Dealing at Arm's Length: Catalysis with N-Heterocyclic Carbene Ligands Bearing Anionic Tethers

Tethered NHC Ligands for Stereoselective Alkyne Semihydrogenations

(2017) Johannes Teichert et al.   SYNTHESIS-STUTTGART

Copper-Catalyzed Asymmetric Conjugate Addition of Dimethylzinc to Acyl-N -methylimidazole Michael Acceptors: Scope, Limitations and Iterative Reactions

(2016) Sammy Drissi-Amraoui et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

(2016) Hirohisa Ohmiya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis

(2016) Jens Mohr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene

(2016) Xiben Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

(2016) Yuto Yasuda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioselective Catalytic Sequence of Cu−H Addition to Vinyl-B(pin)/Allylic Substitution

(2016) Jaehee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benzimidazolium sulfonate ligand precursors and application in ruthenium-catalyzed aromatic amine alkylation with alcohols

(2016) Nazan Kaloglu et al.   CATALYSIS COMMUNICATIONS

Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity

(2016) Abraham J. Jordan et al.   CHEMICAL REVIEWS

Asymmetric Synthesis of Borylalkanes via Copper-Catalyzed Enantioselective Hydroallylation

(2016) Jung Tae Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups

(2016) Fanke Meng et al.   NATURE

Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes

(2016) Zhen-Qi Zhang et al.   ORGANIC LETTERS

Copper-Catalyzed Semihydrogenation of Internal Alkynes with Molecular Hydrogen

(2016) Takamichi Wakamatsu et al.   ORGANOMETALLICS

New benzimidazolium-based chiral ionic liquids: synthesis and application in enantioselective sodium borohydride reductions in water

(2016) Avtar Singh et al.   TETRAHEDRON-ASYMMETRY

N-Heterocyclic Carbenes in Asymmetric Hydrogenation

(2016) Dongbing Zhao et al.   ACS Catalysis

Improvements and Applications of the Transition Metal-Free Asymmetric Allylic Alkylation using Grignard Reagents and Magnesium Alanates

(2015) David Grassi et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Asymmetric Conjugate Addition of Dimethylzinc to Acyl-N-methylimidazole Michael Acceptors: a Powerful Synthetic Platform

(2015) Sammy Drissi-Amraoui et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Designing of thermally stable amide functionalized benzimidazolium perchlorate ionic liquid for transamidation of primary carboxamides

(2015) Prashant Narayan Muskawar et al.   APPLIED CATALYSIS A-GENERAL

A comparative study of hydroxyl- and carboxylate-functionalized imidazolium and benzimidazolium salts as precursors for N-heterocyclic carbene ligands

(2015) Andrés Allegue et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Copper-catalyzed asymmetric conjugate addition of organometallic reagents to extended Michael acceptors

(2015) Thibault E Schmid et al.   Beilstein Journal of Organic Chemistry

Effect of the functionalisation route on a Zr-MOF with an Ir–NHC complex for catalysis

(2015) Fabian Carson et al.   CHEMICAL COMMUNICATIONS

Complexes Bearing Protic N-Heterocyclic Carbenes: Synthesis and Applications

(2015) Mareike C. Jahnke et al.   CHEMISTRY LETTERS

Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2-Substituted Enones and Mg-Enolate Trapping

(2015) Nicolas Germain et al.   CHEMISTRY-A EUROPEAN JOURNAL

Z-Selective Copper(I)-Catalyzed Alkyne Semihydrogenation with Tethered Cu-Alkoxide Complexes

(2015) Felix Pape et al.   CHEMISTRY-A EUROPEAN JOURNAL

Complexes with protic (NH,NH and NH,NR) N-heterocyclic carbene ligands

(2015) Mareike C. Jahnke et al.   COORDINATION CHEMISTRY REVIEWS

An insight into a base-free Michael addition reaction as catalyzed by a bifunctional nickel N-heterocyclic carbene complex using density functional theory studies

(2015) Madanakrishna Katari et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes

(2015) Ying Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination

(2015) Dawen Niu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rare-earth metal alkyl complexes bearing an alkoxy N-heterocyclic carbene ligand: synthesis, characterization, catalysis for isoprene polymerization

(2015) Shiyu Long et al.   NEW JOURNAL OF CHEMISTRY

A New Phenoxide Chelated IrIII N-Heterocyclic Carbene Complex and Its Application in Reductive Amination Reactions

(2015) Derya Gülcemal et al.   ORGANOMETALLICS

Copper-Catalyzed Semihydrogenation of Alkynes to Z-Alkenes

(2015) Kazuhiko Semba et al.   SYNLETT

Chiral Imidazolinium Salts with TIPS Groups for the Palladium-Catalyzed α-Arylation and as Chiral Solvating Agents

(2015) René Wilhelm et al.   SYNLETT

Mechanistic Studies on the Alkylation of Amines with Alcohols Catalyzed by a Bifunctional Iridium Complex

(2015) Agnieszka Bartoszewicz et al.   ACS Catalysis

A Multicomponent Ni-, Zr-, and Cu-Catalyzed Strategy for Enantioselective Synthesis of Alkenyl-Substituted Quaternary Carbons

(2014) Kevin P. McGrath et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile esterification of carboxylic acid using amide functionalized benzimidazolium dicationic ionic liquids

(2014) Prashant Narayan Muskawar et al.   APPLIED CATALYSIS A-GENERAL

Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications

(2014) Stéphane Bellemin-Laponnaz et al.   CHEMICAL REVIEWS

Multicomponent Synthesis of Chiral Bidentate Unsymmetrical UnsaturatedN-Heterocyclic Carbenes: Copper-Catalyzed Asymmetric CC Bond Formation

(2014) Claire Jahier-Diallo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Ligand Cooperation on a Diruthenium Platform: Selective Imine Formation through Acceptorless Dehydrogenative Coupling of Alcohols with Amines

(2014) Biswajit Saha et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Hydrosilylation of Ketones Catalyzed by a Readily Accessible N-Heterocyclic Carbene-Ir Complex at Room Temperature

(2014) Kanako Shinohara et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Quaternary Carbon Stereocenters by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Arylboronates

(2014) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of pincer-type N-heterocyclic carbene palladium complexes with a hemilabile ligand and their application in cross-coupling catalysis

(2014) Vivienne Leigh et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The Influence of Anionic Ligands on Stereoisomerism of Ru Carbenes and Their Importance to Efficiency and Selectivity of Catalytic Olefin Metathesis Reactions

(2014) Sebastian Torker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

(2014) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

(2014) Ayumi Harada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes

(2014) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity

(2014) Hwanjong Jang et al.   ORGANIC LETTERS

Cu-Catalyzed Asymmetric Conjugate Addition of Dialkylzincs to Enones Using a (±)-trans-1,2-Cyclohexanediamine-Based Bis(NHC) Derived from l-Leucinol

(2014) Satoshi Sakaguchi et al.   SYNLETT

Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution

(2014) David Grassi et al.   Chemical Science

Recent Advances in α-Alkylation Reactions using Alcohols with Hydrogen Borrowing Methodologies

(2014) Yasushi Obora   ACS Catalysis

Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones

(2013) Jennifer A. Dabrowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard Reagents

(2013) David Grassi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation

(2013) Lukas B. Delvos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining NHC-Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

(2013) Jennifer A. Dabrowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The NH Functional Group in Organometallic Catalysis

(2013) Baoguo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Design, Synthesis, and Organocatalytic Activity of N-Heterocyclic Carbenes Functionalized with Hydrogen-Bond Donors in Enantioselective Reactions of Homoenolates

(2013) Faisal Nawaz et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of α-Tri- and α-Tetrasubstituted Allylsilanes by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Silylboronates

(2013) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent advances in S-functionalized N-heterocyclic carbene ligands: From the synthesis of azolium salts and metal complexes to applications

(2013) Christophe Fliedel et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes

(2013) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Conjugate Addition to α-Substituted Enones/Enolate Trapping

(2013) Nicolas Germain et al.   ORGANIC LETTERS

Primary Amine Functionalized N-Heterocyclic Carbene Complexes of Iridium: Synthesis, Structure, and Catalysis

(2013) Wylie W. N. O et al.   ORGANOMETALLICS

Synthesis of a chiral N-heterocyclic carbene bearing a m-terphenyl-based phosphate moiety as an anionic N-substituent and its application to copper-catalyzed enantioselective boron conjugate additions

(2013) Tomohiro Iwai et al.   TETRAHEDRON-ASYMMETRY

Multidentate actor ligands as versatile platforms for small molecule activation and catalysis

(2013) Vincent T. Annibale et al.   RSC Advances

Asymmetric Hydrosilane Reduction of Ketones Catalyzed by an Iridium Complex Bearing a Hydroxyamide-Functionalized NHC Ligand

(2012) Shun Kawabata et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents

(2012) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of chiral fluoroalkyl products through copper-free enantioselective allylic alkylation catalyzed by an NHC ligand

(2012) David Grassi et al.   CHEMICAL COMMUNICATIONS

Asymmetric catalysts for stereocontrolled olefin metathesis reactions

(2012) Steffen Kress et al.   CHEMICAL SOCIETY REVIEWS

Formation of Quaternary Stereogenic Centers by NHC-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Polyconjugated Cyclic Enones

(2012) Matthieu Tissot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Free Asymmetric Allylic Alkylation with a Grignard Reagent: Design of the Ligand and Mechanistic Studies

(2012) David Grassi et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Highly Active Bifunctional Iridium Complex with an Alcohol/Alkoxide-Tethered N-Heterocyclic Carbene for Alkylation of Amines with Alcohols

(2012) Agnieszka Bartoszewicz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bidentate Hydroxyalkyl NHC Ligands for the Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents

(2012) Magaly Magrez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Effect of chelating ring size in catalytic ketone hydrogenation: facile synthesis of ruthenium(ii) precatalysts containing an N-heterocyclic carbene with a primary amine donor for ketone hydrogenation and a DFT study of mechanisms

(2012) Hisashi Ohara et al.   DALTON TRANSACTIONS

Chiral NHC Ligands for the Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents

(2012) Nicolas Germain et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Functionalized N-Heterocyclic Carbene Ligands for Dual Enantioselective Control in the Cu-Catalyzed Conjugate Addition of Dialkylzinc Compounds to Acyclic Enones

(2012) Kenta Dohi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Hydroxy-amide Functionalized Azolium Salts for Cu-Catalyzed Asymmetric Conjugate Addition: Stereocontrol Based on Ligand Structure and Copper Precatalyst

(2012) Naoatsu Shibata et al.   JOURNAL OF ORGANIC CHEMISTRY

Thiol-functionalized 1,2,4-triazolium salt as carbene ligand precursor

(2012) Stefanie C. Holm et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Highly tunable anionic tethered N-heterocyclic carbene of Pd(II) complexes for asymmetric allylic alkylation reaction

(2012) Hiroshi Shirasaki et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Z- and Enantioselective Ring-Opening/Cross-Metathesis with Enol Ethers Catalyzed by Stereogenic-at-Ru Carbenes: Reactivity, Selectivity, and Curtin–Hammett Kinetics

(2012) R. Kashif M. Khan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Isolation, Characterization, and Reactivity of High-Energy Stereogenic-at-Ru Carbenes: Stereochemical Inversion through Olefin Metathesis and Other Pathways

(2012) R. Kashif M. Khan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Free Asymmetric Allylic Alkylation Using Grignard Reagents on Bifunctional Allylic Bromides

(2012) David Grassi et al.   ORGANIC LETTERS

Factors Favoring Efficient Bifunctional Catalysis. Study of a Ruthenium(II) Hydrogenation Catalyst Containing an N-Heterocyclic Carbene with a Primary Amine Donor

(2012) Wylie W. N. O et al.   ORGANOMETALLICS

Bifunctional Mechanism with Unconventional Intermediates for the Hydrogenation of Ketones Catalyzed by an Iridium(III) Complex Containing an N-Heterocyclic Carbene with a Primary Amine Donor

(2012) Wylie W. N. O et al.   ORGANOMETALLICS

Synthesis of amino acid derived imidazolidinium salts as new NHC precatalysts

(2012) Ragnhild B. Strand et al.   TETRAHEDRON-ASYMMETRY

Asymmetric induction afforded by chiral azolylidene N-heterocyclic carbenes (NHC) catalysts

(2012) Ragnhild B. Strand et al.   TETRAHEDRON-ASYMMETRY

Ester Hydrogenation Catalyzed by a Ruthenium(II) Complex Bearing an N-Heterocyclic Carbene Tethered with an “NH2” Group and a DFT Study of the Proposed Bifunctional Mechanism

(2012) Wylie W. N. O et al.   ACS Catalysis

Ruthenium-Catalyzed Regio- and Enantioselective Allylic Substitution with Water: Direct Synthesis of Chiral Allylic Alcohols

(2011) Naoya Kanbayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

(2011) Keishi Takatsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Amination of Alcohols

(2011) Sebastian Bähn et al.   ChemCatChem

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Short Synthesis of Chiral 4-Substituted (S)-Imidazolinium Salts Bearing Sulfonates and Their Use in γ-Selective Reactions of Allylic Halides with Grignard Reagents

(2011) Christopher M. Latham et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Bifunctional nickel precatalysts of amido-functionalized N-heterocyclic carbenes for base-free Michael reaction under ambient conditions

(2011) Sachin Kumar et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Enantio- and Regioselective Iridium-Catalyzed Allylic Hydroxylation

(2011) Martin Gärtner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chelated Ruthenium Catalysts forZ-Selective Olefin Metathesis

(2011) Koji Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Z-Selective Homodimerization of Terminal Olefins with a Ruthenium Metathesis Catalyst

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents

(2011) Jennifer A. Dabrowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective and Regioselective Copper-Catalyzed 1,4 Addition of Grignard Reagents to Cyclic Enynones

(2011) Matthieu Tissot et al.   ORGANIC LETTERS

Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for an Inner Sphere Mechanism

(2011) Wylie W. N. O et al.   ORGANOMETALLICS

Ligand design for dual enantioselective control in Cu-catalyzed asymmetric conjugate addition of R2Zn to cyclic enone

(2011) Misato Yoshimura et al.   TETRAHEDRON

Iridium complex bearing a chiral hydroxy-amide functionalized N-heterocyclic carbene: a catalyst precursor for asymmetric transfer hydrogenation

(2011) Hiroyuki Chiyojima et al.   TETRAHEDRON LETTERS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Heteroaryllithium Reagents and Aluminum Chlorides

(2010) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Free Asymmetric Allylic Alkylation with Grignard Reagents

(2010) Olivier Jackowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The hydrogenation of molecules with polar bonds catalyzed by a ruthenium(ii) complex bearing a chelating N-heterocyclic carbene with a primary amine donor

(2010) Wylie W. N. O et al.   CHEMICAL COMMUNICATIONS

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones

(2010) Stefan Kehrli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfur-functionalized N-heterocyclic carbenes and their transition metal complexes

(2010) Matthias Bierenstiel et al.   COORDINATION CHEMISTRY REVIEWS

[Pt2(μ-SAz)(μ-S)]2+ (SAz = azolium thiolate) dication as an unusual source for quadruply bridging sulfide in [Ag2Pt2(μ-SAz)(μ4-S)]3+

(2010) Jingqiu Li et al.   DALTON TRANSACTIONS

Reversal of Stereoselectivity in the Cu-Catalyzed Conjugate Addition Reaction of Dialkylzinc to Cyclic Enone in the Presence of a Chiral Azolium Compound

(2010) Naoatsu Shibata et al.   JOURNAL OF ORGANIC CHEMISTRY

A new C2-symmetric azolium compound for Cu-catalyzed asymmetric conjugate addition of R2Zn to cyclic enone

(2010) Ayako Harano et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

α-Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes: Practical Syntheses of Internal Vinyl Aluminums, Halides, or Boronates

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones

(2010) Tricia L. May et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Steric Properties of a Metathesis Catalyst for Copolymerization of Norbornene and Cyclooctene toward Complete Alternation

(2010) Sebastian Torker et al.   ORGANOMETALLICS

Dinuclear and Tetranuclear Palladium(II) Complexes of a Thiolato-Functionalized, Benzannulated N-Heterocyclic Carbene Ligand and Their Activities toward Suzuki−Miyaura Coupling

(2010) Dan Yuan et al.   ORGANOMETALLICS

Facile route to benzils from aldehydes via NHC-catalyzed benzoin condensation under metal-free conditions

(2010) Yuuki Shimakawa et al.   TETRAHEDRON LETTERS

An Air/Water-Stable Tridentate N-Heterocyclic Carbene- Palladium(II) Complex: Catalytic CH Activation of HydrocarbonsviaHydrogen/Deuterium Exchange Process in Deuterium Oxide

(2009) Joo Ho Lee et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Copper-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E Alkenes

(2009) Katsuhiro Akiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new approach to switching of enantioselectivity in NHC–Cu-catalyzed conjugate addition of alkylzincs to cyclic enones

(2009) Masaki Okamoto et al.   CHEMICAL COMMUNICATIONS

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

Coinage Metal−N-Heterocyclic Carbene Complexes

(2009) Joseph C. Y. Lin et al.   CHEMICAL REVIEWS

Recent advances in enantioselective copper-catalyzed 1,4-addition

(2009) Thomas Jerphagnon et al.   CHEMICAL SOCIETY REVIEWS

Magnesium and zinc complexes of functionalised, saturated N-heterocyclic carbene ligands: carbene lability and functionalisation, and lactide polymerisation catalysis

(2009) Polly L. Arnold et al.   DALTON TRANSACTIONS

Design of Chiral Hydroxyalkyl- and Hydroxyarylazolinium Salts as New Chelating Diaminocarbene Ligand Precursors Devoted to Asymmetric Copper-Catalyzed Conjugate Addition

(2009) Diane Rix et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Nickel Complexes ofN/O-Functionalized N-Heterocyclic Carbenes as Precatalysts for Michael Reactions in Air at Room Temperature Under the Much Preferred Base-Free Conditions

(2009) Sriparna Ray et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Efficient Three-Component Strecker Reaction of Aldehydes/Ketones via NHC-Amidate Palladium(II) Complex Catalysis

(2009) Jamie Jarusiewicz et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Intermolecular Boron Heck-Type Reactions via Oxidative Palladium(II) Catalysis with Chiral Tridentate NHC-Amidate-Alkoxide Ligands

(2009) Kyung Soo Yoo et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transmetalation of a Primary Amino-Functionalized N-Heterocyclic Carbene Ligand from an Axially Chiral Square-Planar Nickel(II) Complex to a Ruthenium(II) Precatalyst for the Transfer Hydrogenation of Ketones

(2009) Wylie W. N. O et al.   ORGANOMETALLICS

Rare [(NHC)2Ni-OH]-Type Terminal Nickel Hydroxo and [(NHC)2Ni]-Type Complexes ofN/O-Functionalized N-Heterocyclic Carbenes as Precatalysts for Highly Desirable Base-Free Michael Reactions in Air at Ambient Temperature

(2009) Manoja K. Samantaray et al.   ORGANOMETALLICS

Construction of a new type of chiral bidentate NHC ligands: copper-catalyzed asymmetric conjugate alkylation

(2009) Tatsuya Uchida et al.   TETRAHEDRON LETTERS

Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones

(2008) Tricia L. May et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Palladium(II) Complexes Possessing a Tridentate N-Heterocyclic Carbene Amidate Alkoxide Ligand: Access to Oxygen-Bridging Dimer Structures

(2008) Satoshi Sakaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Conjugate Addition and Allylic Alkylation with Grignard Reagents

(2008) Syuzanna R. Harutyunyan et al.   CHEMICAL REVIEWS

CuH-Catalyzed Reactions

(2008) Carl Deutsch et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Functionalised Saturated-Backbone Carbene Ligands: Yttrium and Uranyl Alkoxy-Carbene Complexes and Bicyclic Carbene-Alcohol Adducts

(2008) Polly L. Arnold et al.   CHEMISTRY-A EUROPEAN JOURNAL

Donor-Functionalised N-Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions

(2008) Adrien T. Normand et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

New enantiopure imidazolinium carbene ligands incorporating two hydroxy groups for Lewis acid-catalyzed diethyl zinc addition to aldehydes

(2008) Mazhar Gilani et al.   TETRAHEDRON-ASYMMETRY

Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents

(2007) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY