Nickel Chain-Walking Catalysis: A Journey to Migratory Carboboration of Alkenes

Nickel-Catalyzed Regio- and Enantioselective Borylative Coupling of Terminal Alkenes with Alkyl Halides Enabled by an Anionic Bisoxazoline Ligand

(2023) Zheqi Li et al.   Journal of the American Chemical Society

Regio- and enantioselective remote dioxygenation of internal alkenes

(2023) Xiaonan Li et al.   Nature Chemistry

Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes

(2023) Laura Talavera et al.   ACS Catalysis

Ligand-Modulated Regiodivergent Alkenylboration of Allylarenes: Reaction Development and Mechanistic Study

(2023) Caocao Sun et al.   Fundamental Research

Integrating aryl chlorides into nickel-catalyzed 1,1-difunctionalization of alkenes

(2022) Caocao Sun et al.   CHINESE CHEMICAL LETTERS

Nickel-Catalyzed Migratory Benzylboration of Allylbenzenes

(2022) Yangyang Li et al.   TETRAHEDRON LETTERS

Practical Synthesis of Chiral Allylboronates by Asymmetric 1,1‐Difunctionalization of Terminal Alkenes

(2022) Caocao Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed asymmetric 1,2-alkynylboration of vinylarenes

(2022) Mei Duan et al.   TETRAHEDRON LETTERS

sp3 Bis‐Organometallic Reagents via Catalytic 1,1‐Difunctionalization of Unactivated Olefins

(2021) Ruben Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition‐Metal‐Catalyzed Synthesis of Chiral Allylboronates

(2021) Wenbo Ming et al.   CHINESE JOURNAL OF CHEMISTRY

Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions

(2021) Laura M. Wickham et al.   ACCOUNTS OF CHEMICAL RESEARCH

Guanidine Derivatives: How Simple Structural Modification of Histamine H3R Antagonists Has Led to the Discovery of Potent Muscarinic M2R/M4R Antagonists

(2021) Marek Staszewski et al.   ACS Chemical Neuroscience

Regio- and Stereoselective Alkylboration of Endocyclic Olefins Enabled by Nickel Catalysis

(2021) Chao Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyzing Electrosynthesis: A Homogeneous Electrocatalytic Approach to Reaction Discovery

(2020) Juno C. Siu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Three-Component Heck Arylation/Amination of Nonconjugated Cyclodienes

(2020) Daoyong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling

(2020) Yuqiang Li et al.   Nature Communications

Nickel-Catalyzed Chemodivergent 1,1-Difunctionalization of Unactivated α-Olefins with Alkynyl Electrophiles and B2pin2

(2020) Yangyang Li et al.   ACS Catalysis

Sharpless Asymmetric Epoxidation: Applications in the Synthesis of Bioactive Natural Products

(2020) Suélen Karine Sartori et al.   MINI-REVIEWS IN ORGANIC CHEMISTRY

Synergistic Ni/Cu catalyzed migratory arylsilylation of terminal olefins

(2020) Binzhi Zhao et al.   Science Bulletin

Catalyst-controlled enantioselective 1,1-arylboration of unactivated olefins

(2020) Wang Wang et al.   Nature Catalysis

Enantioselective C(sp3)–C(sp3) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis

(2020) Srikrishna Bera et al.   Nature Chemistry

Directed, Palladium(II)-Catalyzed Enantioselective anti-Carboboration of Alkenyl Carbonyl Compounds

(2019) Zhen Liu et al.   ACS Catalysis

Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis

(2019) Wang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes

(2019) Yangyang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters

(2019) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Arylboration of Alkenylarenes: Synthesis of Boron-Substituted Quaternary Carbons and Regiodivergent Reactions

(2019) Liang-An Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies

(2019) Stephen R. Sardini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition‐Metal‐Catalyzed 1,2‐Carboboration of Alkenes: Strategies, Mechanisms, and Stereocontrol

(2019) Zhen Liu et al.   ISRAEL JOURNAL OF CHEMISTRY

Stereoselective Palladium-Catalyzed 1,3-Arylboration of Unconjugated Dienes for Expedient Synthesis of 1,3-Disubstituted Cyclohexanes

(2019) Hailiang Pang et al.   ACS Catalysis

Metal‐Catalyzed Substrate‐Directed Enantioselective Functionalization of Unactivated Alkenes

(2019) Zi‐Xuan Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Difunctionalization of Alkenes Involving Metal Migration

(2019) Yuqiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ortho -Directing Chromium Arene Complexes as Efficient Mediators for Enantiospecific C(sp2 )-C(sp3 ) Cross-Coupling Reactions

(2018) Raphael Bigler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed Regioselective β,δ-Diarylation of Unactivated Olefins in Ketimines via Ligand-Enabled Contraction of Transient Nickellacycles: Rapid Access to Remotely Diarylated Ketones

(2018) Prakash Basnet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed difunctionalization of allyl moieties using organoboronic acids and halides with divergent regioselectivities

(2018) Wanfang Li et al.   Chemical Science

Walking Metals for Remote Functionalization

(2018) Heiko Sommer et al.   ACS Central Science

Enantiospecific and Iterative Suzuki–Miyaura Cross-Couplings

(2017) Jason P. G. Rygus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Ligand-Controlled Nickel-Catalyzed Reductive Relay Cross-Coupling of Alkyl Bromides and Aryl Bromides

(2017) Long Peng et al.   ACS Catalysis

Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

(2016) Takashi Koike et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

(2016) Guoyin Yin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Enantioselective Intermolecular Carboetherification of Dihydrofurans

(2016) Gustavo M. Borrajo-Calleja et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote functionalization through alkene isomerization

(2016) Alexandre Vasseur et al.   Nature Chemistry

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes

(2015) Wei Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Optimization of TRPV6 Calcium Channel Inhibitors Using a 3D Ligand-Based Virtual Screening Method

(2015) Céline Simonin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

(2015) Ying He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

(2015) Hosea M. Nelson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Three-Component Carboboration of Alkenes under Copper Catalysis

(2014) Hiroto Yoshida et al.   SYNTHESIS-STUTTGART

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

Palladium-Catalyzed 1,1-Difunctionalization of Ethylene

(2012) Vaneet Saini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Introduction to Frontiers in Transition Metal Catalyzed Reactions (and a Brief Adieu)

(2011) John A. Gladysz   CHEMICAL REVIEWS

The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

(2011) Stephen D. Roughley et al.   JOURNAL OF MEDICINAL CHEMISTRY

Precise Isomerization Polymerization of Alkenylcyclohexanes: Stereoregular Polymers Containing Six-Membered Rings along the Polymer Chain

(2011) Daisuke Takeuchi   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Intermolecular Difunctionalization of Terminal Alkenes with Organostannanes and Molecular Oxygen

(2009) Kaveri Balan Urkalan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2

(2009) Laura T. Kliman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Intercepting Heck Intermediates:  Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes

(2008) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY