4.7 Article

Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

Journal

DALTON TRANSACTIONS
Volume 44, Issue 3, Pages 891-893

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03449j

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Funding

  1. DFG [DFG 178/13-2]

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The reactions of [MCl(cod)](2) (M = Rh, Ir) with different NHC center dot HX (X = Cl, I), K2CO3 in technical grade acetone under air provide simple access to various [(NHC)MX(cod)] complexes; a facile one-pot synthesis of [(NHC)MCl(CO)(2)] (M = Rh, Ir) is also reported.

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