Rhodium and Iridium Complexes of Lutidine-Based NHC/Amino Pincer Ligands: From Monodentate to Tetradentate Coordination Enabled by C–H Activation

Polymerization of phenylacetylene catalyzed by rhodium(i) complexes with N-functionalized N-heterocyclic carbene ligands

(2022) Marta Angoy et al.   Polymer Chemistry

Nucleophilic Reactivity at a ═CH Arm of a Lutidine-Based CNC/Rh System: Unusual Alkyne and CO2 Activation

(2022) Pablo Hermosilla et al.   INORGANIC CHEMISTRY

N-Methylation of Amines with Methanol Catalyzed by Iridium(I) Complexes Bearing an N,O-Functionalized NHC Ligand

(2022) Miguel González-Lainez et al.   ORGANOMETALLICS

Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights

(2022) Miguel González-Lainez et al.   ORGANOMETALLICS

Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands

(2021) Práxedes Sánchez et al.   ORGANOMETALLICS

Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes

(2021) Isabel Ortega-Lepe et al.   INORGANIC CHEMISTRY

Rh Complexes with Pincer Carbene CNC Lutidine-Based Ligands: Reactivity Studies toward H2 Addition

(2021) Pablo Hermosilla et al.   ORGANOMETALLICS

Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment

(2018) M. Hernández-Juárez et al.   CHEMICAL COMMUNICATIONS

Mechanistic view of Ru-catalyzed C–H bond activation and functionalization: computational advances

(2018) Chunhui Shan et al.   CHEMICAL SOCIETY REVIEWS

New Aspects of Recently Developed Rh(NHC)-Catalyzed Organic Transformations

(2018) Jooyeon Lee et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative addition of iodine to (tBu)4 (POCOP)Ir(CO) complexes

(2017) Jonathan M. Goldberg et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis, structure and reactivity of Pd and Ir complexes based on new lutidine-derived NHC/phosphine mixed pincer ligands

(2016) Práxedes Sánchez et al.   DALTON TRANSACTIONS

Chelating N-heterocyclic carbene–carboranes offer flexible ligand coordination to IrIII, RhIII and RuII: effect of ligand cyclometallation in catalytic transfer hydrogenation

(2016) Jordan Holmes et al.   DALTON TRANSACTIONS

Ruthenium(II) Complexes Containing Lutidine-Derived Pincer CNC Ligands: Synthesis, Structure, and Catalytic Hydrogenation of CN bonds

(2015) Martín Hernández-Juárez et al.   CHEMISTRY-A EUROPEAN JOURNAL

RhIII-Catalyzed C(sp3)H Bond Activation by an External Base Metalation/Deprotonation Mechanism: A Theoretical Study

(2015) Julong Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-ligand cooperation by aromatization-dearomatization as a tool in single bond activation

(2015) D. Milstein   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Crystal structure refinement withSHELXL

(2015) George M. Sheldrick   Acta Crystallographica Section C-Structural Chemistry

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants

(2014) Robert H. Morris   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation

(2014) Ramón Azpíroz et al.   ACS Catalysis

Lutidine-Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties

(2014) Georgy A. Filonenko et al.   ACS Catalysis

Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

(2013) James E. Wheatley et al.   CHEMICAL COMMUNICATIONS

An Alternative Mechanistic Paradigm for the β-ZHydrosilylation of Terminal Alkynes: The Role of Acetone as a Silane Shuttle

(2013) Manuel Iglesias et al.   CHEMISTRY-A EUROPEAN JOURNAL

A synthon for a 14-electron Ir(iii) species: catalyst for highly selective β-(Z) hydrosilylation of terminal alkynes

(2012) Manuel Iglesias et al.   CHEMICAL COMMUNICATIONS

Ligand Effects on the Oxidative Addition of Halogens to (dpp-nacnacR)Rh(phdi)

(2012) David W. Shaffer et al.   INORGANIC CHEMISTRY

WinGXandORTEP for Windows: an update

(2012) Louis J. Farrugia   JOURNAL OF APPLIED CRYSTALLOGRAPHY

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ester hydrogenation catalyzed by Ru-CNN pincer complexes

(2011) Yunshan Sun et al.   CHEMICAL COMMUNICATIONS

Smooth C(alkyl)–H bond activation in rhodium complexes comprising abnormal carbene ligands

(2011) Anneke Krüger et al.   DALTON TRANSACTIONS

Recyclable mesoporous silica-supported chiral ruthenium-(NHC)NN-pincer catalysts for asymmetric reactions

(2011) Carolina del Pozo et al.   GREEN CHEMISTRY

Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts

(2011) M. Victoria Jiménez et al.   ORGANOMETALLICS

Pincer-type Pyridine-Based N-Heterocyclic Carbene Amine Ru(II) Complexes as Efficient Catalysts for Hydrogen Transfer Reactions

(2011) Carolina del Pozo et al.   ORGANOMETALLICS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Bridge functionalized bis-N-heterocyclic carbene rhodium(I) complexes and their application in catalytic hydrosilylation

(2010) Claudia S. Straubinger et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Immobilization of (NHC)NN-Pincer Complexes on Mesoporous MCM-41 Support

(2010) Carolina del Pozo et al.   ORGANOMETALLICS

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation

(2010) David Milstein   TOPICS IN CATALYSIS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Synthesis of Electron-Rich CNN-Pincer Complexes, with N-Heterocyclic Carbene and (S)-Proline Moieties and Application to Asymmetric Hydrogenation

(2009) Mèrce Boronat et al.   ORGANOMETALLICS

Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity

(2008) Kiyofumi Inamoto et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation

(2008) Liangru Yang et al.   ORGANOMETALLICS