Cobalt-Catalyzed C(sp3 )−H Functionalization Reactions

Transition-Metal-Catalyzed Selective Functionalization of C(sp3 )−H Bonds in Natural Products

(2018) Rashad R. Karimov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C−H Arylation Meets Perovskite Solar Cells: Tin-Free Synthesis Shortcut to High-Performance Hole-Transporting Materials

(2018) Yu-Chieh Chang et al.   Chemistry-An Asian Journal

Recent advances in C(sp 3 ) H bond carbonylation by first row transition metals

(2018) Nimmakuri Rajesh et al.   TETRAHEDRON LETTERS

sp3 C–H activation via exo-type directing groups

(2018) Yan Xu et al.   Chemical Science

Cobalt-Catalyzed Allylic C(sp3)–H Carboxylation with CO2

(2017) Kenichi Michigami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Co-Catalyzed Direct Addition of Allylic C(sp3)–H Bonds to Ketones

(2017) Tsuyoshi Mita et al.   ORGANIC LETTERS

Cobalt-Catalyzed Intramolecular Oxidative C(sp3)–H/N–H Carbonylation of Aliphatic Amides

(2017) Li Zeng et al.   ORGANIC LETTERS

Recent Developments in Cobalt Catalyzed Carbon–Carbon and Carbon–Heteroatom Bond Formation via C–H Bond Functionalization

(2017) Zheng-Hui Guan et al.   SYNTHESIS-STUTTGART

Cobalt catalyzed carbonylation of unactivated C(sp3)–H bonds

(2017) Nagaraju Barsu et al.   Chemical Science

Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

(2017) Patrick Williamson et al.   Chemical Science

Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp3)–H Bonds

(2017) W. Neil Palmer et al.   ACS Catalysis

Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis

(2016) Stephen E. Ammann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Cp*CoIII-Catalyzed C(sp3)−H Bond Amidation of 8-Methylquinoline

(2016) Nagaraju Barsu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)–H Bonds

(2016) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study

(2016) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Generation and Isolation of π-Allyl Complexes from Aliphatic Alkenes and an Electron-Deficient Rh(III) Complex: Key Intermediates of Allylic C–H Functionalization

(2016) Yu Shibata et al.   ORGANOMETALLICS

Intramolecular hydrogen transfer reactions catalyzed by pentamethylcyclopentadienyl rhodium and cobalt olefin complexes: Mechanistic studies

(2016) Andrew D. Bolig et al.   POLYHEDRON

Cp*Co(III)-Catalyzed C(sp3)–H Bond Activation: A Highly Stereoselective and Regioselective Alkenylation of 8-Methylquinoline with Alkynes

(2016) Malay Sen et al.   ACS Catalysis

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Recent advances in copper-mediated chelation-assisted functionalization of unactivated C–H bonds

(2016) Wei-Hao Rao et al.   Organic Chemistry Frontiers

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt-Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents

(2015) Juhyeon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions

(2015) Luis C. Misal Castro et al.   CHEMISTRY LETTERS

RhIII-Catalyzed C(sp3)H Bond Activation by an External Base Metalation/Deprotonation Mechanism: A Theoretical Study

(2015) Julong Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances in First-Row-Transition-Metal-Catalyzed Dehydrogenative Cou­pling of C(sp3)-H Bonds

(2015) Jinmin Miao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Cyclization of Aliphatic Amides and Terminal Alkynes with Silver-Cocatalyst

(2015) Jitan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent

(2015) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Study of Sustainability and Scalability in the Cp*Rh(III)-Catalyzed Direct C–H Amidation with 1,4,2-Dioxazol-5-ones

(2015) Yoonsu Park et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp3 carbons

(2015) Xuesong Wu et al.   Nature Communications

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Cobalt-Catalyzed, Aminoquinoline-Directed C(sp2)H Bond Alkenylation by Alkynes

(2014) Liene Grigorjeva et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Palladium-Catalyzed C(sp3)–H Activation for the Formation of Carbon–Carbon and Carbon–Heteroatom Bonds

(2014) Michael Schnürch et al.   SYNTHESIS-STUTTGART

A Cationic High-Valent Cp*CoIIIComplex for the Catalytic Generation of Nucleophilic Organometallic Species: Directed CH Bond Activation

(2013) Tatsuhiko Yoshino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Hydrosilation/Hydrogen-Transfer Cascade Reaction: A New Route to Silyl Enol Ethers

(2013) Thomas W. Lyons et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cp*CoIII-Catalyzed C2-Selective Addition of Indoles to Imines

(2013) Tatsuhiko Yoshino et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

(2012) Thomas Cochet et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Development of more labile low electron count Co(i) sources: mild, catalytic functionalization of activated alkanes using a [(Cp*Co)2-μ-(η4:η4-arene)] complex

(2011) Fernando Hung-Low et al.   CHEMICAL COMMUNICATIONS

Hydroarylation of alkynes catalyzed by nickel

(2011) Yoshiaki Nakao   CHEMICAL RECORD

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

(2011) Emmanuel Ferrer Flegeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Low-Valent Iron-Catalyzed C−C Bond Formation−Addition, Substitution, and C−H Bond Activation

(2010) Eiichi Nakamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation

(2010) Ke Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Carbonylation at Ortho C−H Bonds in Aromatic Amides Leading to Phthalimides: C−H Bond Activation Utilizing a Bidentate System

(2009) Satoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY