Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Palladium(I) Catalyst

Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed

(2015) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf-StableN-(trifluoromethylthio)phthalimide

(2014) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 toiv

(2014) Karl J. Bonney et al.   CHEMICAL SOCIETY REVIEWS

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Kinetic and Computational Studies on Pd(I) Dimer-Mediated Halogen Exchange of Aryl Iodides

(2014) Indrek Kalvet et al.   JOURNAL OF ORGANIC CHEMISTRY

Insight into the Efficiency of Cinnamyl-Supported Precatalysts for the Suzuki–Miyaura Reaction: Observation of Pd(I) Dimers with Bridging Allyl Ligands During Catalysis

(2014) Damian P. Hruszkewycz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Trifluoromethylthiolation of Aryl Halides with Diverse Directing Groups

(2014) Jiabin Xu et al.   ORGANIC LETTERS

Palladium-Catalyzed Trifluoromethylthiolation of Aryl C–H Bonds

(2014) Chunfa Xu et al.   ORGANIC LETTERS

NMR Studies of the Species Present in Cross-Coupling Catalysis Systems Involving Pd(η3-1-Ph-C3H4)(η5-C5H5) and [Pd(η3-1-Ph-C3H4)Cl]2 Activated by PBut3, XPhos, and Mor-Dalphos: Nonexistence of Pd(XPhos)n and Pd(Mor-Dalphos)n (n = 1, 2) at Moderate Temperatures

(2014) Sogol Borjian et al.   ORGANOMETALLICS

Well-Defined BisMETAMORPhos PdI–PdI Complex: Synthesis, Structural Characterization, and Reactivity

(2014) Sander Oldenhof et al.   ORGANOMETALLICS

Combining the Reactivity Properties of PCy3 and PtBu3 into a Single Ligand, P(iPr)(tBu)2. Reaction via Mono- or Bisphosphine Palladium(0) Centers and Palladium(I) Dimer Formation

(2014) Fabien Proutiere et al.   ORGANOMETALLICS

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

(2014) Grégory Danoun et al.   Chemical Science

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation

(2013) Grégory Landelle et al.   Beilstein Journal of Organic Chemistry

Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules

(2013) Sibo Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinuclear Pd(i) complexes—solely precatalysts? Demonstration of direct reactivity of a Pd(i) dimer with an aryl iodide

(2013) Karl J. Bonney et al.   Chemical Science

Redox Reactions in Palladium Catalysis: On the Accelerating and/or Inhibiting Effects of Copper and Silver Salt Additives in Cross-Coupling Chemistry Involving Electron-rich Phosphine Ligands

(2012) Marialuisa Aufiero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinuclear Palladium Complexes-Precursors or Catalysts?

(2012) Robert S. Paton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

(2012) Zhiqiang Weng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Studies on the Amination of Aryl Chlorides with a Monoligated Palladium Catalyst: Kinetic Evidence for a Cooperative Mechanism

(2012) Ciril Jimeno et al.   CHEMISTRY-A EUROPEAN JOURNAL

[Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling

(2012) Anthony Chartoire et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Trifluoromethylthiolations of Aryl Boronic Acids Using a Copper/O2-Based Protocol

(2012) Cheng-Pan Zhang et al.   Chemistry-An Asian Journal

[Pd(μ-Br)(PtBu3)]2 as a Highly Active Isomerization Catalyst: Synthesis of Enol Esters from Allylic Esters

(2012) Patrizia Mamone et al.   ORGANIC LETTERS

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of the Bis(dialkylphosphino)methane Complexes Pd2X2(μ-R2PCH2PR2)2(X = halogen, R = Me or Et) with H2S, S8, COS, and CS2; Detection of Reaction Intermediates

(2011) Craig B. Pamplin et al.   INORGANIC CHEMISTRY

Reactivity and Stability of Dinuclear Pd(I) Complexes: Studies on the Active Catalytic Species, Insights into Precatalyst Activation and Deactivation, and Application in Highly Selective Cross-Coupling Reactions

(2011) Fabien Proutiere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Pd(I)−Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium

(2011) Rafael Huacuja et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Dinuclear Addition of a PdI–PdIMoiety to Arenes: Generation of μ-η3:η3-Arene-PdII2Species

(2011) Tetsuro Murahashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(I)-Bridging Allyl Dimers for the Catalytic Functionalization of CO2

(2011) Damian P. Hruszkewycz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and X-ray Structure Determination of Highly Active Pd(II), Pd(I), and Pd(0) Complexes of Di(tert-butyl)neopentylphosphine (DTBNpP) in the Arylation of Amines and Ketones

(2010) Lensey L. Hill et al.   JOURNAL OF ORGANIC CHEMISTRY

Final Analysis: The Use of Metal Scavengers for Recovery of Palladium Catalyst from Solution

(2010) Stephanie Phillips et al.  

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

A Highly Active Palladium(I) Dimer for Pharmaceutical Applications

(2009) Thomas J. Colacot  

ElectrophilicS-Trifluoromethylation of Cysteine Side Chains inα- andβ-Peptides: Isolation of Trifluoro-methylatedSandostatin®(Octreotide) Derivatives

(2008) Stefania Capone et al.   HELVETICA CHIMICA ACTA

Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols

(2008) Kyrill Stanek et al.   JOURNAL OF ORGANIC CHEMISTRY