Normal-to-Abnormal NHC Rearrangement of AlIII, GaIII, and InIIITrialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2Activation

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

(2015) Melissa Wu. M et al.   DALTON TRANSACTIONS

Synthesis of Heterobimetallic Group 13 Compounds via Oxidative Addition Reaction of Gallanediyl LGa and InEt3

(2015) Chelladurai Ganesamoorthy et al.   ORGANOMETALLICS

Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural, stability and isomerization insights

(2015) Marina Uzelac et al.   Chemical Science

Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications

(2014) Stéphane Bellemin-Laponnaz et al.   CHEMICAL REVIEWS

Group 13 metal (Al, Ga, In, Tl) complexes supported by heteroatom-bonded carbene ligands

(2014) Christophe Fliedel et al.   COORDINATION CHEMISTRY REVIEWS

NHC-Mediated Synthesis of an Asymmetric, Cationic Phosphoranide, a Phosphanide, and Coinage-Metal Phosphanido Complexes

(2013) Kai Schwedtmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unusual Tilted Carbene Coordination in Carbene Complexes of Gallium(I) and Indium(I)

(2013) Alexander Higelin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC to aNHC rearrangement by an organotin sulphide cation

(2013) Michael Wagner et al.   CHEMICAL COMMUNICATIONS

C–H Bond Activation by Radical Ion Pairs Derived from R3P/Al(C6F5)3 Frustrated Lewis Pairs and N2O

(2013) Gabriel Ménard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Normal-to-Abnormal Rearrangement and NHC Activation in Three-Coordinate Iron(II) Carbene Complexes

(2013) Benjamin M. Day et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dialkylgallium Complexes with Alkoxide and Aryloxide Ligands Possessing N-Heterocyclic Carbene Functionalities: Synthesis and Structure

(2013) Paweł Horeglad et al.   ORGANOMETALLICS

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene-Zinc Complexes

(2012) Yuzhong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anionic N-Heterocyclic Carbenes That Contain a Weakly Coordinating Borate Moiety

(2012) Sabrina Kronig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal Complexes of Anionic N-Heterocyclic Dicarbene Ligands

(2012) Rebecca A. Musgrave et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3-Based Frustrated Lewis Pairs

(2012) Gabriel Ménard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond

(2012) Kate F. Donnelly et al.   CHEMICAL COMMUNICATIONS

Cationic Gallium(III) Halide Complexes: A New Generation of π-Lewis Acids

(2012) Shun Tang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Abnormal, mesoionic and remote N-heterocyclic carbene complexes

(2012) Robert H. Crabtree   COORDINATION CHEMISTRY REVIEWS

Proton Transfer Reactions of Triazol-3-ylidenes: Kinetic Acidities and Carbon Acid pKa Values for Twenty Triazolium Salts in Aqueous Solution

(2012) Richard S. Massey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-Based Lewis Pairs for Hydrogen Activation

(2011) Jason W. Runyon et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Modelling fundamental arene–borane contacts: spontaneous formation of a dibromoborenium cation driven by interaction between a borane Lewis acid and an arene π system

(2011) Hassanatu B. Mansaray et al.   CHEMICAL COMMUNICATIONS

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Low valent and hydride complexes of NHC coordinated gallium and indium

(2011) Graham E. Ball et al.   DALTON TRANSACTIONS

Chelating C4-Bound Imidazolylidene Complexes through Oxidative Addition of Imidazolium Salts to Palladium(0)

(2011) Anneke Krüger et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High-Molecular-Weight Polymers

(2010) Yuetao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unusual reactivity in organoaluminium and NHC chemistry: deprotonation of AlMe3 by an NHC moiety involving the formation of a sterically bulky NHC–AlMe3 Lewis adduct

(2010) Anne-Laure Schmitt et al.   CHEMICAL COMMUNICATIONS

Selective heterolytic P–P bond cleavage of white phosphorus by a frustrated carbene-borane Lewis pair

(2010) Dirk Holschumacher et al.   DALTON TRANSACTIONS

Reactions of Amine- and Phosphane-Borane Adducts with Frustrated Lewis Pair Combinations of Group 14 Triflates and Sterically Hindered Nitrogen Bases

(2010) George R. Whittell et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Room Temperature Reduction of CO2to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane

(2010) Gabriel Ménard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Viable Anionic N-Heterocyclic Dicarbene

(2010) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 4- and 4,5-Functionalized Imidazol-2-ylidenes from a Single 4,5-Unsubstituted Imidazol-2-ylidene

(2010) Daniel Mendoza-Espinosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a stable adduct of dialane(4) (Al2H4) via hydrogenation of a magnesium(I) dimer

(2010) Simon J. Bonyhady et al.   Nature Chemistry

Three-Coordinate N-Heterocyclic Carbene Nickel Nitrosyl Complexes

(2010) Matthew S. Varonka et al.   ORGANOMETALLICS

Performance of density functional theory on homogeneous gold catalysis

(2010) Olalla Nieto Faza et al.   THEORETICAL CHEMISTRY ACCOUNTS

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

F-Block N-Heterocyclic Carbene Complexes

(2009) Polly L. Arnold et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Tertiary Amine andN-Heterocyclic Carbene Coordinated Haloalanes-Synthesis, Structure, and Application

(2009) Sean G. Alexander et al.   CHEMISTRY-A EUROPEAN JOURNAL

CO2, Magnesium, Aluminum, and Zinc Adducts of N-Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis

(2009) Bhasker Bantu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Consistent van der Waals Radii for the Whole Main Group

(2009) Manjeera Mantina et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of an Amino-Linked N-Heterocyclic Carbene and the Reactivity of its Aluminum Adduct

(2009) Wei-Chih Shih et al.   ORGANOMETALLICS

Isolation of a C5-Deprotonated Imidazolium, a Crystalline "Abnormal" N-Heterocyclic Carbene

(2009) E. Aldeco-Perez et al.   SCIENCE

Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair

(2008) Dirk Holschumacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Abnormal and Normal N-Heterocyclic Carbene Osmium Polyhydride Complexes Obtained by Direct Metalation of Imidazolium Salts

(2008) Beatriz Eguillor et al.   ORGANOMETALLICS