Accessible Syntheses of Late Transition Metal (Pre)Catalysts Bearing N-Heterocyclic Carbene Ligands

Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

(2015) R. Savka et al.   DALTON TRANSACTIONS

Simple synthesis of neutral and cationic Cu-NHC complexes

(2015) Bo Liu et al.   DALTON TRANSACTIONS

Synthesis and characterisation of Au(I)-(ITent) complexes

(2015) Scott R. Patrick et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of Homoleptic and Heteroleptic Bis-N-heterocylic Carbene Group 11 Complexes

(2015) Faïma Lazreg et al.   ORGANOMETALLICS

Heterogenization of Pd–NHC complexes onto a silica support and their application in Suzuki–Miyaura coupling under batch and continuous flow conditions

(2015) Alberto Martínez et al.   Catalysis Science & Technology

From acetone metalation to the catalytic α-arylation of acyclic ketones with NHC–nickel(ii) complexes

(2014) Mickaël Henrion et al.   CHEMICAL COMMUNICATIONS

Chemistry of Iron N-Heterocyclic Carbene Complexes: Syntheses, Structures, Reactivities, and Catalytic Applications

(2014) Korbinian Riener et al.   CHEMICAL REVIEWS

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Expanded-RingN-Heterocyclic Carbenes Efficiently Stabilize Gold(I) Cations, Leading to High Activity in π-Acid-Catalyzed Cyclizations

(2014) Oleg S. Morozov et al.   CHEMISTRY-A EUROPEAN JOURNAL

[(IPent)PdCl2(morpholine)]: A Readily Activated Precatalyst for Room-Temperature, Additive-Free Carbon-Sulfur Coupling

(2014) Jennifer L. Farmer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alternative Synthetic Methods for PEPPSI-Type Palladium Complexes

(2014) Kerry-Ann Green et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Structural Characterization, Solution Dynamics, and Reactivity of Palladium Complexes with Benzimidazolin- 2-ylidene N-Heterocyclic Carbene Ligands

(2014) Stephan Hohloch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Facile-prepared sulfonated water-soluble PEPPSI-Pd-NHC catalysts for aerobic aqueous Suzuki–Miyaura cross-coupling reactions

(2014) Rui Zhong et al.   GREEN CHEMISTRY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Iridium(i) hydroxides in catalysis: rearrangement of allylic alcohols to ketones

(2014) David J. Nelson et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Methoxy-Functionalized N-Heterocyclic Carbenes

(2014) David J. Nelson et al.   ORGANOMETALLICS

Synthesis and Characterization of Gold(I) Complexes of Dibenzotropylidene-Functionalized NHC Ligands (Trop-NHCs)

(2014) Marcel Brill et al.   ORGANOMETALLICS

Mesoionic Triazolylidene Nickel Complexes: Synthesis, Ligand Lability, and Catalytic C–C Bond Formation Activity

(2014) Yingfei Wei et al.   ORGANOMETALLICS

Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling

(2014) Jay J. Dunsford et al.   ORGANOMETALLICS

Liberation of N-heterocyclic carbenes (NHCs) from thermally labile progenitors: protected NHCs as versatile tools in organo- and polymerization catalysis

(2014) Stefan Naumann et al.   Catalysis Science & Technology

Simple and efficient synthesis of [MCI(NHC)] (M = Au, Ag) complexes

(2013) Renso Visbal et al.   CHEMICAL COMMUNICATIONS

Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

(2013) Alba Collado et al.   CHEMICAL COMMUNICATIONS

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

(2013) Orlando Santoro et al.   CHEMICAL COMMUNICATIONS

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Iridium(I) Hydroxides: Powerful Synthons for Bond Activation

(2013) Byron J. Truscott et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfination by Using Pd-PEPPSI Complexes: Studies into Precatalyst Activation, Cationic and Solvent Effects and the Role of Butoxide Base

(2013) Mahmoud Sayah et al.   CHEMISTRY-A EUROPEAN JOURNAL

Large yet Flexible N-Heterocyclic Carbene Ligands for Palladium Catalysis

(2013) Sebastien Meiries et al.   CHEMISTRY-A EUROPEAN JOURNAL

(IPr)Pd(pydc) (pydc = pyridine-2,6-dicarboxylate) – A highly active precatalyst for the sterically hindered C–N coupling reactions

(2013) Yan-Jing Li et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and reactivity of (benz)imidazol-2-ylidenes with exocyclic N-acyl or N-sulfonyl groups

(2013) Markus Jonek et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Redox-active cyclopentadienyl Ni complexes with quinoid N-heterocyclic carbene ligands for the electrocatalytic hydrogen release from chemical fuels

(2013) Oana R. Luca et al.   NEW JOURNAL OF CHEMISTRY

Sanofi’s Solvent Selection Guide: A Step Toward More Sustainable Processes

(2013) Denis Prat et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Carbon–Heteroatom Coupling Using Pd-PEPPSI Complexes

(2013) Cory Valente et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Simplified Preparation of Copper(I) NHCs Using Aqueous Ammonia

(2013) Clémentine Gibard et al.   ORGANOMETALLICS

Direct Synthesis of Iron(0) N-Heterocyclic Carbene Complexes by Using Fe3(CO)12 and Their Application in Reduction of Carbonyl Groups

(2013) Svenja Warratz et al.   ORGANOMETALLICS

Gold and Palladium Hetero-Bis-NHC Complexes: Characterizations, Correlations, and Ligand Redistributions

(2013) Shuai Guo et al.   ORGANOMETALLICS

Effect of Electronic Enrichment of NHCs on the Catalytic Activity of [Pd(NHC)(acac)Cl] in Buchwald–Hartwig Coupling

(2013) Gaëtan Le Duc et al.   ORGANOMETALLICS

Enhanced Activity of [Ni(NHC)CpCl] Complexes in Arylamination Catalysis

(2013) Anthony R. Martin et al.   ORGANOMETALLICS

Efficient PEPPSI-Themed Palladium N-Heterocyclic Carbene Precatalysts for the Mizoroki–Heck Reaction

(2013) Yong-Chieh Lin et al.   ORGANOMETALLICS

Monodentate Palladium Complexes Bearing Abnormal and Normal Carbene Ligands with a Formally Identical Steric Environment

(2013) Chun-Hung Ke et al.   ORGANOMETALLICS

Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions

(2013) Laure Benhamou et al.   ORGANOMETALLICS

N-Heterocyclic carbene (NHC)–copper-catalysed transformations of carbon dioxide

(2013) Liang Zhang et al.   Chemical Science

Copper N-heterocyclic carbene complexes in catalysis

(2013) Jonathan D. Egbert et al.   Catalysis Science & Technology

The Development of Bulky Palladium NHC Complexes for the Most-Challenging Cross-Coupling Reactions

(2012) Cory Valente et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recyclable Hybrid Silica-Based Catalysts Derived from Pd-NHC Complexes for Suzuki, Heck and Sonogashira Reactions

(2012) Guadalupe Borja et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and electrochemistry of a series of cyclopentadienyl Ni N-heterocyclic carbene compounds

(2012) Oana R. Luca et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Proton Transfer Reactions of Triazol-3-ylidenes: Kinetic Acidities and Carbon Acid pKa Values for Twenty Triazolium Salts in Aqueous Solution

(2012) Richard S. Massey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroleptic Bis(N-heterocyclic carbene)Copper(I) Complexes: Highly Efficient Systems for the [3+2] Cycloaddition of Azides and Alkynes

(2012) Faïma Lazreg et al.   ORGANOMETALLICS

Synthesis and Catalytic Activity in Suzuki Coupling of Nickel Complexes Bearing n-Butyl- and Triethoxysilylpropyl-Substituted NHC Ligands: Toward the Heterogenization of Molecular Catalysts

(2012) Anna Magdalena Oertel et al.   ORGANOMETALLICS

[Pd(IPr*)(3-Cl-pyridinyl)Cl2]: A Novel and Efficient PEPPSI Precatalyst

(2012) Anthony Chartoire et al.   ORGANOMETALLICS

[Pd(IPr*OMe)(acac)Cl]: Tuning the N-Heterocyclic Carbene in Catalytic C–N Bond Formation

(2012) Sebastien Meiries et al.   ORGANOMETALLICS

[Pd(IPr*)(acac)Cl]: An Easily Synthesized, Bulky Precatalyst for C–N Bond Formation

(2012) Sebastien Meiries et al.   ORGANOMETALLICS

Synthesis and Structure of Palladium 1,2,3-Triazol-5-ylidene Mesoionic Carbene PEPPSI Complexes and Their Catalytic Applications in the Mizoroki–Heck Reaction

(2012) Eric C. Keske et al.   ORGANOMETALLICS

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling catalysis: a perfect union

(2011) George C. Fortman et al.   CHEMICAL SOCIETY REVIEWS

Expanding GSK's solvent selection guide – embedding sustainability into solvent selection starting at medicinal chemistry

(2011) Richard K. Henderson et al.   GREEN CHEMISTRY

Microwave-assisted synthesis of (N-heterocyclic carbene)Ni(Cp)Cl complexes

(2011) Brant Landers et al.   INORGANICA CHIMICA ACTA

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

(2011) Emmanuel Ferrer Flegeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Nitrile C–H Bond Activation in Nickel NHC Complexes: A Route to New Nickelacycles

(2011) Anna Magdalena Oertel et al.   ORGANOMETALLICS

Aminolysis of Bis[bis(trimethylsilyl)amido]iron and -cobalt as a Versatile Route to N-Heterocyclic Carbene Complexes

(2011) Andreas A. Danopoulos et al.   ORGANOMETALLICS

Influence of a Very BulkyN-Heterocyclic Carbene in Gold-Mediated Catalysis

(2011) Adrián Gómez-Suárez et al.   ORGANOMETALLICS

(N-Heterocyclic Carbene)PdCl2(TEA) Complexes: Studies on the Effect of the “Throw-Away” Ligand in Catalytic Activity

(2011) Ming-Tsz Chen et al.   ORGANOMETALLICS

A direct and practical approach for the synthesis of Au(I)-NHC complexes from commercially available imidazolium salts and Au(III) salts

(2011) Shifa Zhu et al.   TETRAHEDRON LETTERS

The Development and Catalytic Uses of N-Heterocyclic Carbene Gold Complexes

(2010) Steven P. Nolan   ACCOUNTS OF CHEMICAL RESEARCH

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper N-heterocyclic carbene (NHC) complexes as carbene transfer reagents

(2010) Marc R. L. Furst et al.   CHEMICAL COMMUNICATIONS

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

A N-heterocyclic carbene gold hydroxide complex: a golden synthon

(2010) Sylvain Gaillard et al.   CHEMICAL COMMUNICATIONS

pKas of the conjugate acids of N-heterocyclic carbenes in water

(2010) Eleanor M. Higgins et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Modified [(IPr)Pd(R-acac)Cl] Complexes: Influence of the acac Substitution on the Catalytic Activity in Aryl Amination

(2010) Nicolas Marion et al.   Chemistry-An Asian Journal

Half-sandwich NHC-nickel(ii) complexes as pre-catalysts for the fast Suzuki coupling of aryl halides: a comparative study

(2010) Vincent Ritleng et al.   DALTON TRANSACTIONS

Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents

(2010) Cécilia A. Citadelle et al.   DALTON TRANSACTIONS

Transfer Hydrogenation of Ketones by Ruthenium Complexes Bearing Benzimidazol-2-ylidene Ligands

(2010) Nevin Gürbüz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The development and use of novel iridium complexes as catalysts for ortho-directed hydrogen isotope exchange reactions

(2010) Göran N. Nilsson et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

C−H Activation of Acetonitrile at Nickel: Ligand Flip and Conversion of N-Bound Acetonitrile into a C-Bound Cyanomethyl Ligand

(2010) Anna Magdalena Oertel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of N-heterocyclic carbene ligands and derived ruthenium olefin metathesis catalysts

(2010) Xavier Bantreil et al.   Nature Protocols

Evidence for C−H···X−Ir (X = Cl or I) Hydrogen Bonding between Imidazolium Salts and Iridium-Bound Halides and Formation of Ir(I) NHC Complexes†

(2010) Weiwei Zuo et al.   ORGANOMETALLICS

A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)

(2010) George C. Fortman et al.   ORGANOMETALLICS

Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species

(2010) Jiseul Chun et al.   ORGANOMETALLICS

Microwave-Assisted Synthesis of N-Heterocyclic Carbene- Palladium(II) Complexes

(2009) Ole H. Winkelmann et al.   ADVANCED SYNTHESIS & CATALYSIS

Pd-PEPPSI-IPent: An Active, Sterically Demanding Cross-Coupling Catalyst and Its Application in the Synthesis of Tetra-Ortho-Substituted Biaryls

(2009) Michael G. Organ et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Based Olefin Metathesis Catalysts BearingN-Heterocyclic Carbene Ligands

(2009) Cezary Samojłowicz et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Coinage Metal−N-Heterocyclic Carbene Complexes

(2009) Joseph C. Y. Lin et al.   CHEMICAL REVIEWS

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

Synthesis, Structure, and Polymerization Activity of Cyclopentadienylnickel(II) N-Heterocyclic Carbene Complexes: Selective Cross-Metathesis in Metal Coordination Spheres

(2009) Włodzimierz Buchowicz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer

(2009) M. Emin Günay et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and catalytic properties of novel ruthenium N-heterocyclic-carbene complexes

(2009) Serpil Demir et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Comparative Study on (NHC)Pd(acac)Cl Complexes (NHC = N-heterocyclic carbene): Indications for the Origin of the Different Reactivity of Saturated and Unsaturated NHC in Cross-Coupling Reactions

(2009) Ole H. Winkelmann et al.   ORGANOMETALLICS

Synthesis and structure of indenylnickel(II) chlorides bearing free N-heterocyclic carbene ligands and their catalysis for styrene polymerization

(2009) Ling-Zhi Xie et al.   POLYHEDRON

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

C−H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene

(2008) Yasuhiro Ohki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Abnormal and Normal N-Heterocyclic Carbene Osmium Polyhydride Complexes Obtained by Direct Metalation of Imidazolium Salts

(2008) Beatriz Eguillor et al.   ORGANOMETALLICS

A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium

(2008) Macarena Poyatos et al.   ORGANOMETALLICS

Iridium Abnormal N-Heterocyclic Carbene Hydrides via Highly Selective C−H Activation

(2008) Guoyong Song et al.   ORGANOMETALLICS

Practical One-Pot, Three-Component Synthesis of N-Heterocyclic Carbene (NHC) Ligated Palladacycles Derived fromN,N-Dimethylbenzylamine

(2008) Eric Assen B. Kantchev et al.   ORGANOMETALLICS

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS