Recent progress toward organophosphorus compounds based on phosphorus-centered radical difunctionalizations

Copper-Catalyzed Cycloaddition between Secondary Phosphine Oxides and Alkynes: Synthesis of Benzophosphole Oxides

(2016) Pengbo Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes

(2016) Jingjing Zhao et al.   CHEMICAL COMMUNICATIONS

K2S2O8-mediated metal-free direct P–H/C–H functionalization: a convenient route to benzo[b]phosphole oxides from unactivated alkynes

(2016) Dumei Ma et al.   GREEN CHEMISTRY

Silver-Catalyzed Cascade Radical Cyclization: A Direct Approach to 3,4-Disubstituted Dihydroquinolin-2(1H)-ones through Activation of the P–H Bond and Functionalization of the C(sp2)–H Bond

(2016) Honglin Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free, Visible Light-Photocatalyzed Synthesis of Benzo[b]phosphole Oxides: Synthetic and Mechanistic Investigations

(2016) Valentin Quint et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-promoted cinnamamidyl radical-mediated oxidative cascade cyclization: highly regioselective synthesis of phosphorylated azaspiro[4.5]decenones

(2016) Zhao-Zhao Zhou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cascade Phosphinoylation/Cyclization/Isomerization Process for the Synthesis of 2-Phosphinoyl-9H-pyrrolo[1,2-a]indoles

(2016) Su Chen et al.   ORGANIC LETTERS

A Cascade Phosphinoylation/Cyclization/Desulfonylation Process for the Synthesis of 3-Phosphinoylindoles

(2016) Yuzhen Gao et al.   ORGANIC LETTERS

Silver(I)-Mediated Phosphorylation/Cyclization Cascade of N-Cyanamide Alkenes for Divergent Access to Quinazolinones and Dihydroisoquinolinones

(2016) Jing Zheng et al.   ORGANIC LETTERS

Visible-Light-Induced Cascade Reaction of Isocyanides and N-Arylacrylamides with Diphenylphosphine Oxide via Radical C–P and C–C Bond Formation

(2016) Chun-Xiao Li et al.   ORGANIC LETTERS

Copper-catalyzed cycloaddition between hydrogen phosphonates and activated alkenes: synthesis of phosphonoisoquinolinediones

(2016) Ju Wu et al.   RSC Advances

A one-pot strategy to synthesize β-ketophosphonates: silver/copper catalyzed direct oxyphosphorylation of alkynes with H-phosphonates and oxygen in the air

(2015) Xin Chen et al.   CHEMICAL COMMUNICATIONS

Mn(OAc)3-mediated phosphonation–lactonization of alkenoic acids: synthesis of phosphono-γ-butyrolactones

(2015) Yuzhen Gao et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed tandem phosphination–decarboxylation–oxidation of alkynyl acids with H-phosphine oxides: a facile synthesis of β-ketophosphine oxides

(2015) Pengbo Zhang et al.   CHEMICAL COMMUNICATIONS

Mn(iii)-mediated phosphonation–azidation of alkenes: a facile synthesis of β-azidophosphonates

(2015) Jian Xu et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Phosphonation–Annulation Approaches to the Synthesis of β-Phosphonotetrahydrofurans Involving C–P and C–O Bonds Formation

(2015) Yuzhen Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper/Iron-Catalyzed Aerobic Oxyphosphorylation of Terminal Alkynes Leading to β-Ketophosphonates

(2015) Niannian Yi et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-catalyzed cascade addition/cyclization: highly efficient access to phosphonylated quinoline-2,4(1H,3H)-diones

(2015) Ya-Min Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides

(2015) Gaobo Hu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Silver-Catalyzed Oxidative Cyclization of Propargylamide-Substituted Indoles: Synthesis of Phosphorated Indoloazepinones Derivatives

(2015) Hui-Liang Hua et al.   ORGANIC LETTERS

β-Ketophosphonate Formation via Aerobic Oxyphosphorylation of Alkynes or Alkynyl Carboxylic Acids with H-Phosphonates

(2015) Mingxin Zhou et al.   ORGANIC LETTERS

Metal-free direct difunctionalization of alkenes with I2O5 and P(O)–H compounds leading to β-iodophosphates

(2015) Chunli Liu et al.   Organic Chemistry Frontiers

Silver-Promoted P-radical Cyclization Reaction with the Addition to Isonitrile

(2015) Bin Yang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Silver-catalyzed carbon–phosphorus functionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization: access to phosphorylated aza-decenones

(2014) Li-Jing Wang et al.   CHEMICAL COMMUNICATIONS

Peroxides as “Switches” of Dialkyl H-Phosphonate: Two Mild and Metal-Free Methods for Preparation of 2-Acylbenzothiazoles and Dialkyl Benzothiazol-2-ylphosphonates

(2014) Xiao-Lan Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese(III)-Mediated Selective Diphenylphosphinoyl Radical Reaction of 1,4-Diaryl-1-butynes for the Synthesis of 2-Phosphinoylated 3,4-Dihydronaphathalenes

(2014) Da-Peng Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives

(2014) Zhao-Zhao Zhou et al.   ORGANIC LETTERS

Silver-Catalyzed Synthesis of 3-Phosphorated Coumarins via Radical Cyclization of Alkynoates and Dialkyl H-Phosphonates

(2014) Xia Mi et al.   ORGANIC LETTERS

Copper(I) Iodide Mediated Synthesis of Carbohydrate-Based Terminal Allenes by ATA Reaction

(2014) Shengming Ma et al.   SYNTHESIS-STUTTGART

Metal-free oxidative arylphosphination of activated N-substituted-N-arylacrylamide derivatives using K2S2O8

(2014) Ya-Min Li et al.   TETRAHEDRON

Silver-catalyzed 2-isocyanobiaryls insertion/cyclization with phosphine oxides: synthesis of 6-phosphorylated phenanthridines

(2014) Jia-Jia Cao et al.   TETRAHEDRON

Synthesis of phenanthridin-6-yldiphenylphosphine oxides by oxidative cyclization of 2-isocyanobiphenyls with diarylphosphine oxides

(2014) Yuewen Li et al.   TETRAHEDRON

Mn(OAc)3-mediated synthesis of β-hydroxyphosphonates from P(O)–H compounds and alkenes

(2014) Yuzhen Gao et al.   RSC Advances

Synthesis of 6-Phenanthridinephosphonates via a Radical Phosphonation and Cyclization Process Mediated by Manganese(III) Acetate

(2014) Yuzhen Gao et al.   Asian Journal of Organic Chemistry

An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving CC and CP Bond Formation

(2013) Yuto Unoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Annulations toward Phosphorylated Oxindoles: Silver-Catalyzed Carbon-Phosphorus Functionalization of Alkenes

(2013) Ya-Min Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel regio- and stereoselective phosphonyl radical addition to glycals promoted by Mn(ii)–air: syntheses of 1,2-dideoxy 2-C-diphenylphosphinylglycopyranosides

(2013) Fuyi Zhang et al.   CHEMICAL COMMUNICATIONS

Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides

(2013) Yun-Rong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Radical Phosphonofluorination of Unactivated Alkenes

(2013) Chengwei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

6-Phosphorylated Phenanthridines from 2-Isocyanobiphenyls via Radical C–P and C–C Bond Formation

(2013) Bo Zhang et al.   ORGANIC LETTERS

Preparation of 5-Membered Rings via Radical Addition- Translocation-Cyclization (RATC) Processes Mediated by Diethyl Thiophosphites

(2011) Christophe Lamarque et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates

(2011) Wei Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese(iii)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

(2011) Xiang-Qiang Pan et al.   CHEMICAL COMMUNICATIONS

Review on Modern Advances of Chemical Methods for the Introduction of a Phosphonic Acid Group

(2011) Charles S. Demmer et al.   CHEMICAL REVIEWS

Synthesis of Phosphonylated and Thiolated Indenones by Manganese(III)-Mediated Addition of Phosphorus- and Sulfur-Centered Radicals to 1,3-Diarylpropynones

(2011) Jun Zhou et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of β-hydroxyphosphonates by iron-catalyzed oxidative addition of phosphonyl radicals to alkenes

(2011) Tsuyoshi Taniguchi et al.   TETRAHEDRON LETTERS