Polar organometallic strategies for regioselective C–H metallation of N-heterocyclic carbenes

Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C–H Functionalizations

(2017) Marina Uzelac et al.   INORGANIC CHEMISTRY

A Stable Anionic Dithiolene Radical

(2017) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deprotonation of Group 14 Metal Amide Complexes Bearing Ditopic Carbanionic N-Heterocyclic Carbene Ligands. Constitutional Isomerism and Dynamic Behavior

(2017) Jordan B. Waters et al.   ORGANOMETALLICS

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans-Metal-Trapping

(2016) Marina Uzelac et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis

(2016) Alexandre Nasr et al.   COORDINATION CHEMISTRY REVIEWS

Heavier Alkali-metal Gallates as Platforms for Accessing Functionalized Abnormal NHC Carbene-Gallium Complexes

(2016) Marina Uzelac et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule

(2015) Antonio J. Martínez-Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented directed lateral lithiations of tertiary carbons on NHC platforms

(2015) Andreas A. Danopoulos et al.   CHEMICAL COMMUNICATIONS

Normal-to-Abnormal NHC Rearrangement of AlIII, GaIII, and InIIITrialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2Activation

(2015) Gilles Schnee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Coordination chemistry of ditopic carbanionic N-heterocyclic carbenes

(2015) Jordan B. Waters et al.   COORDINATION CHEMISTRY REVIEWS

Accessing Sodium Ferrate Complexes Containing Neutral and Anionic N-Heterocyclic Carbene Ligands: Structural, Synthetic, and Magnetic Insights

(2015) Lewis C. H. Maddock et al.   INORGANIC CHEMISTRY

Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights

(2015) Marina Uzelac et al.   Chemical Science

Fusing N-Heterocyclic Carbenes with Carborane Anions

(2014) Ahmad El-Hellani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

‘Janus-type’ organopotassium chemistry observed in deprotonation of mesoionic imidazolium aminides and amino N-heterocyclic carbenes: coordination and organometallic polymers

(2014) Andreas A. Danopoulos et al.   CHEMICAL COMMUNICATIONS

Ruthenium Complexes of an Abnormally Bound, Anionic N-Heterocyclic Carbene

(2014) Conor Pranckevicius et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkali metal salts of ditopic carbanionic carbenes as reagents for the synthesis of novel complexes of group 12 and 14 metals

(2014) Jordan B. Waters et al.   DALTON TRANSACTIONS

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation

(2014) A. J. Martinez-Martinez et al.   SCIENCE

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation–alkylaluminium-trapping reagents?

(2014) David R. Armstrong et al.   Chemical Science

Site specific carboxylation of abnormal anionic N-heterocyclic dicarbenes with CO2

(2013) Monika Vogt et al.   CHEMICAL COMMUNICATIONS

Abnormal N-heterocyclic carbene main group organometallic chemistry: a debut to the homogeneous catalysis

(2013) Tamal K. Sen et al.   DALTON TRANSACTIONS

Iridium(I) Complexes with Anionic N-Heterocyclic Carbene Ligands as Catalysts for the Hydrogenation of Alkenes in Nonpolar Media

(2013) Eugene L. Kolychev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au(i) complex with a NHC anion

(2013) David R. Armstrong et al.   Chemical Science

Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

(2013) A. J. Martínez-Martínez et al.   Chemical Science

NHC-Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene-Zinc Complexes

(2012) Yuzhong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anionic N-Heterocyclic Carbenes That Contain a Weakly Coordinating Borate Moiety

(2012) Sabrina Kronig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Anionic N-Heterocyclic Dicarbenes to Abnormal Carbene–Borane Complexes: A Logical Synthetic Route

(2012) Yuzhong Wang et al.   ORGANOMETALLICS

N-Heterocyclic-Carbene-Induced Monomerization of Sterically Encumbered Dialkylmagnesium and Dialkylmanganese Polymers

(2011) Alan R. Kennedy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

N-Heterocyclic Carbenes and Charge Separation in Heterometallic s-Block Silylamides

(2011) Michael S. Hill et al.   INORGANIC CHEMISTRY

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures

(2010) Elaine Crosbie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs

(2010) Alan R. Kennedy et al.   DALTON TRANSACTIONS

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

(2010) David R. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Viable Anionic N-Heterocyclic Dicarbene

(2010) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

A Hydride-Rich Magnesium Cluster

(2009) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metallation versus Indirect Nonsynergic Lateral Metallation

(2009) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

(2009) A. R. Kennedy et al.   SCIENCE

A New Interpretation of the Reaction Pathway of Deprotonative Metalation with TMP−Zn-ate/TMEDA Complex [TMEDA·Na(μ-tBu)(μ-TMP)Zn(tBu)]

(2008) Daisuke Nobuto et al.   JOURNAL OF ORGANIC CHEMISTRY