Journal
GREEN CHEMISTRY
Volume 19, Issue 1, Pages 82-87Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc02517j
Keywords
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Funding
- National Natural Science Foundation of China (NSFC) [21432003, 21272102]
- Program for Chang-jiang Scholars and Innovative Research Team in University (PCSIRT) [IRT_15R27]
- Special Research Fund for the Doctoral Program of Higher Education [20130211130005]
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We have reported herein a catalyst-free 1,3-dipolar cycloaddition of C, N-cyclic azomethine imines and 3-nitroindoles by which a series of five-ring-fused tetrahydroisoquinolines featuring an indoline scaffold were obtained as single diastereomers in moderate to high yields without any additives under mild conditions. Moreover, the current method provides a novel and convenient approach for the efficient incorporation of two biologically important scaffolds (tetrahydroisoquinoline and indoline).
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