Pre-inverse-crowns: synthetic, structural and reactivity studies of alkali metal magnesiates primed for inverse crown formation

Modifying Alkylzinc Reactivity with 2,2′-Dipyridylamide: Activation oftBuZn Bonds forpara-Alkylation of Benzophenone

(2013) David R. Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mixed AggregAte (MAA): A Single Concept for All Dipolar Organometallic Aggregates. 2. Syntheses and Reactivities of Homo/HeteroMAAs

(2013) Florence Mongin et al.   CHEMICAL REVIEWS

Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray Crystallographic and NMR Spectroscopic Studies

(2013) Eva Hevia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Characterization of Hexameric and Octamericsec-Butyllithium/sec-Butoxide Mixed Aggregates

(2013) Chicheung Su et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

TMPZnOPiv•LiCl: A New Base for the Preparation of Air-Stable Solid Zinc Pivalates of Sensitive Aromatics and Heteroaromatics

(2013) Christos I. Stathakis et al.   ORGANIC LETTERS

In Situ Anionic Shielding for Regioselective Metalation: Directed peri and Iterative Metalation Routes to Polyfunctionalized 7-Azaindoles

(2012) Cédric Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Higher-Order Zincates as Transmetalators in Alkyl-Alkyl Negishi Cross-Coupling

(2012) Lucas C. McCann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ambient temperature zincation of N-Boc pyrrolidine and its solvent dependency

(2012) Jennifer A. Garden et al.   CHEMICAL COMMUNICATIONS

Directed Remote Aromatic Metalations: Mechanisms and Driving Forces

(2012) David Tilly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereocontrol with Lithium Trimethylzincate toward Gibberellin Synthesis

(2012) Minoru Isobe et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Metalation ofN,N-Diisopropylferrocenecarboxamide and Methyl Ferrocenecarboxylate Using Lithium-Metal Chiral Bases

(2012) Gandrath Dayaker et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cationic, Neutral, and Anionic Allyl Magnesium Compounds: Unprecedented Ligand Conformations and Reactivity Toward Unsaturated Hydrocarbons

(2012) Crispin Lichtenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structural Elucidation, and Diffusion-Ordered NMR Studies of Homoleptic Alkyllithium Magnesiates: Donor-Controlled Structural Variations in Mixed-Metal Chemistry

(2012) Sharon E. Baillie et al.   ORGANOMETALLICS

Li+-templated complexation of cylindrical macrotricyclic host with naphthalene diimide: Cation-controlled switchable complexation processes

(2012) Fei Zeng et al.   Science China-Chemistry

(Chiral) lithium–(magnesium–)zinc and lithium–cobalt combinations as dual reagents for aromatic deproto-metalation and aryl transfer to aldehydes

(2012) David Tilly et al.   TETRAHEDRON

Opening the black box of mixed-metal TMP metallating reagents: direct cadmation or lithium–cadmium transmetallation?

(2012) David R. Armstrong et al.   Chemical Science

Two-, three- and four-component coupling to form isoquinolones based on directed metalation

(2012) Monika I. Antczak et al.   Chemical Science

“LiZn(TMP)3”, a Zincate or a Turbo-Lithium Amide Reagent? DOSY NMR Spectroscopic Evidence

(2011) Pablo García-Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pure α-Metallated Benzyllithium from a Single-Crystal-to-Single-Crystal Transition

(2011) Tanja Tatic et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases

(2011) Benjamin Haag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Rings in Chemical and Biological Recognition: Energetics and Structures

(2011) Laura M. Salonen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Meta-metallation ofN,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

(2011) David R Armstrong et al.   Beilstein Journal of Organic Chemistry

Remote functionalisation via sodium alkylamidozincate intermediates: access to unusual fluorenone and pyridyl ketone reactivity patterns

(2011) James J. Crawford et al.   CHEMICAL COMMUNICATIONS

Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone

(2011) D. R. Armstrong et al.   CHEMICAL COMMUNICATIONS

New lithium-zincate approaches for the selective functionalisation of pyrazine: direct dideprotozincation vs. nucleophilic alkylation

(2011) Sharon E. Baillie et al.   CHEMICAL COMMUNICATIONS

Molecular Structures of THF-Solvated Alkali-Metal 2,2,6,6-Tetramethylpiperidides Finally Revealed: X-ray Crystallographic, DFT, and NMR (including DOSY) Spectroscopic Studies

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Identification of a Higher-Order Organozincate Intermediate Involved in Negishi Cross-Coupling Reactions by Mass Spectrometry and NMR Spectroscopy

(2011) Howard N. Hunter et al.   CHEMISTRY-A EUROPEAN JOURNAL

General Copper-Catalyzed Transformations of Functional Groups from Arylboronic Acids in Water

(2011) Haijun Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Polar Organometallic Reagents: an Evergreen Tool for Tuning the Reactivity of Unsaturated Systems

(2011) Annamaria Deagostino et al.   CURRENT ORGANIC CHEMISTRY

Synthesis and structural chemistry of alkali metal tris(HMDS) magnesiates containing chiral diamine donor ligands

(2011) Pablo García-Álvarez et al.   DALTON TRANSACTIONS

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands

(2011) Jennifer A. Garden et al.   DALTON TRANSACTIONS

Assessing the reactivity of sodium zincate [(TMEDA)Na(TMP)ZntBu2] towards benzoylferrocene: deprotonative metalationvs.alkylation reactions

(2011) Eva Hevia et al.   DALTON TRANSACTIONS

Synthesis and structural elucidation of a rare example of a tris(amido) potassium magnesiate

(2011) Ben J. Fleming et al.   INORGANICA CHIMICA ACTA

Measurement of Solution Viscosity via Diffusion-Ordered NMR Spectroscopy (DOSY)

(2011) Weibin Li et al.   JOURNAL OF CHEMICAL EDUCATION

Reactivity of mixed organozinc and mixed organocopper reagents: 5-A kinetic insight to compare the transfer ability of the same group in copper catalyzed alkylation of mixed and homozincates

(2011) Ender Erdik et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex, (THF)Li(TMP)Zn(tBu)2 and applications in in situ cross coupling reactions

(2011) Victoria L. Blair et al.   TETRAHEDRON LETTERS

Convenient Electrophilic Fluorination of Functionalized Aryl and Heteroaryl Magnesium Reagents

(2010) Shigeyuki Yamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities

(2010) David R. Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The first asymmetric organolithium tetramers with simple ether donor bases

(2010) Tanja Tatic et al.   CHEMICAL COMMUNICATIONS

Structural elaboration of the surprising ortho-zincation of benzyl methyl ether

(2010) Liam Balloch et al.   CHEMICAL COMMUNICATIONS

Reaction Mechanism for the LiCl-Mediated Directed Zinc Insertion: A Computational and Experimental Study

(2010) Ching-Yuan Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diffusion Coefficient−Formula Weight Correlation Analysis via Diffusion-Ordered Nuclear Magnetic Resonance Spectroscopy (DOSY NMR) To Examine Acylglycerol Mixtures and Biodiesel Production

(2010) Aaron M. Socha et al.   ENERGY & FUELS

Novel quinoline and naphthalene derivatives as potent antimycobacterial agents

(2010) Ram Shankar Upadhayaya et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

(2010) David R. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

(2010) Robert E. Mulvey et al.   Nature Chemistry

Physically Separated References for Diffusion Coefficient-Formula Weight (D-FW) Analysis of Diffusion-Ordered NMR Spectroscopy (DOSY) in Water

(2010) Weibin Li et al.   ORGANIC LETTERS

Phosphorodiamidate-Directed Metalation ofN-Heterocycles using Mg- and Zn-TMP Bases

(2010) Christoph J. Rohbogner et al.   ORGANIC LETTERS

Scaleable Preparation of Functionalized OrganometallicsviaDirected Ortho Metalation Using Mg- and Zn-Amide Bases

(2010) Stefan H. Wunderlich et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Concerning the Structures of Alkali-Metal-MediatedorthoZincation of Benzamides and PhenylO-Carbamate

(2010) Liam Balloch et al.   ORGANOMETALLICS

2,3-Functionalization of furans, benzofurans and thiophenes via magnesiation and sulfoxide–magnesium exchange

(2009) Laurin Melzig et al.   CHEMICAL COMMUNICATIONS

Theoretical Study on the Halogen-Zinc Exchange Reaction by Using Organozincate Compounds

(2009) Shinji Nakamura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structural Tracking of the Potassium-Mediated Magnesiation of Anisole

(2009) William Clegg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metallation versus Indirect Nonsynergic Lateral Metallation

(2009) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Chemoselective Metalation of Chloropyrimidine Derivatives with TMPMgCl⋅LiCl and TMP2Zn⋅2 MgCl2⋅2 LiCl

(2009) Marc Mosrin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Polyfunctional Arylmagnesium, Arylzinc, and Benzylic Zinc Reagents by Using Magnesium in the Presence of LiCl

(2009) Fabian M. Piller et al.   CHEMISTRY-A EUROPEAN JOURNAL

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

(2009) Ross Campbell et al.   DALTON TRANSACTIONS

New Mixed Li/Mg and Li/Mg/Zn Amides for the Chemoselective Metallation of Arenes and Heteroarenes

(2009) Christoph J. Rohbogner et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Alkali-Metal-Mediated Manganation(II) of Naphthalenes: Constructing Metalla-Anthracene and Metalla-Phenanthrene Structures

(2009) Victoria L. Blair et al.   INORGANIC CHEMISTRY

Kinetics of Bromine−Magnesium Exchange Reactions in Substituted Bromobenzenes

(2009) Lei Shi et al.   JOURNAL OF ORGANIC CHEMISTRY

Combined Directedorthoand Remote Metalation−Suzuki Cross-Coupling Strategies. Efficient Synthesis of Heteroaryl-Fused Benzopyranones from BiarylO-Carbamates

(2009) Clint A. James et al.   JOURNAL OF ORGANIC CHEMISTRY

Formula Weight Prediction by Internal Reference Diffusion-Ordered NMR Spectroscopy (DOSY)

(2009) Deyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Fully Substituted Pyrazoles via Regio- and Chemoselective Metalations

(2009) Christina Despotopoulou et al.   ORGANIC LETTERS

Enantioselective Conjugate Addition of a Lithium Ester Enolate Catalyzed by Chiral Lithium Amides: A Possible Intermediate Characterized

(2009) Baptiste Lecachey et al.   ORGANIC LETTERS

Characterization of Reactive Intermediates by Multinuclear Diffusion-Ordered NMR Spectroscopy (DOSY)

(2008) Deyu Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Radical Catalysis of Kumada Cross-Coupling Reactions Using Functionalized Grignard Reagents

(2008) Georg Manolikakes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Method formeta andpara Functionalization of Arenes Using TMP2Mg⋅2 LiCl

(2008) Christoph J. Rohbogner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient Preparation of Polyfunctional Aryl Magnesium Reagents by a Direct Magnesium Insertion in the Presence of LiCl

(2008) Fabian M. Piller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural and Magnetic Insights into the Trinuclear Ferrocenophane and Unexpected Hydrido Inverse Crown Products of Alkali-Metal-Mediated Manganation(II) of Ferrocene

(2008) Victoria L. Blair et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Mono- and 1,2-Difunctionalisation of Cyclopentene Derivatives via Mg and Cu Intermediates

(2008) Christina Despotopoulou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isolation and characterisation of a (−)-sparteine coordinated mixed alkyl/amido sodium magnesiate, a chiral variant of an important utility ate base

(2008) Alan R. Kennedy et al.   DALTON TRANSACTIONS

Analysis of an Asymmetric Addition with a 2:1 Mixed Lithium Amide/n-Butyllithium Aggregate

(2008) Jia Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Aggregation Studies of Complexes Containing a Chiral Lithium Amide andn-Butyllithium

(2008) Deyu Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Regio- and Chemoselective Multiple Functionalization of Pyrimidine Derivatives by Selective Magnesiations using TMPMgCl·LiCl

(2008) Marc Mosrin et al.   ORGANIC LETTERS

Preparation of Functionalized Alkylmagnesium Derivatives Using an I/Mg-Exchange

(2008) Christian B. Rauhut et al.   ORGANIC LETTERS

Oxidative Amination of Cuprated Pyrimidine and Purine Derivatives

(2008) Nadège Boudet et al.   ORGANIC LETTERS

Regio- and Chemoselective Synthesis of Fully Substituted Thiophenes

(2008) Fabian M. Piller et al.   ORGANIC LETTERS

Relative Rates of Bromine–Magnesium Exchange Reactions in Substituted Bromobenzene Derivatives

(2007) Lei Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structurally Defined Reactions of Sodium TMP–Zincate with Nitrile Compounds: Synthesis of a Salt-Like Sodium Sodiumdizincate and Other Unexpected Ion-Pair Products

(2007) William Clegg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese(ii)–lithium and –sodium inverse crown ether (ICE) complexes

(2007) Alan R. Kennedy et al.   CHEMICAL COMMUNICATIONS

Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate

(2007) David R. Armstrong et al.   CHEMICAL COMMUNICATIONS

Determining accurate molecular sizes in solution through NMR diffusion spectroscopy

(2007) Alceo Macchioni et al.   CHEMICAL SOCIETY REVIEWS

Preparation of Fully Substituted Anilines for the Synthesis of Functionalized Indoles

(2007) Armin H. Stoll et al.   ORGANIC LETTERS