Liberation of N-heterocyclic carbenes (NHCs) from thermally labile progenitors: protected NHCs as versatile tools in organo- and polymerization catalysis

N-Heterocyclic Carbene Catalyzed Activation of Esters: A New Option for Asymmetric Domino Reactions

(2014) Pankaj Chauhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-Opening Polymerization and Copolymerization of Propylene Oxide Catalyzed by N-Heterocyclic Carbenes

(2014) Ronald Lindner et al.   ChemCatChem

N-Heterocyclic Carbene Catalyzed Carba-, Sulfa-, and Phospha-Michael Additions with NHC·CO2 Adducts as Precatalysts

(2014) Morgan Hans et al.   JOURNAL OF ORGANIC CHEMISTRY

Latent and Delayed Action Polymerization Systems

(2014) Stefan Naumann et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Structures and Ambident Reactivities of Azolium Enolates

(2013) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Characterization of the Key Intermediates of Carbene-Catalyzed Umpolung by NMR Spectroscopy and X-Ray Diffraction: Breslow Intermediates, Homoenolates, and Azolium Enolates

(2013) Albrecht Berkessel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1-n-Butyl-3-methylimidazolium-2-carboxylate: a versatile precatalyst for the ring-opening polymerization of ε-caprolactone andrac-lactide under solvent-free conditions

(2013) Astrid Hoppe et al.   Beilstein Journal of Organic Chemistry

N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

(2013) Maréva Fèvre et al.   CHEMICAL SOCIETY REVIEWS

Acyl anion free N-heterocyclic carbene organocatalysis

(2013) Sarah J. Ryan et al.   CHEMICAL SOCIETY REVIEWS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Solid-State Covalent Capture of CO2by Using N-Heterocyclic Carbenes

(2013) Monika Vogt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dual catalysis: new approaches for the polymerization of lactones and polar olefins

(2013) Estefanía Piedra-Arroni et al.   DALTON TRANSACTIONS

Adducts of Nitrous Oxide and N-Heterocyclic Carbenes: Syntheses, Structures, and Reactivity

(2013) Alexander G. Tskhovrebov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anionic Ring-Opening Homo- and Copolymerization of Lactams by Latent, Protected N-Heterocyclic Carbenes for the Preparation of PA 12 and PA 6/12

(2013) Stefan Naumann et al.   MACROMOLECULES

Polymerization of methyl methacrylate by latent pre-catalysts based on CO2-protected N-heterocyclic carbenes

(2013) Stefan Naumann et al.   Polymer Chemistry

Azolium hydrogen carbonates and azolium carboxylates as organic pre-catalysts for N-heterocyclic carbene-catalysed group transfer and ring-opening polymerisations

(2013) Maréva Fèvre et al.   Polymer Chemistry

Protected N-heterocyclic carbenes as latent pre-catalysts for the polymerization of ε-caprolactone

(2013) Stefan Naumann et al.   Polymer Chemistry

Polymerization of cyclic esters using N-heterocyclic carbene carboxylate catalysts

(2013) Emilie Brulé et al.   Polymer Chemistry

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Polymerization of ε-Caprolactam by Latent Precatalysts Based on Protected N-Heterocyclic Carbenes

(2013) Stefan Naumann et al.   ACS Macro Letters

Umpolung by N-Heterocyclic Carbenes: Generation and Reactivity of the Elusive 2,2-Diamino Enols (Breslow Intermediates)

(2012) Albrecht Berkessel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A quantitative approach to nucleophilic organocatalysis

(2012) Herbert Mayr et al.   Beilstein Journal of Organic Chemistry

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

(2012) Xavier Bugaut et al.   CHEMICAL SOCIETY REVIEWS

Acyclic diaminocarbenes (ADCs) as a promising alternative to N-heterocyclic carbenes (NHCs) in transition metal catalyzed organic transformations

(2012) Vadim P. Boyarskiy et al.   COORDINATION CHEMISTRY REVIEWS

Abnormal, mesoionic and remote N-heterocyclic carbene complexes

(2012) Robert H. Crabtree   COORDINATION CHEMISTRY REVIEWS

Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism

(2012) Yuetao Zhang et al.   DALTON TRANSACTIONS

N-Heterocyclic carbene metal complexes in medicinal chemistry

(2012) Luciano Oehninger et al.   DALTON TRANSACTIONS

Epoxy Resin/Ionic Liquid Systems: The Influence of Imidazolium Cation Size and Anion Type on Reactivity and Thermomechanical Properties

(2012) Honorata Maka et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Imidazolium Hydrogen Carbonates versus Imidazolium Carboxylates as Organic Precatalysts for N-Heterocyclic Carbene Catalyzed Reactions

(2012) Maréva Fèvre et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkyne and Reversible Nitrile Activation: N,N′-Diamidocarbene-Facilitated Synthesis of Cyclopropenes, Cyclopropenones, and Azirines

(2012) Jonathan P. Moerdyk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Benzobisimidazolium-Based Fluorescent and Colorimetric Chemosensor for CO2

(2012) Zhiqian Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Imidazol(in)ium Hydrogen Carbonates as a Genuine Source of N-Heterocyclic Carbenes (NHCs): Applications to the Facile Preparation of NHC Metal Complexes and to NHC-Organocatalyzed Molecular and Macromolecular Syntheses

(2012) Maréva Fèvre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparative Study of Imidazole and Pyridine Catalyzed Reduction of Carbon Dioxide at Illuminated Iron Pyrite Electrodes

(2012) Andrew B. Bocarsly et al.   ACS Catalysis

Ionic liquids as benign catalysts for the carbonylation of amines to formamides

(2011) Young-Seop Choi et al.   APPLIED CATALYSIS A-GENERAL

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Synthesis and Organocatalytic Applications of Imidazol(in)ium-2-thiocarboxylates

(2011) Morgan Hans et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic carbene functionalized MCM-41 as an efficient catalyst for chemical fixation of carbon dioxide

(2011) Hui Zhou et al.   GREEN CHEMISTRY

Imidazolidene Carboxylate Bound MBPh4Complexes (M = Li, Na) and Their Relevance in Transcarboxylation Reactions

(2011) Bret R. Van Ausdall et al.   JOURNAL OF ORGANIC CHEMISTRY

Assessment of Stereoelectronic Factors That Influence the CO2 Fixation Ability of N-Heterocyclic Carbenes: A DFT Study

(2011) Manjaly J. Ajitha et al.   JOURNAL OF ORGANIC CHEMISTRY

Poly(N-heterocyclic-carbene)s and their CO2Adducts as Recyclable Polymer-Supported Organocatalysts for Benzoin Condensation and Transesterification Reactions

(2011) Julien Pinaud et al.   MACROMOLECULES

Distinct Reactivity of Mono- and Bis-NHC Silver Complexes: Carbene Donors versus Carbene–Halide Exchange Reagents

(2011) Ulrich Hintermair et al.   ORGANOMETALLICS

Glycolysis of poly(ethylene terephthalate) (PET) using basic ionic liquids as catalysts

(2011) Q.F. Yue et al.   POLYMER DEGRADATION AND STABILITY

Cooperative Lewis acid/N-heterocyclic carbene catalysis

(2011) Daniel T. Cohen et al.   Chemical Science

Polymer-Supported, Carbon Dioxide-Protected N-Heterocyclic Carbenes: Synthesis and Application in Organo- and Organometallic Catalysis

(2010) Gajanan Manohar Pawar et al.   ADVANCED SYNTHESIS & CATALYSIS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

pKas of the conjugate acids of N-heterocyclic carbenes in water

(2010) Eleanor M. Higgins et al.   CHEMICAL COMMUNICATIONS

[(NHC)(NHCewg)RuCl2(CHPh)] Complexes with Modified NHCewg Ligands for Efficient Ring-Closing Metathesis Leading to Tetrasubstituted Olefins

(2010) Volodymyr Sashuk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic and Thermodynamic Evaluation of the Reversible N-Heterocyclic Carbene−Isothiocyanate Coupling Reaction: Applications in Latent Catalysis

(2010) Brent C. Norris et al.   JOURNAL OF ORGANIC CHEMISTRY

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Imidazol(in)ium-2-carboxylates as N-Heterocyclic Carbene Precursors for the Synthesis of Second Generation Ruthenium Metathesis Catalysts

(2009) Xavier Sauvage et al.   ADVANCED SYNTHESIS & CATALYSIS

N-Heterocyclic Carbenes as Efficient Organocatalysts for CO2Fixation Reactions

(2009) Yoshihito Kayaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of Carbon Dioxide into Methanol with Silanes over N-Heterocyclic Carbene Catalysts

(2009) Siti Nurhanna Riduan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

CO2and SnIIAdducts of N-Heterocyclic Carbenes as Delayed-Action Catalysts for Polyurethane Synthesis

(2009) Bhasker Bantu et al.   CHEMISTRY-A EUROPEAN JOURNAL

CO2, Magnesium, Aluminum, and Zinc Adducts of N-Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis

(2009) Bhasker Bantu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Assessing the Potential of Zwitterionic NHC·CS2Adducts for Probing the Stereoelectronic Parameters of N-Heterocyclic Carbenes

(2009) Lionel Delaude et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Systematic Investigation of Factors Influencing the Decarboxylation of Imidazolium Carboxylates

(2009) Bret R. Van Ausdall et al.   JOURNAL OF ORGANIC CHEMISTRY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unexpected CO2Splitting Reactions To Form CO withN-Heterocyclic Carbenes as Organocatalysts and Aromatic Aldehydes as Oxygen Acceptors

(2009) Liuqun Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbenes for the Organocatalytic Ring-Opening Polymerization of ε-Caprolactone

(2009) Nahrain E. Kamber et al.   MACROMOLECULES

N-Heterocyclic Carbene Functionalized Polymer for Reversible Fixation−Release of CO2

(2009) Hui Zhou et al.   MACROMOLECULES

Harnessing the Potential of N‐Heterocyclic Carbenes for the Rejuvenation of Group‐Transfer Polymerization of (Meth)Acrylics

(2008) Jean Raynaud et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [(NHC)CuCl] complex as a latent Click catalyst

(2008) Silvia Díez-González et al.   CHEMICAL COMMUNICATIONS

Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

(2008) Heiko Jacobsen et al.   COORDINATION CHEMISTRY REVIEWS

CO2Adducts ofN-Heterocyclic Carbenes: Thermal Stability and Catalytic Activity toward the Coupling of CO2with Epoxides

(2008) Hui Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Group Transfer Polymerization of Acrylates Catalyzed by N-Heterocyclic Carbenes

(2008) Marc D. Scholten et al.   MACROMOLECULES

Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures

(2008) Manuel Iglesias et al.   ORGANOMETALLICS