Ruthenium(II) Complexes Containing Lutidine-Derived Pincer CNC Ligands: Synthesis, Structure, and Catalytic Hydrogenation of CN bonds

Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst

(2014) Georgy A. Filonenko et al.   ChemCatChem

Solvent free selective dehydrogenation of indolic and carbazolic molecules with an iridium pincer catalyst

(2014) Daniel F. Brayton et al.   CHEMICAL COMMUNICATIONS

Controlled hydrogenative depolymerization of polyesters and polycarbonates catalyzed by ruthenium(ii) PNN pincer complexes

(2014) Eric M. Krall et al.   CHEMICAL COMMUNICATIONS

Formation of Unsaturated Vicinal Zr+/P Frustrated Lewis Pairs by the Unique 1,1-Carbozirconation Reactions

(2014) Xin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unravelling the Mechanism of the Asymmetric Hydrogenation of Acetophenone by [RuX2(diphosphine)(1,2-diamine)] Catalysts

(2014) Pavel A. Dub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Perdehydrogenation and Perhydrogenation of Fused Bicyclic N-Heterocycles Catalyzed by Iridium Complexes Bearing a Functional Bipyridonate Ligand

(2014) Ken-ichi Fujita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Molecular Iron Catalyst for the Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(i) PNP pincer-type complex and the reaction with dihydrogen

(2014) Matthias Vogt et al.   Chemical Science

Lutidine-Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties

(2014) Georgy A. Filonenko et al.   ACS Catalysis

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

(2013) Dipankar Srimani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Hydrogenation for the In Situ Regeneration of an NAD(P)H Model: Biomimetic Reduction of α-Keto-/α-Iminoesters

(2013) Liang-Qiu Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acceptorless Dehydrogenation of Nitrogen Heterocycles with a Versatile Iridium Catalyst

(2013) Jianjun Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A 4-coordinate Ru(ii) imido: unusual geometry, synthesis, and reactivity

(2013) Amrendra K. Singh et al.   CHEMICAL COMMUNICATIONS

Activation of CO2 by phosphinoamide hafnium complexes

(2013) Michael J. Sgro et al.   CHEMICAL COMMUNICATIONS

Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

(2013) Chelsea A. Huff et al.   CHEMICAL COMMUNICATIONS

Facile N–H Bond Cleavage of Ammonia by an Iridium Complex Bearing a Noninnocent PNP-Pincer Type Phosphaalkene Ligand

(2013) Yung-Hung Chang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Nitriles by Metal Ligand Cooperation. Reversible Formation of Ketimido- and Enamido-Rhenium PNP Pincer Complexes and Relevance to Catalytic Design

(2013) Matthias Vogt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source

(2013) Ekambaram Balaraman et al.   Nature Chemistry

Hydrogenation of Dimethyl Carbonate to Methanol by trans-[Ru(H)2(PNN)(CO)] Catalysts: DFT Evidence for Ion-Pair-Mediated Metathesis Paths for C–OMe Bond Cleavage

(2013) Faraj Hasanayn et al.   ORGANOMETALLICS

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Catalytic CO2 Hydrogenation to Formate by a Ruthenium Pincer Complex

(2013) Chelsea A. Huff et al.   ACS Catalysis

The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer

(2013) Georgy A. Filonenko et al.   ACS Catalysis

Asymmetric Hydrogenation of N-Arylimines Catalyzed by the Xyl-Skewphos/DPEN-Ruthenium(II) Complex

(2012) Noriyoshi Arai et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium Pincer-Catalyzed Cross-Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions

(2012) Dipankar Srimani et al.   ADVANCED SYNTHESIS & CATALYSIS

Acceptorless and Base-Free Dehydrogenation of Alcohols and Amines using Ruthenium-Hydride Complexes

(2012) Senthilkumar Muthaiah et al.   ADVANCED SYNTHESIS & CATALYSIS

Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex

(2012) Michael J. Sgro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure

(2012) Dipankar Srimani et al.   CHEMICAL COMMUNICATIONS

N-heterocyclic carbene transition metal complexes for catalysis in aqueous media

(2012) Heriberto Diaz Velazquez et al.   CHEMICAL SOCIETY REVIEWS

Coordination chemistry beyond Werner: interplay between hydrogen bonding and coordination

(2012) Jan Reedijk   CHEMICAL SOCIETY REVIEWS

Highly Enantioselective Imine Hydrogenation Catalyzed by Ruthenium Phosphane-Phosphite Diamine Complexes

(2012) Mónica Vaquero et al.   CHEMISTRY-A EUROPEAN JOURNAL

A New Mode of Activation of CO2 by Metal-Ligand Cooperation with Reversible CC and MO Bond Formation at Ambient Temperature

(2012) Matthias Vogt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands

(2012) Martín Hernández-Juárez et al.   DALTON TRANSACTIONS

Nucleophilic Attack on Coordinated Imines: The Synthesis of C-Bonded Acetylacetonates of Palladium(II) and Mechanistic Insights

(2012) Thomas Birkle et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Aldehyde Binding through Reversible C–C Coupling with the Pincer Ligand upon Alcohol Dehydrogenation by a PNP–Ruthenium Catalyst

(2012) Michael Montag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrophenanthridine: A New and Easily Regenerable NAD(P)H Model for Biomimetic Asymmetric Hydrogenation

(2012) Qing-An Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Outer sphere hydrogenation catalysis

(2012) Odile Eisenstein et al.   NEW JOURNAL OF CHEMISTRY

Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)

(2012) Chelsea A. Huff et al.   ORGANOMETALLICS

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Unprecedented Catalytic Hydrogenation of Urea Derivatives to Amines and Methanol

(2011) Ekambaram Balaraman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Hydrogen Production from Alcohols under Mild Reaction Conditions

(2011) Martin Nielsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Peptides and Pyrazines from β-Amino Alcohols through Extrusion of H2 Catalyzed by Ruthenium Pincer Complexes: Ligand-Controlled Selectivity

(2011) Boopathy Gnanaprakasam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenation of imino bonds with half-sandwich metal catalysts

(2011) Chao Wang et al.   CHEMICAL COMMUNICATIONS

Ester hydrogenation catalyzed by Ru-CNN pincer complexes

(2011) Yunshan Sun et al.   CHEMICAL COMMUNICATIONS

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols

(2011) Ekambaram Balaraman et al.   CHEMICAL COMMUNICATIONS

Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand

(2011) Jarl Ivar van der Vlugt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic and geometrical manipulation of the excited state of bis-terdentate homo- and heteroleptic ruthenium complexes

(2011) Joydev Dinda et al.   DALTON TRANSACTIONS

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Direct Synthesis of Polyamides via Catalytic Dehydrogenation of Diols and Diamines

(2011) Hanxiang Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–Phosphinoaryloxide Complexes

(2011) Andy M. Chapman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cascade Catalysis for the Homogeneous Hydrogenation of CO2to Methanol

(2011) Chelsea A. Huff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO

(2011) Ekambaram Balaraman et al.   Nature Chemistry

α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines

(2011) Jared W. Rigoli et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Development of Platinum(II) and -(IV) CNC Pincer Complexes and Their Application in a Hydrovinylation Reaction

(2011) Daniel Serra et al.   ORGANOMETALLICS

New CNN-Type Ruthenium Pincer NHC Complexes. Mild, Efficient Catalytic Hydrogenation of Esters

(2011) Eran Fogler et al.   ORGANOMETALLICS

Pincer-type Pyridine-Based N-Heterocyclic Carbene Amine Ru(II) Complexes as Efficient Catalysts for Hydrogen Transfer Reactions

(2011) Carolina del Pozo et al.   ORGANOMETALLICS

Direct Synthesis of Imines from Alcohols and Amines with Liberation of H2

(2010) Boopathy Gnanaprakasam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highlights of Transition Metal-Catalyzed Asymmetric Hydrogenation of Imines

(2010) Nicolas Fleury-Brégeot et al.   ChemCatChem

Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines

(2010) Jian-Hua Xie et al.   CHEMICAL REVIEWS

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation

(2010) Eugene Khaskin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

(2010) Ekambaram Balaraman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The effect of temperature, catalyst and sterics on the rate of N-heterocycledehydrogenation for hydrogenstorage

(2010) Darrell Dean et al.   NEW JOURNAL OF CHEMISTRY

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

Mechanistic analysis of the transition metal-catalyzed hydrogenation of imines and functionalized enamines

(2009) Amandine Fabrello et al.   COORDINATION CHEMISTRY REVIEWS

CuIComplexes with a Noninnocent PNP Ligand: Selective Dearomatization and Electrophilic Addition Reactivity

(2009) Jarl Ivar van der Vlugt et al.   INORGANIC CHEMISTRY

Activation of the C−N Bond in Nitromethane by Palladium α-Diimine Complexes

(2009) Suzanne R. Golisz et al.   JOURNAL OF ORGANIC CHEMISTRY

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Metal−Ligand Cooperation in H2Production and H2O Decomposition on a Ru(II) PNN Complex: The Role of Ligand Dearomatization−Aromatization

(2009) Jun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Catalytic System for Reversible Dehydrogenation−Hydrogenation Reactions of Nitrogen Heterocycles with Reversible Interconversion of Catalytic Species

(2009) Ryohei Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Water Splitting and Oxygen−Oxygen Bond Formation by a Mononuclear Ruthenium Complex

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic and neutral NiIIcomplexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species

(2008) Jarl Ivar van der Vlugt et al.   DALTON TRANSACTIONS

Hydrogen storage in liquid organic heterocycles

(2008) Robert H. Crabtree   Energy & Environmental Science

Donor-Functionalised N-Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions

(2008) Adrien T. Normand et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity

(2008) Kiyofumi Inamoto et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Origin of Enantioselective Hydrogenation of Ketones by RuH2(diphosphine)(diamine) Catalysts: A Theoretical Study

(2008) Tom Leyssens et al.   ORGANOMETALLICS

Theoretical Analysis of the Hydrogen-Transfer Reaction to CN, CC, and CC Bonds Catalyzed by Shvo’s Ruthenium Complex

(2008) Aleix Comas-Vives et al.   ORGANOMETALLICS