Carbene Complexes Based on Dilithium Methandiides

The Ketimide Ligand is Not Just an Inert Spectator: Heteroallene Insertion Reactivity of an Actinide-Ketimide Linkage in a Thorium Carbene Amide Ketimide Complex

(2014) Erli Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex

(2014) Erli Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methandiide as a Non-Innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis

(2014) Julia Becker et al.   CHEMISTRY-A EUROPEAN JOURNAL

Substitution Effects on the Formation of T-Shaped Palladium Carbene and Thioketone Complexes from Li/Cl Carbenoids

(2014) Sebastian Molitor et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of the uranium(iv) carbene complex [U(BIPMTMS)(Cl)(μ-Cl)2Li(THF)2] (BIPMTMS= {C(PPh2NSiMe3)2}) towards carbonyl and heteroallene substrates: metallo-Wittig, adduct formation, C–F bond activation, and [2 + 2]-cycloaddition reactions

(2014) Oliver J. Cooper et al.   DALTON TRANSACTIONS

Synthesis and stability of Li/Cl carbenoids based on bis(iminophosphoryl)methanes

(2014) Kai-Stephan Feichtner et al.   DALTON TRANSACTIONS

Synthesis and Electronic Structure of Carbene Complexes Based on a Sulfonyl-Substituted Dilithio Methandiide

(2014) Julia Becker et al.   ORGANOMETALLICS

The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

(2013) Oliver J. Cooper et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Bonding in Carbene Complexes of an Unsymmetrical Dilithio Methandiide: A Combined Experimental and Theoretical Study

(2013) Viktoria H. Gessner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Uranium carbene compounds

(2013) Michel Ephritikhine   COMPTES RENDUS CHIMIE

On the structure and ambiphilicity of a sulfonyl substituted α-chloro lithium base

(2013) Julia Becker et al.   DALTON TRANSACTIONS

Activation of X-H Bonds (X = N, P, O, S) with SCS Pincer Palladium Complexes: A Theoretical Study

(2013) Emmanuel Nicolas et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of Phosphorus(V)-Stabilized Geminal Dianions. The Cases of Mixed P═X/P→BH3 (X = S, O) and P═S/SiMe3 Derivatives

(2013) Hadrien Heuclin et al.   ORGANOMETALLICS

Structure, Bonding, and Reactivity of Room-Temperature-Stable Lithium Chloride Carbenoids

(2013) Claudia Kupper et al.   ORGANOMETALLICS

Reactivity Studies of a T-Shaped Yttrium Carbene: C–F and C–O Bond Activation and C═C Bond Formation Promoted by [Y(BIPM)(I)(THF)2] (BIPM = C(PPh2NSiMe3)2)

(2013) David P. Mills et al.   ORGANOMETALLICS

Complexes containing multiple bonding interactions between lanthanoid elements and main-group fragments

(2013) Owen T. Summerscales et al.   RSC Advances

Transmetalation of a nucleophilic carbene fragment: from early to late transition metals

(2012) Marie Fustier-Boutignon et al.   CHEMICAL COMMUNICATIONS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

Tetrahedral versus Planar Four-Coordinate Carbon: A Sulfonyl-Substituted Methandiide

(2012) Peter Schröter et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mixed (PS/PO)-Stabilized Geminal Dianion: Facile Diastereoselective Intramolecular CH Activations by a Related Ruthenium-Carbene Complex

(2012) Hadrien Heuclin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double Bonds

(2012) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of the Yttrium Alkyl Carbene Complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})2–: From Insertions, Substitutions, and Additions to Nontypical Transformations

(2012) David P. Mills et al.   ORGANOMETALLICS

Uranium-Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and Comparison of UVC and UIVC Bonds

(2011) Oliver J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Early metal bis(phosphorus-stabilised)carbene chemistry

(2011) Stephen T. Liddle et al.   CHEMICAL SOCIETY REVIEWS

The ThC double bond: an experimental and computational study of thorium poly-carbene complexes

(2011) Wenshan Ren et al.   DALTON TRANSACTIONS

Coordination Behavior of the S-C-S Monoanion and O-C-O and S-C-S Dianions toward CoII

(2011) Hadrien Heuclin et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Actinide Metals with Multiple Bonds to Carbon: Synthesis, Characterization, and Reactivity of U(IV) and Th(IV) Bis(iminophosphorano)methandiide Pincer Carbene Complexes

(2011) Guibin Ma et al.   INORGANIC CHEMISTRY

Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds

(2011) Jean-Christophe Tourneux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of a Palladium Thioketone Complex from a Thiophosphinoyl Stabilized Li/Cl Carbenoid

(2011) Viktoria H. Gessner   ORGANOMETALLICS

Uranium(IV) Nucleophilic Carbene Complexes

(2011) Jean-Christophe Tourneux et al.   ORGANOMETALLICS

A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

(2010) Oliver J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Geminal dianions stabilized by phosphonium substituents

(2010) Sjoerd Harder   COORDINATION CHEMISTRY REVIEWS

Synthesis and structure of [U{C(PPh2NMes)2}2] (Mes = 2,4,6-Me3C6H2): A homoleptic uranium bis(carbene) complex with two formal UC double bonds

(2010) Oliver J. Cooper et al.   DALTON TRANSACTIONS

Nucleophilic Scandium Carbene Complexes

(2010) Marie Fustier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spot the difference

(2010) Daniel J. Mindiola et al.   Nature Chemistry

Synthesis and Structure of Magnesium and Group 13 Metal Bis(thiophosphinoyl)methanediide Complexes

(2010) Wing-Por Leung et al.   ORGANOMETALLICS

Synthesis and Characterization of Magnesium and Aluminum Bis(phosphoranyl)methanediide Complexes

(2010) Jiayi Guo et al.   ORGANOMETALLICS

Synthesis and Characterization of Dysprosium and Lanthanum Bis(iminophosphorano)methanide and -methanediide Complexes

(2010) Ashley J. Wooles et al.   ORGANOMETALLICS

Rare, Hexatomic, Boat-Shaped, Cross-Linked Bis(iminodiphenylphosphorano)methanediide Pincer Carbon Bridged Photoluminescent Copper Clusters Capped with Methyl or Halide Bridges

(2010) Guibin Ma et al.   ORGANOMETALLICS

Methandiide Complexes (R2CM2) of the Heavier Alkali Metals (M=Potassium, Rubidium, Cesium): Reaching the Limit?

(2009) Lars Orzechowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main-group and transition-metal complexes of bis(phosphinimino)methanides

(2009) Tarun K. Panda et al.   CHEMICAL SOCIETY REVIEWS

Structure Formation Principles and Reactivity of Organolithium Compounds

(2009) Viktoria H. Gessner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Calcium carbene complexes with boranophosphorano side-arms: CaC[P(Ph)2BH3]2

(2009) Lars Orzechowski et al.   DALTON TRANSACTIONS

Phosphorus stabilized carbene complexes: bisphosphonate dianion synthesis, reactivity and DFT studies of O∼C∼O zirconium(iv) complexes

(2009) Hadrien Heuclin et al.   DALTON TRANSACTIONS

The UC Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene Complexes

(2009) Thibault Cantat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structure of [Li2C(PPh2═NSiMe3)(PPh2═S)]: A Geminal Dianionic Ligand

(2009) Jun-Hui Chen et al.   ORGANOMETALLICS

Heteroleptic [M(CH2C6H5)2(I)(THF)3] Complexes (M = Y or Er): Remarkably Stable Precursors to Yttrium and Erbium T-Shaped Carbenes

(2009) David P. Mills et al.   ORGANOMETALLICS

13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)

(2009) Han Vinh Huynh et al.   ORGANOMETALLICS

A Rare-Earth Metal Variant of the Tebbe Reagent

(2008) Rannveig Litlabø et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and structural characterisation of an yttrium–alkyl–alkylidene

(2008) Stephen T. Liddle et al.   CHEMICAL COMMUNICATIONS

Homo- and Heterodimetallic Geminal Dianions Derived from the Bis(phosphinimine) {Ph2P(NSiMe3)}2CH2 and the Alkali Metals Li, Na, and K

(2008) Katherine L. Hull et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bis-phosphorus stabilised carbene complexes

(2008) Thibault Cantat et al.   DALTON TRANSACTIONS

Heterobimetallic Bisphosphonate Titanium Complexes: Carbene-Like Carbanions?

(2008) Martin Spichty et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Structure/Reactivity Studies on an α-Lithiated Benzylsilane: Chemical Interpretation of Experimental Charge Density

(2008) Holger Ott et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Stabilized Methylidene and Oxoscandium Complexes

(2008) Jennifer Scott et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY