TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation–alkylaluminium-trapping reagents?

Reactivity and catalytic activity of tert-butoxy-aluminium hydride reagents

(2014) Robert J. Less et al.   DALTON TRANSACTIONS

Synthetically Important Alkali-Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

(2013) Robert E. Mulvey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of functionalized aryl and heteroaryl aluminum reagents by halogen–lithium exchange

(2013) Thomas Klatt et al.   CHEMICAL COMMUNICATIONS

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 1. Structural Data

(2013) Anne Harrison-Marchand et al.   CHEMICAL REVIEWS

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

(2013) Florence Mongin et al.   CHEMICAL REVIEWS

Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray Crystallographic and NMR Spectroscopic Studies

(2013) Eva Hevia et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Convenient Alumination of Functionalized Aromatics by Using the Frustrated Lewis Pair Et3Al and TMPMgCl⋅LiCl

(2013) Andreas Unsinn et al.   CHEMISTRY-A EUROPEAN JOURNAL

An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

(2013) Robert E. Mulvey   DALTON TRANSACTIONS

Deproto-metallation using a mixed lithium–zinc base and computed CH acidity of 1-aryl 1H-benzotriazoles and 1-aryl 1H-indazoles

(2013) Elisabeth Nagaradja et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

(2012) Ben Conway et al.   CHEMICAL COMMUNICATIONS

Deproto-metallation and computed CH acidity of 2-aryl-1,2,3-triazoles

(2012) Floris Chevallier et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Opening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?

(2012) David R. Armstrong et al.   Chemical Science

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

(2011) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethylpiperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products

(2011) Elaine Crosbie et al.   DALTON TRANSACTIONS

Structurally Powered Synergic 2,2,6,6-Tetramethylpiperidine Bimetallics: New Reflections through Lithium-MediatedOrthoAluminations

(2011) Robert E. Mulvey et al.   INORGANIC CHEMISTRY

Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures

(2010) Elaine Crosbie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Aluminum Bases for the Highly Chemoselective Preparation of Aryl and Heteroaryl Aluminum Compounds

(2009) Stefan H. Wunderlich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deprotonative Metalation of Functionalized Aromatics Using Mixed Lithium-Cadmium, Lithium-Indium, and Lithium-Zinc Species

(2009) Katia Snégaroff et al.   CHEMISTRY-A EUROPEAN JOURNAL

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

(2009) Ben Conway et al.   ORGANOMETALLICS

Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)

(2008) Deyu Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Unmasking Representative Structures of TMP-Active Hauser and Turbo-Hauser Bases

(2008) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mixed Alkylamido Aluminate as a Kinetically Controlled Base

(2008) Hiroshi Naka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determining accurate molecular sizes in solution through NMR diffusion spectroscopy

(2007) Alceo Macchioni et al.   CHEMICAL SOCIETY REVIEWS