Enantioselective Rhodium-Catalyzed Dimerization of ω-Allenyl Carboxylic Acids: Straightforward Synthesis of C 2 -Symmetric Macrodiolides

Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Pyridazinones with Terminal Allenes

(2017) Shaista Parveen et al.   ORGANIC LETTERS

Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes

(2016) Philipp Koschker et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Rhodium-Catalyzed Atom-Economical Macrolactonization

(2016) Stephanie Ganss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers

(2016) Zi Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Diastereoselective Cyclization of Allenyl-Sulfonylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives

(2016) Pierre A. Spreider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent and Protecting-Group-Free Synthesis of the Helicascolide Family: A Rhodium-Catalyzed Atom-Economical Lactonization Strategy

(2016) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies

(2016) Alexander M. Haydl et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective Rhodium-Catalyzed Addition of β-Keto Esters, β-Keto Amides, and 1,3-Diketones to Internal Alkynes

(2016) Thorsten M. Beck et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Macrodiolide Formation by the Thioesterase of a Modular Polyketide Synthase

(2015) Yongjun Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Self-Assembly of Disorazole C1through a One-Pot Alkyne Metathesis Homodimerization Strategy

(2015) Kevin J. Ralston et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iterative Mechanism of Macrodiolide Formation in the Anticancer Compound Conglobatin

(2015) Yongjun Zhou et al.   CHEMISTRY & BIOLOGY

Specific Optical Rotations and the Horeau Effect

(2015) Cody L. Covington et al.   CHIRALITY

Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2015) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lessons from the Synthetic Chemist Nature

(2015) Gerrit Jürjens et al.   NATURAL PRODUCT REPORTS

Total Synthesis of Marinomycin A Based on a Direct Dimerization Strategy

(2014) Tatsuya Nishimaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (18S)- and (18R)-Homolargazole by Rhodium-Catalyzed Hydrocarboxylation

(2014) Christoph Schotes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1

(2014) Alexander W. H. Speed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward the ideal synthesis and molecular function through synthesis-informed design

(2014) Paul A. Wender   NATURAL PRODUCT REPORTS

Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation

(2013) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Antimalarial 20-membered macrolides from Streptomyces sp. BCC33756

(2013) Aibrohim Dramae et al.   TETRAHEDRON

Asymmetric Catalytic Alkynylation of Acetaldehyde: Application to the Synthesis of (+)-Tetrahydropyrenophorol

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Update 1 of: Macrolactonizations in the Total Synthesis of Natural Products

(2012) A. Parenty et al.   CHEMICAL REVIEWS

Total synthesis of marinomycin A using salicylate as a molecular switch to mediate dimerization

(2012) P. Andrew Evans et al.   Nature Chemistry

Macrocycles Are Great Cycles: Applications, Opportunities, and Challenges of Synthetic Macrocycles in Drug Discovery

(2011) Eric Marsault et al.   JOURNAL OF MEDICINAL CHEMISTRY

Total Synthesis of the Cyanolide A Aglycon

(2011) Michael R. Gesinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

(2011) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

(2011) Alexandre Lumbroso et al.   Chemical Science

Naturally Occurring Dimers from Chemical Perspective

(2010) Gaoyan Lian et al.   CHEMISTRY & BIODIVERSITY

Aiming for the Ideal Synthesis

(2010) Tanja Gaich et al.   JOURNAL OF ORGANIC CHEMISTRY

Redox Economy in Organic Synthesis

(2009) Noah Z. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation, biology and chemistry of the disorazoles: new anti-cancer macrodiolides

(2009) Chad D. Hopkins et al.   NATURAL PRODUCT REPORTS

Synthesis at the molecular frontier

(2009) Paul A. Wender et al.   NATURE

Stereoselective total synthesis of (−)-pyrenophorol

(2009) J.S. Yadav et al.   TETRAHEDRON LETTERS

Enantiospecific Total Synthesis of the Hapalindoles, Fischerindoles, and Welwitindolinonesviaa Redox Economic Approach

(2008) Jeremy M. Richter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The exploration of macrocycles for drug discovery — an underexploited structural class

(2008) Edward M. Driggers et al.   NATURE REVIEWS DRUG DISCOVERY