Rh(iii)-catalyzed C–H olefination of N-pentafluoroaryl benzamides using air as the sole oxidant

An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and AlkenesviaCH Functionalization

(2014) Lei Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct access to isoindolines through tandem Rh(iii)-catalyzed alkenylation and cyclization of N-benzyltriflamides

(2014) Neeraj Kumar Mishra et al.   CHEMICAL COMMUNICATIONS

Rh-Catalyzed oxidative C–H activation/annulation: converting anilines to indoles using molecular oxygen as the sole oxidant

(2014) Guoying Zhang et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Oxidative Olefination of Phenols Bearing Removable Directing Groups under Molecular Oxygen

(2014) Bin Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Aerobic Oxidative C–H Olefination of Cyclic N-Sulfonyl Ketimines Catalyzed by a Rhodium Catalyst

(2014) Nan-Jin Wang et al.   ORGANIC LETTERS

Ligand-Controlled C(sp3)-H Arylation and Olefination in Synthesis of Unnatural Chiral  -Amino Acids

(2014) J. He et al.   SCIENCE

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed CH Bond Activation

(2013) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl CH Activation

(2013) Xi-Sha Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(II)-Catalyzed ortho- or meta-C–H Olefination of Phenol Derivatives

(2013) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

(2013) Guoying Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complementary Regioselectivity in Rh(III)-Catalyzed Insertions of Potassium Vinyltrifluoroborate via C–H Activation: Preparation and Use of 4-Trifluoroboratotetrahydroisoquinolones

(2013) Marc Presset et al.   ORGANIC LETTERS

Oxidant-Free Rh(III)-Catalyzed Direct C–H Olefination of Arenes with Allyl Acetates

(2013) Chao Feng et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Oxidative Olefination of Pyridines and Quinolines: Multigram-Scale Synthesis of Naphthyridinones

(2013) Jun Zhou et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenyl Phenols Using an Oxidizing Directing Group

(2013) Yangyang Shen et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Ortho-Trifluoromethylation of Benzylamines

(2013) Masanori Miura et al.   ORGANIC LETTERS

Role of Mono-N-protected Amino Acid Ligands in Palladium(II)-Catalyzed Dehydrogenative Heck Reactions of Electron-Deficient (Hetero)arenes: Experimental and Computational Studies

(2013) Xuefeng Cong et al.   ORGANOMETALLICS

Enantioenriched Isoindolinones from Chiral Phase-Transfer-Catalyzed Intramolecular Aza-Michael Reactions

(2013) Eric Deniau et al.   SYNLETT

Rh(iii)-catalyzed C–H activation/cycloaddition of benzamides and methylenecyclopropanes: divergence in ring formation

(2013) Sunliang Cui et al.   Chemical Science

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

(2012) Alison N. Campbell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen

(2012) Wanqing Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Aerobic Dehydrogenative Heck Reactions of Heterocycles with Styrenes: A Negative Effect of Metallic Co-Oxidants

(2012) Alexandre Vasseur et al.   ADVANCED SYNTHESIS & CATALYSIS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

(2012) Zhuangzhi Shi et al.   CHEMICAL SOCIETY REVIEWS

Amide-Directed Tandem CC/CN Bond Formation through CH Activation

(2012) Chen Zhu et al.   Chemistry-An Asian Journal

Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS

(2012) Ting Lv et al.   JOURNAL OF FLUORINE CHEMISTRY

Palladium Catalyzed C–H Functionalization of O-Arylcarbamates: Selective ortho-Bromination Using NBS

(2012) Alex John et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed N-Nitroso-Directed C–H Olefination of Arenes. High-Yield, Versatile Coupling under Mild Conditions

(2012) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Annulation of Sulfonylhydrazones with Alkenes

(2012) Guifei Li et al.   ORGANIC LETTERS

Tandem Rh(III)-Catalyzed Oxidative Acylation of Secondary Benzamides with Aldehydes and Intramolecular Cyclization: The Direct Synthesis of 3-Hydroxyisoindolin-1-ones

(2012) Satyasheel Sharma et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Alkenylations of Anilides and Benzamides in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Enantioselective Total Synthesis of (+)-Lithospermic Acid

(2012) Arun K. Ghosh et al.   ORGANIC LETTERS

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions

(2011) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes

(2011) Marion H. Emmert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium catalyzed C–H olefination of N-benzoylsulfonamides with internal alkenes

(2011) Chen Zhu et al.   CHEMICAL COMMUNICATIONS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1H-pyrazoles with Alkynes and Acrylates

(2011) Xingwei Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Oxidative ortho-C–H Borylation of Arenes

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Convergent Total Synthesis of (+)-Lithospermic Acid via a Late-Stage Intermolecular C−H Olefination

(2011) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Selective Olefination of Arene Esters via C−H Bond Activation

(2011) Sae Hume Park et al.   ORGANIC LETTERS

Regioselective Pd-Catalyzed Aerobic Aza-Wacker Cyclization for Preparation of Isoindolinones and Isoquinolin-1(2H)-ones

(2011) Guoqiang Yang et al.   ORGANIC LETTERS

N-Acylsulfonamide Assisted Tandem C−H Olefination/Annulation: Synthesis of Isoindolinones

(2011) Chen Zhu et al.   ORGANIC LETTERS

New Heteroannulation Reactions ofN-Alkoxybenzamides by Pd(II) Catalyzed C–H Activation

(2011) Joe W. Wrigglesworth et al.   ORGANIC LETTERS

Scope and Mechanistic Study of the Coupling Reaction of α,β-Unsaturated Carbonyl Compounds with Alkenes: Uncovering Electronic Effects on Alkene Insertion vs Oxidative Coupling Pathways

(2011) Ki-Hyeok Kwon et al.   ORGANOMETALLICS

Constructing Multiply Substituted Arenes Using Sequential Palladium(II)-Catalyzed CH Olefination

(2010) Keary M. Engle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl−CF3Bond-Forming Reductive Elimination from Palladium(IV)

(2010) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Olefination ofsp3C−H Bonds

(2010) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Tandem Oxidative Olefination−Michael Reactions between Aryl Carboxamides and Alkenes

(2010) Fen Wang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant

(2009) Keith M. Gligorich et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants

(2009) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Olefination of Electron-Deficient Arenes Using 2,6-Dialkylpyridine Ligands

(2009) Yang-Hui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

(2008) Julio Piera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(II)-Catalyzed Cross-Coupling of sp3C−H Bonds with sp2and sp3Boronic Acids Using Air as the Oxidant

(2008) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote C–H bond functionalization reveals the distance-dependent isotope effect

(2008) Jiao-Jie Li et al.   TETRAHEDRON