Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification

Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

(2015) Adrian B. Pritzius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Self-Assembly of Disorazole C1through a One-Pot Alkyne Metathesis Homodimerization Strategy

(2015) Kevin J. Ralston et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Marinomycin A Based on a Direct Dimerization Strategy

(2014) Tatsuya Nishimaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes

(2014) Changkun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unlocking theN2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (18S)- and (18R)-Homolargazole by Rhodium-Catalyzed Hydrocarboxylation

(2014) Christoph Schotes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers

(2014) Changkun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1

(2014) Alexander W. H. Speed et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Cyanolide A in the Absence of Protecting Groups, Chiral Auxiliaries, or Premetalated Carbon Nucleophiles

(2013) Andrew R. Waldeck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of Highly Substituted Tetrahydropyranones: Application to the Total Synthesis of Cyanolide A

(2013) Gidget C. Tay et al.   ORGANIC LETTERS

Asymmetric Catalytic Alkynylation of Acetaldehyde: Application to the Synthesis of (+)-Tetrahydropyrenophorol

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes

(2012) Michael L. Cooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concise Synthetic Approaches for the Laurencia Family: Formal Total Syntheses of (±)-Laurefucin and (±)-E- and (±)-Z-Pinnatifidenyne

(2012) Scott A. Snyder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total synthesis of marinomycin A using salicylate as a molecular switch to mediate dimerization

(2012) P. Andrew Evans et al.   Nature Chemistry

Cyclopropane Compatibility with Oxidative Carbocation Formation: Total Synthesis of Clavosolide A

(2012) GuangRong Peh et al.   ORGANIC LETTERS

From Total Synthesis to Diverted Total Synthesis: Case Studies in the Amphidinolide Series

(2011) Alois Fürstner   ISRAEL JOURNAL OF CHEMISTRY

Macrocycles Are Great Cycles: Applications, Opportunities, and Challenges of Synthetic Macrocycles in Drug Discovery

(2011) Eric Marsault et al.   JOURNAL OF MEDICINAL CHEMISTRY

Formal Total Synthesis of Cyanolide A

(2011) Srihari Pabbaraja et al.   JOURNAL OF ORGANIC CHEMISTRY

A Formal Synthesis of (−)-Cyanolide A Featuring a Stereoselective Mukaiyama Aldol Reaction and Oxocarbenium Reduction

(2011) Robert J. Sharpe et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of the Cyanolide A Aglycon

(2011) Michael R. Gesinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

(2011) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalysed direct C–C coupling of methanol and allenes

(2011) Joseph Moran et al.   Nature Chemistry

Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

(2011) Alexandre Lumbroso et al.   Chemical Science

On the Reach of Chemical Synthesis: Creation of a Mini-Pipeline from an Academic Laboratory

(2010) Rebecca M. Wilson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Probing the Biology of Natural Products: Molecular Editing by Diverted Total Synthesis

(2010) Alex M. Szpilman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Naturally Occurring Dimers from Chemical Perspective

(2010) Gaoyan Lian et al.   CHEMISTRY & BIODIVERSITY

Cyanolide A, a Glycosidic Macrolide with Potent Molluscicidal Activity from the Papua New Guinea CyanobacteriumLyngbya bouillonii

(2010) Alban R. Pereira et al.   JOURNAL OF NATURAL PRODUCTS

Synthesis of Molluscicidal Agent Cyanolide A Macrolactone fromd-(−)-Pantolactone

(2010) Atul K. Hajare et al.   JOURNAL OF ORGANIC CHEMISTRY

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2Catalyst System: Insights into the Effect of Naphthoquinone

(2010) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total synthesis of cyanolide A

(2010) Zhen Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Total Synthesis of Cyanolide A and Confirmation of Its Absolute Configuration

(2010) Hyoungsu Kim et al.   ORGANIC LETTERS

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

(2009) Takahiro Kawamoto et al.   CHEMICAL COMMUNICATIONS

Water Overcomes Methyl Group Directing Effects in Epoxide-Opening Cascades

(2009) Christopher J. Morten et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates

(2009) Derek C. Vrieze et al.   ORGANIC LETTERS

An Efficient Formal Synthesis of (−)-Clavosolide A Featuring a “Mismatched” Stereoselective Oxocarbenium Reduction

(2009) Jesse D. Carrick et al.   ORGANIC LETTERS

Synthesis and Biological Activity of Largazole and Derivatives

(2008) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The exploration of macrocycles for drug discovery — an underexploited structural class

(2008) Edward M. Driggers et al.   NATURE REVIEWS DRUG DISCOVERY

Iridium-Catalyzed Hydrocarboxylation of 1,1-Dimethylallene:  Byproduct-Free Reverse Prenylation of Carboxylic Acids

(2008) In Su Kim et al.   ORGANIC LETTERS

Total Synthesis of the Marine Metabolite (−)-Clavosolide D

(2008) Peter T. Seden et al.   ORGANIC LETTERS

Total synthesis of clavosolide A

(2008) Tushar Kanti Chakraborty et al.   TETRAHEDRON

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION