Trapping σ-Alkyl-Palladium(II) Intermediates with Arynes Encompassing Intramolecular C−H Activation: Spirobiaryls through Pd-Catalyzed Cascade Reactions

2-Arylacetamides as Versatile Precursors for 3-Aminoisocoumarin and Homophthalimide Derivatives: Palladium-Catalyzed Cascade Double Carbonylation Reactions

(2016) Roberto Frutos-Pedreño et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Diversely Functionalized Oxindoles Enabled by Migratory Insertion of Isocyanide to a Transient σ-Alkylpalladium(II) Complex

(2016) Wangqing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce-Smiles Rearrangement

(2016) Catherine M. Holden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Domino Heck/Intermolecular C–H Bond Functionalization: Efficient Synthesis of Alkylated Polyfluoroarene Derivatives

(2016) Xin-Xing Wu et al.   ORGANIC LETTERS

Double Heteroatom Functionalization of Arenes Using Benzyne Three-Component Coupling

(2015) José-Antonio García-López et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Orchestrated Triple CH Activation Reactions Using Two Directing Groups: Rapid Assembly of Complex Pyrazoles

(2015) Weibo Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Domino Heck/borylation sequence towards indolinone-3-methyl boronic esters: trapping of the σ-alkylpalladium intermediate with boron

(2015) Dipak D. Vachhani et al.   CHEMICAL COMMUNICATIONS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Highly Regio- and Stereoselective Formation of C–C Double Bonds: An Efficient Method for the Synthesis of Benzofuran-, Dihydrobenzofuran-, and Indoline-Containing Alkenes

(2015) Yang Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Domino Aryne Precursor: Efficient Construction of 2,4-Disubstituted Benzothiazoles

(2015) Jiarong Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Enantioselective Domino Heck/Intermolecular C–H Bond Functionalization: Development and Application to the Synthesis of (+)-Esermethole

(2015) Wangqing Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Cascade CH Functionalization of Phenylacetophenones

(2014) Vaibhav P. Mehta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Biocatalytic Repertoire of Natural Biaryl Formation

(2014) Hülya Aldemir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Heck Reaction/CH Activation/Amination Sequence with Diaziridinone: A Facile Approach to Indolines

(2014) Huaiji Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkylation of Terminal Alkynes with Transient σ-Alkylpalladium(II) Complexes: A Carboalkynylation Route to Alkyl-Substituted Alkynes

(2014) Ming-Bo Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Role of Aryne Distortions, Steric Effects, and Charges in Regioselectivities of Aryne Reactions

(2014) Jose M. Medina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Use of 2-Bromophenylboronic Esters as Benzyne Precursors in the Pd-Catalyzed Synthesis of Triphenylenes

(2014) José-Antonio García-López et al.   ORGANIC LETTERS

Diastereoselective Palladium-Catalyzed Arylcyanation/Heteroarylcyanation of Enantioenriched N-Allylcarboxamides

(2014) Hyung Yoon et al.   ORGANIC LETTERS

Pd-Catalyzed Dehydrogenative Aryl–Aryl Bond Formation via Double C(sp2)–H Bond Activation: Efficient Synthesis of [3,4]-Fused Oxindoles

(2014) Ala Bunescu et al.   ORGANIC LETTERS

Insertion Reactions on Carbopalladated Benzyne: From Eight- to Nine- and Ten-Membered Palladacycles. Applications to the Synthesis of N-Heterocycles

(2014) María-José Oliva-Madrid et al.   ORGANOMETALLICS

Palladium-Catalyzed Through-Space C(sp3)H and C(sp2)H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles

(2013) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Cascade Crossover Annulation of o-Alkynylarylhalides and Diarylacetylenes Leading to Dibenzo[a,e]pentalenes

(2013) Jian Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Heck-Type Cascade Reactions with N-Tosyl Hydrazones: An Efficient Way to Alkenes via in Situ Generated Alkylpalladium

(2013) Xianglei Liu et al.   ORGANIC LETTERS

Domino Carbopalladation-Carbonylation: Investigation of Substrate Scope

(2012) Brinton Seashore-Ludlow et al.   ADVANCED SYNTHESIS & CATALYSIS

Activation of a C(sp3)H Bond by a Transient σ-Alkylpalladium(II) Complex: Synthesis of Spirooxindoles Through a Palladium-Catalyzed Domino Carbopalladation/C(sp3)C(sp3) Bond-Forming Process

(2012) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion of benzyne into the Pd–C bond. Synthesis of unnatural amino acid derivatives by sequential insertion of benzyne and CO: 2,2′-functionalized biaryls containing alkylamino and carboxymethyl substituents. Isolation of stable carbopalladated-benzyne intermediates

(2012) José-Antonio García-López et al.   CHEMICAL COMMUNICATIONS

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

Use of benzynes for the synthesis of heterocycles

(2012) Anton V. Dubrovskiy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Domino Carbopalladation–Cross-Coupling for the Synthesis of 3,3-Disubstituted Oxindoles

(2012) Brinton Seashore-Ludlow et al.   ORGANIC LETTERS

A Model Study for Constructing the DEF-Benzoxocin Ring System of Menogaril and Nogalamycin via a Reductive Heck Cyclization

(2012) Ruogu Peng et al.   ORGANIC LETTERS

Spirocyclization by Palladium-Catalyzed Domino Heck–Direct C–H Arylation Reactions: Synthesis of Spirodihydroquinolin-2-ones

(2012) Tiffany Piou et al.   ORGANIC LETTERS

Unique properties of chiral biaryl-based secondary aminecatalysts for asymmetric enamine catalysis

(2012) Taichi Kano et al.   Chemical Science

Palladium-Catalyzed Carboiodination of Alkenes: Carbon−Carbon Bond Formation with Retention of Reactive Functionality

(2011) Stephen G. Newman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Carbohalogenation: Bromide to Iodide Exchange and Domino Processes

(2011) Stephen G. Newman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of a Tetracyclic Butterfly-Like Scaffold: Palladium-Catalyzed Heck/Arylation Cascade

(2010) Ko Hoon Kim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Domino Process to Spirooxindoles: Ligand Effect on Aminopalladation versus Carbopalladation

(2010) Stéphanie Jaegli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-catalyzed domino Heck/cyanation: synthesis of 3-cyanomethyloxindoles and their conversion to spirooxoindoles

(2010) Stéphanie Jaegli et al.   TETRAHEDRON

Formation of pentacyclic structures by a domino sequence on cyclic enamides

(2009) Gedu Satyanarayana et al.   CHEMICAL COMMUNICATIONS

Theoretical aspects of palladium-catalysed carbon–carbon cross-coupling reactions

(2009) Liqin Xue et al.   CHEMICAL SOCIETY REVIEWS

Domino Palladium-Catalyzed Heck-Intermolecular Direct Arylation Reactions

(2009) Olivier René et al.   ORGANIC LETTERS

Water-Controlled Regioselectivity of Pd-Catalyzed Domino Reaction Involving a C−H Activation Process: Rapid Synthesis of Diverse Carbo- and Heterocyclic Skeletons

(2009) Zhiyao Lu et al.   ORGANIC LETTERS

Palladium-Catalyzed Tandem Heck Reaction/CH Functionalization—Preparation of Spiro-Indane-Oxindoles

(2008) Rebecca T. Ruck et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 6-oxacyclopropa[a]indene derivatives starting from Baylis–Hillman adducts via Pd-mediated C(sp3)–H activation

(2008) Hoo Sook Kim et al.   TETRAHEDRON LETTERS