Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications

Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands

(2017) Yuki Toya et al.   ORGANOMETALLICS

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

(2017) Zheng Yang et al.   Organic Chemistry Frontiers

Pincer cobalt complex-catalyzed Z-selective hydrosilylation of terminal alkynes

(2017) Xiaoyong Du et al.   Organic Chemistry Frontiers

Regio- and Enantioselective Cobalt-Catalyzed Sequential Hydrosilylation/Hydrogenation of Terminal Alkynes

(2016) Jun Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

(2016) Ziqing Zuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes

(2016) Jun Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Olefin Hydrosilylation Catalyzed by Iron Complexes with Iminobipyridine Ligand

(2016) Kazumasa Hayasaka et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

The cobalt(II) complex of a new tridentate Schiff-base ligand as a catalyst for hydrosilylation of olefins

(2016) Adam Gorczyński et al.   CATALYSIS COMMUNICATIONS

Dynamic Responsive Systems for Catalytic Function

(2016) Matea Vlatković et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Hydrosilylation/Cyclization of 1,6-Enynes

(2016) Tuo Xi et al.   JOURNAL OF ORGANIC CHEMISTRY

Bis(acetylacetonato)Ni(II)/NaBHEt3-catalyzed hydrosilylation of 1,3-dienes, alkenes and alkynes

(2016) Venu Srinivas et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

(2016) Daisuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Asymmetric Piers Hydrosilylation

(2016) Lars Süsse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Impressive Rate Raise of the Hydrosilation Reaction Through UV-Activation: Energy and Time Saving

(2016) Sophie Marchi et al.   MACROMOLECULAR MATERIALS AND ENGINEERING

Alkyl-functionalization of porous silicon via multimode microwave-assisted hydrosilylation

(2016) Jasper C. Small et al.   POLYHEDRON

Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)2Si(Me)H as a Stoichiometric Reductant

(2016) Balaram Raya et al.   ACS Catalysis

Hydrosilylation of Olefins Catalyzed by Well-Defined Cationic Aluminum Complexes: Lewis Acid versus Insertion Mechanisms

(2016) Kayla Jakobsson et al.   ACS Catalysis

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

(2016) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Synthesis of Triazolylidene Nickel Complexes and Their Catalytic Application in Selective Aldehyde Hydrosilylation

(2016) Yingfei Wei et al.   ACS Catalysis

Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts

(2016) Iraklis Pappas et al.   ACS Catalysis

Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation

(2016) Teresa K. Meister et al.   ACS Catalysis

Nickel and Iron Pincer Complexes as Catalysts for the Reduction of Carbonyl Compounds

(2015) Sumit Chakraborty et al.   ACCOUNTS OF CHEMICAL RESEARCH

Majority-Rules-Type Helical Poly(quinoxaline-2,3-diyl)s as Highly Efficient Chirality-Amplification Systems for Asymmetric Catalysis

(2015) Yuan-Zhen Ke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Silane-Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis

(2015) Jiawei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decatungstate-Photocatalyzed Si−H/C−H Activation in Silyl Hydrides: Hydrosilylation of Electron-Poor Alkenes

(2015) Hisham Qrareya et al.   ChemCatChem

Platinum nanoparticles in suspension are as efficient as Karstedt's complex for alkene hydrosilylation

(2015) Thomas Galeandro-Diamant et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed asymmetric hydrosilylation of ketones

(2015) Ziqing Zuo et al.   CHEMICAL COMMUNICATIONS

Artificial switchable catalysts

(2015) Victor Blanco et al.   CHEMICAL SOCIETY REVIEWS

Nanocontact printing stamp material via bi-functionalization of polyhedral oligomeric silsesquioxanes

(2015) Julia Kastner et al.   EUROPEAN POLYMER JOURNAL

Hydrosilylation vs. dehydrogenative silylation of styrene catalysed by iron(0) carbonyl complexes with multivinylsilicon ligands – Mechanistic implications

(2015) Bogdan Marciniec et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Visible light-activated hydrosilation reaction

(2015) S. Marchi et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

(2015) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Substrate Activation and Catalysis at an Intact Metal–Metal Bond Using a Redox-Active Supporting Ligand

(2015) Talia J. Steiman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Comparison of the Reactivity of Two Platinum Catalysts for Silicone Polymer Cross-Linking by UV-Activated Hydrosilation Reaction

(2015) Sophie Marchi et al.   Macromolecular Reaction Engineering

Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study

(2015) Sebastian Keess et al.   ORGANOMETALLICS

Combinatorial Approach to the Catalytic Hydrosilylation of Styrene Derivatives: Catalyst Systems Composed of Organoiron(0) or (II) Precursors and Isocyanides

(2015) Yusuke Sunada et al.   ORGANOMETALLICS

Imine Nitrogen Bridged Binuclear Nickel Complexes via N–H Bond Activation: Synthesis, Characterization, Unexpected C,N-Coupling Reaction, and Their Catalytic Application in Hydrosilylation of Aldehydes

(2015) Lin Wang et al.   ORGANOMETALLICS

Iron-Catalyzed Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions

(2015) Francis S. Wekesa et al.   ORGANOMETALLICS

UV-cured silicone composites obtained via hydrosilation andin-situgeneration of inorganic particles

(2015) Sophie Marchi et al.   POLYMER ENGINEERING AND SCIENCE

Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex

(2015) Toni T. Metsänen et al.   Chemical Science

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

(Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins

(2015) Venu Srinivas et al.   Catalysis Science & Technology

Synthesis of silicone elastomers containing trifluoropropyl groups and their use in dielectric elastomer transducers

(2015) Mihaela Dascalu et al.   RSC Advances

Precursor strategies for metallic nano- and micropatterns using soft lithography

(2015) F. M. Wisser et al.   Journal of Materials Chemistry C

Highly Transparent and Durable Superhydrophobic Hybrid Nanoporous Coatings Fabricated from Polysiloxane

(2014) Ding Wang et al.   ACS Applied Materials & Interfaces

Enantioselective Lewis-Base-Catalyzed Asymmetric Hydrosilylation of Substituted BenzophenoneN-Aryl Imines: Efficient Synthesis of Chiral (Diarylmethyl)amines

(2014) Xiao-Yan Hu et al.   ADVANCED SYNTHESIS & CATALYSIS

The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes)PFPh2][B(C6F5)4]2

(2014) Michael H. Holthausen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrosilylation cross-linking of silicon fluids by a novel class of iron(0) catalysts

(2014) Bogdan Marciniec et al.   APPLIED CATALYSIS A-GENERAL

(N-Phosphinoamidinate)cobalt-Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity

(2014) Adam J. Ruddy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amorphous silicon carbide films prepared using vaporized silicon ink

(2014) Takashi Masuda et al.   JAPANESE JOURNAL OF APPLIED PHYSICS

Electrochemical and Corrosion Stability of Nanostructured Silicon by Graphene Coatings: Toward High Power Porous Silicon Supercapacitors

(2014) Shahana Chatterjee et al.   Journal of Physical Chemistry C

Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes

(2014) Zhenbo Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Influence of carbon enrichment on electrical conductivity and processing of polycarbosilane derived ceramic for MEMS applications

(2014) Federico Dalcanale et al.   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

Substituent Effects on the Kinetics of Bifunctional Styrene SAM Formation on H-Terminated Si

(2014) Esther Frederick et al.   LANGMUIR

Modification of Silicone Elastomer with Zwitterionic Silane for Durable Antifouling Properties

(2014) Shiou-Bang Yeh et al.   LANGMUIR

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Silicone elastomers with high dielectric permittivity and high dielectric breakdown strength based on dipolar copolymers

(2014) Frederikke Bahrt Madsen et al.   POLYMER

Thermo and Dynamic Mechanical Properties of the High Refractive Index Silicone Resin for Light Emitting Diode Packaging

(2014) Dan Dan Li et al.   IEEE Transactions on Components Packaging and Manufacturing Technology

The synthesis and characterization of carboxybetaine functionalized polysiloxanes for the preparation of anti-fouling surfaces

(2014) Liujun Cheng et al.   RSC Advances

3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

(2013) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Hydrosilation of CO2to a Bis(silylacetal) Using an Anilido Bipyridyl-Ligated Organoscandium Catalyst

(2013) Francis A. LeBlanc et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrosilylation kinetics of silicon nanocrystals

(2013) Wei Sun et al.   CHEMICAL COMMUNICATIONS

Highly efficient catalytic hydrosilylation of carbon dioxide by an N-heterocyclic carbene copper catalyst

(2013) Liang Zhang et al.   CHEMICAL COMMUNICATIONS

The use of siloxanes, silsesquioxanes, and silicones in organic semiconducting materials

(2013) Brett A. Kamino et al.   CHEMICAL SOCIETY REVIEWS

Polymers for electronics and spintronics

(2013) Piotr Bujak et al.   CHEMICAL SOCIETY REVIEWS

Catalyst design for iron-promoted reductions: an iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H–Si) moieties

(2013) Yusuke Sunada et al.   DALTON TRANSACTIONS

A new approach to light-gated Pt catalysts for the hydrosilylation

(2013) Magnus R. Buchner et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cooperative Adsorption of Lipoprotein Phospholipids, Triglycerides, and Cholesteryl Esters Are a Key Factor in Nonspecific Adsorption from Blood Plasma to Antifouling Polymer Surfaces

(2013) Gesine Gunkel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Analysis of the Catalytic Cycle of the Borane-Promoted Imine Reduction with Hydrosilanes: Spectroscopic Detection of Unexpected Intermediates and a Refined Mechanism

(2013) Julia Hermeke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin Isomerization and Hydrosilylation Catalysis by Lewis Acidic Organofluorophosphonium Salts

(2013) Manuel Pérez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Semiconductor surface functionalization for advances in electronics, energy conversion, and dynamic systems

(2013) Andrew V. Teplyakov et al.   JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A

Functionalization of oxide-free silicon surfaces

(2013) William J. I. DeBenedetti et al.   JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A

Multifunctional Silicon Surfaces: Reaction of Dichlorocarbene Generated from Seyferth Reagent with Hydrogen-Terminated Silicon (111) Surfaces

(2013) Wenjun Liu et al.   LANGMUIR

UV-Induced Frontal Polymerization of a Pt-Catalyzed Hydrosilation Reaction

(2013) Marco Sangermano et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Silylium Ion Promoted Reduction of Imines with Hydrosilanes

(2013) Kristine Müther et al.   ORGANOMETALLICS

Preparation and characterization of PDMS composites by UV-hydrosilation for outdoor polymeric insulators

(2013) Sophie Marchi et al.   POLYMER COMPOSITES

New hybrid materials based on poly(ethyleneoxide)-grafted polysilazane by hydrosilylation and their anti-fouling activities

(2013) Thi Dieu Hang Nguyen et al.   Beilstein Journal of Nanotechnology

Efficient Reduction of Esters to Aldehydes through Iridium-Catalyzed Hydrosilylation

(2012) Chen Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Durable antimicrobial finishing of cellulose with QSA silicone by supercritical adsorption

(2012) Yong Chen et al.   APPLIED SURFACE SCIENCE

New approach to synthesis of functionalised silsesquioxanes via hydrosilylation

(2012) Hieronim Maciejewski et al.   CATALYSIS COMMUNICATIONS

Selective switchable iron-catalyzed hydrosilylation of carboxylic acids

(2012) Luis C. Misal Castro et al.   CHEMICAL COMMUNICATIONS

Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane

(2012) Marius Mewald et al.   CHEMISTRY-A EUROPEAN JOURNAL

UV-activated hydrosilation reaction for silicone polymer crosslinking

(2012) M. Sangermano et al.   JOURNAL OF APPLIED POLYMER SCIENCE

Antigraffiti polyurethane coating containing fluorocarbon side chains grafted polymethylsiloxane

(2012) Hu Liu et al.   Journal of Coatings Technology and Research

Enhancing the Efficiency of Multicrystalline Silicon Solar Cells by the Inkjet Printing of Silicon-Quantum-Dot Ink

(2012) Xiaodong Pi et al.   Journal of Physical Chemistry C

Poly(2-oxazoline)-derived Contact Biocides: Contributions to the Understanding of Antimicrobial Activity

(2012) Andrew M. Kelly et al.   MACROMOLECULAR BIOSCIENCE

Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging

(2012) Nan Gao et al.   OPTICAL MATERIALS

Copper-Catalyzed Formic Acid Synthesis from CO2 with Hydrosilanes and H2O

(2012) Ken Motokura et al.   ORGANIC LETTERS

Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

(2012) Kouji Kamata et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Closing the Organosilicon Synthetic Cycle: Efficient Heterogeneous Hydrosilylation of Alkenes over SiliaCat Pt(0)

(2012) Rosaria Ciriminna et al.   ACS Sustainable Chemistry & Engineering

N-Heterocyclic Carbene-Catalyzed Hydrosilylation of Styryl and Propargylic Alcohols with Dihydrosilanes

(2011) Qiwu Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Mild and Efficient Functionalization of Hydrogen-Terminated Si(111) via Sonochemical Activated Hydrosilylation

(2011) Yu Lin Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development and Mechanistic Investigation of a Highly Efficient Iridium(V) Silyl Complex for the Reduction of Tertiary Amides to Amines

(2011) Sehoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrosilylation on photoactivated catalysts

(2011) D. A. de Vekki   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

Artificial Light-Gated Catalyst Systems

(2010) Ragnar S. Stoll et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed hydrosilylation reactions

(2010) Ming Zhang et al.   APPLIED ORGANOMETALLIC CHEMISTRY

High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

(2010) Takeshi Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoswitchable Catalysis Mediated by Dynamic Aggregation of Nanoparticles

(2010) Yanhu Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Microcontact Printing: Limitations and Achievements

(2009) András Perl et al.   ADVANCED MATERIALS

UV‐activated hydrosilylation: a facile approach for synthesis of hyperbranched polycarbosilanes

(2009) Guo‐Bin Zhang et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Chemical Reactions on Surface Molecules Attached to Silicon Quantum Dots

(2009) Amane Shiohara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION