Escape from Palladium: Nickel-Catalyzed Catellani Annulation

Recent Advances in C(sp3)–C(sp3) Cross-Coupling Chemistry: A Dominant Performance of Nickel Catalysts

(2022) Ramagonolla Kranthikumar   ORGANOMETALLICS

Hydrocarbon ladder polymers with ultrahigh permselectivity for membrane gas separations

(2022) Holden W. H. Lai et al.   SCIENCE

Recent Advances in Non-Precious Metal Catalysis

(2022) Hao Wu et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Modular Entry to Functionalized Tetrahydrobenzo[b]azepines via the Palladium/Norbornene Cooperative Catalysis Enabled by a C7-Modified Norbornene

(2021) Xin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Ipso/Ortho Difunctionalization of Aryl Bromides with Alkynes and Alkyl Bromides via a Vinyl-to-Aryl 1,4-Hydride Shift

(2021) Yuli He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Cyclobutanation of Aryl Sulfonates through both C–O and C–H Cleavage

(2020) Liangwei Zhang et al.   ORGANOMETALLICS

Facile Synthesis and Study of Microporous Catalytic Arene-Norbornene Annulation–Tröger’s Base Ladder Polymers for Membrane Air Separation

(2020) Xiaohua Ma et al.   ACS Macro Letters

Remote sp2 C–H Carboxylation via Catalytic 1,4-Ni Migration with CO2

(2020) Marino Börjesson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium/Norbornene-Catalyzed Indenone Synthesis from Simple Aryl Iodides: Concise Syntheses of Pauciflorol F and Acredinone A

(2019) Feipeng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-Step Synthesis of a Less-Aggregated Water-Soluble Poly(p-phenylene ethynylene) with Meta Side Chains via Palladium/Norbornene Cooperative Catalysis

(2019) Ki-Young Yoon et al.   MACROMOLECULES

Microporous Polyimides from Ladder Diamines Synthesized by Facile Catalytic Arene–Norbornene Annulation as High-Performance Membranes for Gas Separation

(2019) Mahmoud A. Abdulhamid et al.   CHEMISTRY OF MATERIALS

Nickel-Catalyzed Asymmetric Reductive Diarylation of Vinylarenes

(2019) David Anthony et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/Norbornene Cooperative Catalysis

(2019) Jianchun Wang et al.   CHEMICAL REVIEWS

1,4‐Migration of Transition Metals in Organic Synthesis

(2019) Abdur Rahim et al.   CHINESE JOURNAL OF CHEMISTRY

C–H Activation versus Ring Opening and Inner- versus Outer-Sphere Concerted Metalation–Deprotonation in Rh(III)-Catalyzed Oxidative Coupling of Oxime Ether and Cyclopropanol: A Density Functional Theory Study

(2019) Ran Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

Tuning the Molecular Weights, Chain Packing, and Gas-Transport Properties of CANAL Ladder Polymers by Short Alkyl Substitutions

(2019) Holden W. H. Lai et al.   MACROMOLECULES

Modular and regioselective synthesis of all-carbon tetrasubstituted olefins enabled by an alkenyl Catellani reaction

(2019) Jianchun Wang et al.   Nature Chemistry

Modular In Situ Functionalization Strategy: Multicomponent Polymerization by Palladium/Norbornene Cooperative Catalysis

(2018) Ki-Young Yoon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

(2018) Jianchun Wang et al.   Nature Chemistry

The Pd(II)-Initiated Catellani-type Reactions

(2018) Qianghui Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinaphthobenzo[1,2:4,5]dicyclobutadiene: Antiaromatic and Orthogonally Tunable Electronics and Packing

(2018) Zexin Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Pharmaceutical Industry Perspective on Sustainable Metal Catalysis

(2018) John D. Hayler et al.   ORGANOMETALLICS

Development of New Electrophiles in Palladium/Norbornene-Catalyzed ortho-Functionalization of Aryl Halides

(2018) Zhenhua Gu et al.   SYNLETT

Carboxylate Ligand-Exchanged Amination/C(sp3)–H Arylation Reaction via Pd/Norbornene Cooperative Catalysis

(2018) Bo-Sheng Zhang et al.   ACS Catalysis

Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)2 and Discovery of Fe(OTf)3 as a Highly Effective Cocatalyst

(2017) Dian Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Streamlined Synthesis of Polycyclic Conjugated Hydrocarbons Containing Cyclobutadienoids via C–H Activated Annulation and Aromatization

(2017) Zexin Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of [3]Naphthylenes and Tuning of Their Antiaromaticity

(2017) Zexin Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbonylative Rearrangement of Norbornadiene via Dinuclear Carbon–Carbon Oxidative Addition

(2017) Douglas R. Hartline et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Study of Ni-Catalyzed C–H Functionalization: Factors That Control the Competition of Oxidative Addition and Radical Pathways

(2017) Humair M. Omer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation

(2016) Nicola Della Ca’ et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytically Asymmetric Pd/Norbornene Catalysis: Enantioselective Synthesis of (+)-Rhazinal, (+)-Rhazinilam, and (+)-Kopsiyunnanine C1–3

(2016) Kun Zhao et al.   ORGANIC LETTERS

OrthoCH Acylation of Aryl Iodides by Palladium/Norbornene Catalysis

(2015) Zhe Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Oxidative Coupling of Primary Amines with Internal Alkynes through CH Bond Activation: Scope and Mechanistic Studies

(2015) Sara Ruiz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Factors Impacting the Mechanism of the Mono-N-Protected Amino Acid Ligand-Assisted and Directing-Group-Mediated C–H Activation Catalyzed by Pd(II) Complex

(2015) Brandon E. Haines et al.   ACS Catalysis

Nickel: The “Spirited Horse” of Transition Metal Catalysis

(2015) Valentine P. Ananikov   ACS Catalysis

Total synthesis of (+)-kopsihainanine A

(2014) Masaya Mizutani et al.   CHEMICAL COMMUNICATIONS

Synthesis of Pyrrolophenanthridine Alkaloids Based on C(sp3)H and C(sp2)H Functionalization Reactions

(2014) Chihiro Tsukano et al.   Chemistry-An Asian Journal

Application of the Palladium-Catalysed Norbornene-Assisted Catellani Reaction Towards the Total Synthesis of (+)-Linoxepin and Isolinoxepin

(2014) Zafar Qureshi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanisms and Reactivity Differences for Cycloaddition of Anhydride to Alkyne Catalyzed by Palladium and Nickel Catalysts: Insight from Density Functional Calculations

(2014) Hujun Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of Rigid Ladder Polymers via Palladium Catalyzed Annulation

(2014) Sheng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Total Synthesis of (+)-Linoxepin by Utilizing the Catellani Reaction

(2013) Harald Weinstabl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Chemoselective Catellani Ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal

(2013) Xianwei Sui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Regioselective 2-Alkylation of Indoles via a Norbornene-Mediated C–H Activation: Mechanism and Applications

(2012) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal Synthesis of Nitidine and NK109 via Palladium-Catalyzed Domino Direct Arylation/N-Arylation of Aryl Triflates

(2011) Mathieu Blanchot et al.   ORGANIC LETTERS

Electrophilic, Ambiphilic, and Nucleophilic C−H Bond Activation: Understanding the Electronic Continuum of C−H Bond Activation Through Transition-State and Reaction Pathway Interaction Energy Decompositions

(2010) Daniel H. Ess et al.   ORGANOMETALLICS

Bidentate phosphines as ligands in the palladium-catalyzed intramolecular arylation: the intermolecular base-assisted proton abstraction mechanism

(2008) Sergio Pascual et al.   TETRAHEDRON