Substitution Effects on the Formation of T-Shaped Palladium Carbene and Thioketone Complexes from Li/Cl Carbenoids

A Cerium(IV)-Carbon Multiple Bond

(2013) Matthew Gregson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gated access to α-lithiated phenyltetrahydrofuran: functionalisation via direct lithiation of the parent oxygen heterocycle

(2013) Rosmara Mansueto et al.   CHEMICAL COMMUNICATIONS

The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

(2013) Oliver J. Cooper et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of Stabilized Li/Cl Carbenoids towards Lewis Base Adducts of BH3: BH Bond Activation versus Carbene Dimerization

(2013) Sebastian Molitor et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Bonding in Carbene Complexes of an Unsymmetrical Dilithio Methandiide: A Combined Experimental and Theoretical Study

(2013) Viktoria H. Gessner et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the structure and ambiphilicity of a sulfonyl substituted α-chloro lithium base

(2013) Julia Becker et al.   DALTON TRANSACTIONS

Facile B–H Bond Activation of Borane by Stable Carbenoid Species

(2013) Hadrien Heuclin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic Systems

(2013) Morgane Pasco et al.   ORGANOMETALLICS

Synthesis of Phosphorus(V)-Stabilized Geminal Dianions. The Cases of Mixed P═X/P→BH3 (X = S, O) and P═S/SiMe3 Derivatives

(2013) Hadrien Heuclin et al.   ORGANOMETALLICS

Reactivity Studies of a T-Shaped Yttrium Carbene: C–F and C–O Bond Activation and C═C Bond Formation Promoted by [Y(BIPM)(I)(THF)2] (BIPM = C(PPh2NSiMe3)2)

(2013) David P. Mills et al.   ORGANOMETALLICS

Direct observation of a lithiated oxirane: a synergistic study using spectroscopic, crystallographic, and theoretical methods on the structure and stereodynamics of lithiated ortho-trifluoromethyl styrene oxide

(2013) Antonio Salomone et al.   Chemical Science

Complexes containing multiple bonding interactions between lanthanoid elements and main-group fragments

(2013) Owen T. Summerscales et al.   RSC Advances

A Two-Coordinate Palladium Complex with Two Dialkylphosphinyl Ligands

(2012) Takeaki Iwamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tetrahedral versus Planar Four-Coordinate Carbon: A Sulfonyl-Substituted Methandiide

(2012) Peter Schröter et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mixed (PS/PO)-Stabilized Geminal Dianion: Facile Diastereoselective Intramolecular CH Activations by a Related Ruthenium-Carbene Complex

(2012) Hadrien Heuclin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double Bonds

(2012) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of the Yttrium Alkyl Carbene Complex [Y(BIPM)(CH2C6H5)(THF)] (BIPM = {C(PPh2NSiMe3)2})2–: From Insertions, Substitutions, and Additions to Nontypical Transformations

(2012) David P. Mills et al.   ORGANOMETALLICS

Uranium-Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and Comparison of UVC and UIVC Bonds

(2011) Oliver J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dispersion and Back-Donation Gives Tetracoordinate [Pd(PPh3)4]

(2011) Mårten S. G. Ahlquist et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

2-Lithiated-2-phenyloxetane: a new attractive synthon for the preparation of oxetane derivatives

(2011) Donato Ivan Coppi et al.   CHEMICAL COMMUNICATIONS

Extending unsupported metal-only Lewis pairs to palladium

(2011) Jürgen Bauer et al.   CHEMICAL COMMUNICATIONS

Early metal bis(phosphorus-stabilised)carbene chemistry

(2011) Stephen T. Liddle et al.   CHEMICAL SOCIETY REVIEWS

Oxygen Binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR3, NHC =N-Heterocyclic Carbene). Synthesis and Structure of a Paramagnetictrans-[Pd(NHC)2(η1-O2)2] Complex

(2011) Xiaochen Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of a Palladium Thioketone Complex from a Thiophosphinoyl Stabilized Li/Cl Carbenoid

(2011) Viktoria H. Gessner   ORGANOMETALLICS

A Monomeric Dilithio Methandiide with a Distorted trans-Planar Four-Coordinate Carbon

(2010) Oliver J. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anatomy of Long-Lasting Love Affairs with Lithium Carbenoids: Past and Present Status and Future Prospects

(2010) Vito Capriati et al.   CHEMISTRY-A EUROPEAN JOURNAL

Geminal dianions stabilized by phosphonium substituents

(2010) Sjoerd Harder   COORDINATION CHEMISTRY REVIEWS

Regioselective C−H Activation and Sequential C−C and C−O Bond Formation Reactions of Aryl Ketones Promoted by an Yttrium Carbene

(2010) David P. Mills et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spot the difference

(2010) Daniel J. Mindiola et al.   Nature Chemistry

Reactions of (Silyl)(silylene)tungsten and -molybdenum Complexes with Sulfur Reagents

(2010) Takako Muraoka et al.   ORGANOMETALLICS

Methandiide Complexes (R2CM2) of the Heavier Alkali Metals (M=Potassium, Rubidium, Cesium): Reaching the Limit?

(2009) Lars Orzechowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main-group and transition-metal complexes of bis(phosphinimino)methanides

(2009) Tarun K. Panda et al.   CHEMICAL SOCIETY REVIEWS

Reaction of 3,3,5,5-Tetraphenyl-1,2,4-trithiolane with Pt0(bisphosphane)(η2-nbe) Complexes Bearing Bridged Bisphosphane Ligands with Various Bite Angles

(2009) Thomas Weisheit et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Superior Precursor for Palladium(0)-Based Cross-Coupling and Other Catalytic Reactions

(2009) Danielle M. Norton et al.   JOURNAL OF ORGANIC CHEMISTRY

Tricarbonylrhenium(I) and manganese(I) complexes of 2-(pyrazolyl)-4-toluidine

(2009) Brendan J. Liddle et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The UC Double Bond: Synthesis and Study of Uranium Nucleophilic Carbene Complexes

(2009) Thibault Cantat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroleptic [M(CH2C6H5)2(I)(THF)3] Complexes (M = Y or Er): Remarkably Stable Precursors to Yttrium and Erbium T-Shaped Carbenes

(2009) David P. Mills et al.   ORGANOMETALLICS

Bis-phosphorus stabilised carbene complexes

(2008) Thibault Cantat et al.   DALTON TRANSACTIONS

Cyclometalation of Thiobenzophenones with Mononuclear Methyliron and ‐cobalt Complexes

(2008) Robert Beck et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Revised Basis Sets for the LANL Effective Core Potentials

(2008) Lindsay E. Roy et al.   Journal of Chemical Theory and Computation

2-Lithio-3,3-dimethyl-2-oxazolinyloxirane: Carbanion or Azaenolate? Structure, Configurational Stability, and Stereodynamics in Solution

(2008) Vito Capriati et al.   JOURNAL OF ORGANIC CHEMISTRY