Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation

(2016) Nicola Della Ca’ et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Norbornene-Mediated Tandem ortho-C–H-Amination/ipso-C–I-Cyanation of Iodoarenes: Regiospecific Synthesis of 2-Aminobenzonitrile

(2016) Biju Majhi et al.   ORGANIC LETTERS

Palladium-Catalyzed Norbornene-Mediated Tandem Amination/Cyanation Reaction: A Method for the Synthesis of ortho-Aminated Benzonitriles

(2016) Bo Luo et al.   ORGANIC LETTERS

Palladium-Catalyzed Alkynylation and Concomitant ortho Alkylation of Aryl Iodides

(2016) Chuanhu Lei et al.   ACS Catalysis

Reagent-Enabled ortho -Alkoxycarbonylation of Aryl Iodides via Palladium/Norbornene Catalysis

(2016) Jianchun Wang et al.   Chem

Palladium-Catalyzed One-Pot Consecutive Amination and Sonogashira Coupling for Selective Synthesis of 2-Alkynylanilines

(2015) Shanfei Pan et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Catellaniortho-Acylation Reaction: An Efficient and Regiospecific Synthesis of Diaryl Ketones

(2015) Yunze Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

OrthoCH Acylation of Aryl Iodides by Palladium/Norbornene Catalysis

(2015) Zhe Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Heteroarylation and Concomitantortho-Alkylation of Aryl Iodides

(2015) Chuanhu Lei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Enabled Meta-C–H Alkylation and Arylation Using a Modified Norbornene

(2015) Peng-Xiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Amine-Directed Meta-Selective C–H Arylation via Pd/Norbornene Catalysis

(2015) Zhe Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular C–H Functionalization Cascade of Aryl Iodides

(2015) Hang Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-enabled meta-C–H activation using a transient mediator

(2015) Xiao-Chen Wang et al.   NATURE

Palladium-catalysed norbornene-mediated C–H functionalization of arenes

(2015) Juntao Ye et al.   Nature Chemistry

Decarboxylative Alkynyl Termination of Palladium-Catalyzed Catellani Reaction: A Facile Synthesis of α-Alkynyl Anilines via Ortho C–H Amination and Alkynylation

(2015) Fenggang Sun et al.   ORGANIC LETTERS

Palladium-Catalyzed Acylation/Alkenylation of Aryl Iodide: A Domino Approach Based on the Catellani–Lautens Reaction

(2015) Ping-Xin Zhou et al.   ACS Catalysis

Palladium-Catalyzed/Norbornene-Mediated CH Activation/N-Tosylhydrazone Insertion Reaction: A Route to Highly Functionalized Vinylarenes

(2014) Ping-Xin Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium/Norbornene-Mediated Tandem CH Amination/CI Alkenylation Reaction of Aryl Iodides with Secondary CyclicO-Benzoyl Hydroxylamines and Activated Terminal Olefins

(2014) Zhi-Yuan Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Biaryl Tertiary Amines through Pd/Norbornene Joint Catalysis in a Remote C–H Amination/Suzuki Coupling Reaction

(2014) Changqing Ye et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed/Norbornene-Mediated ortho-Amination/N-Tosylhydrazone Insertion Reaction: An Approach to the Synthesis of ortho-Aminated Vinylarenes

(2014) Ping-Xin Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Palladium/Norbornene Catalytic System: Chelation as a Tool To Control Regioselectivity of Pd(IV) Reductive Elimination

(2013) Max Malacria et al.   JOURNAL OF ORGANIC CHEMISTRY

Ortho vs Ipso: Site-Selective Pd and Norbornene-Catalyzed Arene C–H Amination Using Aryl Halides

(2013) Zhe Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Mechanistic Studies of Pd-Catalyzed Regioselective Aryl CH Bond Functionalization with Strained Alkenes: Origin of Regioselectivity

(2011) David I. Chai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Of the Ortho Effect in Palladium/Norbornene-Catalyzed Reactions: A Theoretical Investigation

(2011) Giovanni Maestri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Reductiveortho-Arylation: Evidence for the Decomposition of 1,2-Dimethoxyethane and Subsequent Arylpalladium(II) Reduction

(2010) Andrew Martins et al.   ORGANIC LETTERS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Catalytic Sequential Reactions Involving Palladacycle-Directed Aryl Coupling Steps

(2008) Marta Catellani et al.   ACCOUNTS OF CHEMICAL RESEARCH

Application of Secondary Alkyl Halides to a Domino Aryl Alkylation Reaction for the Synthesis of Aromatic Heterocycles

(2008) Alena Rudolph et al.   JOURNAL OF ORGANIC CHEMISTRY

Aromaticortho-Benzylation Reveals an Unexpected Reductant

(2008) Andrew Martins et al.   ORGANIC LETTERS