Palladium-Catalyzed C−H Silylation through Palladacycles Generated from Aryl Halides

Ruthenium-Catalyzed Site-Selective Intramolecular Silylation of Primary C–H Bonds for Synthesis of Sila-Heterocycles

(2017) Huaquan Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Z-Vinylsilanes via Palladium-Catalyzed Direct Intermolecular Silylation of C(sp2)–H Bonds

(2017) Jin-Long Pan et al.   ORGANIC LETTERS

Palladium-Catalyzed Remote meta-Selective C–H Bond Silylation and Germanylation

(2017) Atanu Modak et al.   ORGANOMETALLICS

Palladium-Catalyzed Formal [4 + 1] Annulation via Metal Carbene Migratory Insertion and C(sp2)–H Bond Functionalization

(2017) Shuai Xu et al.   ACS Catalysis

Experimental and Computational Studies on Remote γ-C(sp3)–H Silylation and Germanylation of Aliphatic Carboxamides

(2017) Arghya Deb et al.   ACS Catalysis

Trapping σ-Alkyl-Palladium(II) Intermediates with Arynes Encompassing Intramolecular C−H Activation: Spirobiaryls through Pd-Catalyzed Cascade Reactions

(2016) Marta Pérez-Gómez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent and Stereoselective Synthesis of β-Silyl-α-Amino Acids through Palladium-Catalyzed Intermolecular Silylation of Unactivated Primary and Secondary C−H Bonds

(2016) Yue-Jin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed direct intermolecular silylation of remote unactivated C(sp3)–H bonds

(2016) Jin-Long Pan et al.   CHEMICAL COMMUNICATIONS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed C(sp3)–H Functionalization/Carbenoid Insertion: All-Carbon Quaternary Centers via Multiple C–C Bond Formation

(2016) Álvaro Gutiérrez-Bonet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borylation of Olefin C–H Bond via Aryl to Vinyl Palladium 1,4-Migration

(2016) Tian-Jiao Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote C−H alkylation and C−C bond cleavage enabled by an in situ generated palladacycle

(2016) Juntao Ye et al.   Nature Chemistry

An Approach to Tetraphenylenes via Pd-Catalyzed C–H Functionalization

(2016) Hang Jiang et al.   ORGANIC LETTERS

Sequential Difunctionalization of 2-Iodobiphenyls by Exploiting the Reactivities of a Palladacycle and an Acyclic Arylpalladium Species

(2016) Dushen Chen et al.   ORGANIC LETTERS

Synthesis of Fluorenes Starting from 2-Iodobiphenyls and CH2Br2 through Palladium-Catalyzed Dual C–C Bond Formation

(2016) Guangfa Shi et al.   ORGANIC LETTERS

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bulky End-Capped [1]Benzothieno[3,2-b]benzothiophenes: Reaching High-Mobility Organic Semiconductors by Fine Tuning of the Crystalline Solid-State Order

(2015) Guillaume Schweicher et al.   ADVANCED MATERIALS

Rhodium-Catalyzed Enantioselective Intramolecular CH Silylation for the Syntheses of Planar-Chiral Metallocene Siloles

(2015) Qing-Wei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Recent Advances in First-Row-Transition-Metal-Catalyzed Dehydrogenative Cou­pling of C(sp3)-H Bonds

(2015) Jinmin Miao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Intramolecular C–N Bond Cleavage, 1,4-Migration, sp3 C–H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Desilylative Acyloxylation of Silicon–Carbon Bonds on (Trimethylsilyl)arenes: Synthesis of Phenol Derivatives from Trimethylsilylarenes

(2015) Keisuke Gondo et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxalyl Amide Directed Silylation and Germanylation of Amine Derivatives

(2015) Changpeng Chen et al.   ORGANIC LETTERS

Carbon–hydrogen (C–H) bond activation at PdIV: a Frontier in C–H functionalization catalysis

(2015) Joseph J. Topczewski et al.   Chemical Science

Cobalt-Catalyzed C–H Activation

(2015) Marc Moselage et al.   ACS Catalysis

Palladium-Catalysed, Directed CH Coupling with Organometallics

(2014) Ramesh Giri et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed C(sp3)H Activation: A Facile Method for the Synthesis of 3,4-Dihydroquinolinone Derivatives

(2014) Jia-Xuan Yan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Heck Reaction/CH Activation/Amination Sequence with Diaziridinone: A Facile Approach to Indolines

(2014) Huaiji Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arene C–H functionalisation using a removable/modifiable or a traceless directing group strategy

(2014) Fengzhi Zhang et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C–H Bond Arylation

(2014) De-Wei Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intramolecular Asymmetric C–H Functionalization/Cyclization Reaction of Metallocenes: An Efficient Approach toward the Synthesis of Planar Chiral Metallocene Compounds

(2014) Ruixian Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of 1-alkenes into 1,4-diols through an auxiliary-mediated formal homoallylic C–H oxidation

(2014) Nugzar Ghavtadze et al.   Nature Chemistry

Palladium-Catalyzed Direct C–H Silylation and Germanylation of Benzamides and Carboxamides

(2014) Kyalo Stephen Kanyiva et al.   ORGANIC LETTERS

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Palladium-Catalyzed Through-Space C(sp3)H and C(sp2)H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles

(2013) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SYNTHESIS AND REACTIONS OF SILICON-BRIDGED DITHIENYLBIPHENYLS. FINE TUNING OF ELECTRONIC STATES BY BRIDGING SILICON CHAIN LENGTHS

(2012) Joji Ohshita et al.   HETEROCYCLES

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Removable Directing Groups in Organic Synthesis and Catalysis

(2011) Géraldine Rousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Hydrometalation and Bismetalation of Biphenylene

(2011) Takanori Matsuda et al.   ORGANOMETALLICS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds

(2010) Tomonari Ureshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Palladium-Catalyzed Alkane C−H Arylation from Aryl Chlorides

(2010) Sophie Rousseaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters

(2009) Martin���R. Albicker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of pentacyclic structures by a domino sequence on cyclic enamides

(2009) Gedu Satyanarayana et al.   CHEMICAL COMMUNICATIONS

Synthesis and applications of silicon-containing α-amino acids

(2009) Matthew Mortensen et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Tandem Heck Reaction/CH Functionalization—Preparation of Spiro-Indane-Oxindoles

(2008) Rebecca T. Ruck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Iridium-Catalyzed CH Functionalization/Silylation of Heteroarenes

(2008) Biao Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Annulation of Acyloximes with Arynes (or Alkynes): Synthesis of Phenanthridines and Isoquinolines

(2008) Thibaud Gerfaud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Disilane- and siloxane-bridged biphenyl and bithiophene derivatives as electron-transporting materials in OLEDs

(2008) Hiroyuki Kai et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study

(2008) Manon Chaumontet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY