: The Meta-Selective Arylation of Phenols

(2014) Junfei Luo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild, Ferrocene-Catalyzed C–H Imidation of (Hetero)Arenes

(2014) Klement Foo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes

(2014) Laura J. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Copper-Catalyzed Three-Component Reaction of Triethoxysilanes, Sulfur Dioxide, and Hydrazines

(2014) Xianbo Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Decarboxylative Coupling of α- Oxocarboxylic Acids with C(sp2)H of 2-Aryloxypyridines

(2013) Jinzhong Yao et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Three-Component Diaryl Sulfone Synthesis Exploiting the Sulfur Dioxide Surrogate DABSO

(2013) Edward J. Emmett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed CH Alkenylations of Phenols with Removable Directing Groups

(2013) Wenbo Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(II)-Catalyzed ortho- or meta-C–H Olefination of Phenol Derivatives

(2013) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

(2013) Philippe Bisseret et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

DABSO-Based, Three-Component, One-Pot Sulfone Synthesis

(2013) Alex S. Deeming et al.   ORGANIC LETTERS

Synthesis of Sulfones from Organozinc Reagents, DABSO, and Alkyl Halides

(2013) Benjamin N. Rocke et al.   ORGANIC LETTERS

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A palladium-catalyzed reaction of aryl halides, potassium metabisulfite, and hydrazines

(2012) Shengqing Ye et al.   CHEMICAL COMMUNICATIONS

2-Pyridylmethyl ether: a readily removable and efficient directing group for amino acidligand accelerated ortho-C–H olefination of phenols

(2012) Xuefeng Cong et al.   CHEMICAL COMMUNICATIONS

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

Palladium-catalysed aminosulfonylation of aryl-, alkenyl- and heteroaryl halides: scope of the three-component synthesis of N-aminosulfonamides

(2012) Edward J. Emmett et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal-Free Ortho C–H Borylation of 2-Phenoxypyridines under Mild Conditions

(2012) Liting Niu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed C–H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Dibenzofurans via Palladium-Catalyzed Phenol-Directed C–H Activation/C–O Cyclization

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Selective C–H Activation/Olefination of Phenol Carbamates

(2011) Tian-Jun Gong et al.   ORGANIC LETTERS

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Palladium-CatalyzedOrtho-Arylation ofO-Phenylcarbamates with Simple Arenes and Sodium Persulfate

(2010) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Aminosulfonylation of Aryl Halides

(2010) Bao Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-CatalyzedOrthoArylation of 2-Phenoxypyridines with Potassium Aryltrifluoroborates via C−H Functionalization

(2010) Jean-Ho Chu et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Phenol Esters

(2009) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Acylation of sp2C−H bond: Direct Access to Ketones from Aldehydes

(2009) Xiaofei Jia et al.   ORGANIC LETTERS