Stereogenic-at-Cobalt(III) Complex Catalyzed Halocyclization of Alkynes: Enantioselective Access to Axially Chiral ortho-Halo-C2-indoles

An Isolable Vinylidene ortho‐Quinone Methide: Synthesis, Structure and Reactivity

(2022) Hong Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Enantioselective C–H Arylation of Indoles

(2022) Nicolas Jacob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atroposelective Construction of Nine‐Membered Carbonate Bridged Biaryls

(2022) Shiqi Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Details of Asymmetric Bromocyclization with BINAP Monoxide: Identification of Chiral Proton-Bridged Bisphosphine Oxide Complex and Its Application to Parallel Kinetic Resolution

(2022) Kenji Yamashita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic atroposelective construction of axially chiral N, N- and N, S-1,2-azoles through novel ring formation approach

(2022) Yu Chang et al.   Nature Communications

Catalytic Chemo-, Regio-, Diastereo-, and Enantioselective Bromochlorination of Unsaturated Systems Enabled by Lewis Base-Controlled Chloride Release

(2022) Alexandra E. Lubaev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Atropisomers via Vinylidene ortho-Quinone Methides (VQMs)

(2022) Wenling Qin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Atroposelective Synthesis of Indole Derivatives Bearing Axial Chirality: Strategies and Applications

(2022) Hong-Hao Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Intermolecular Iodinative Difunctionalization of Allylic Sulfonamides Enabled by Organosulfide Catalysis: Modular Entry to Iodinated Chiral Molecules

(2022) Lihao Liao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Ugi and Ugi-azide reactions catalyzed by anionic stereogenic-at-cobalt(III) complexes

(2022) Bing-Bing Sun et al.   Nature Communications

Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications

(2021) Osamu Kitagawa   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Enantioselective Construction of Chiral Azepine Skeleton Bearing Multiple‐Stereogenic Elements

(2021) Shengli Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Urea group-directed organocatalytic asymmetric versatile dihalogenation of alkenes and alkynes

(2021) San Wu et al.   Nature Catalysis

Diversity-Oriented Enantioselective Construction of Atropisomeric Heterobiaryls and N -Aryl Indoles via Vinylidene Ortho -Quinone Methides

(2021) Da Xu et al.   CCS Chemistry

Atroposelective sp 3 C—H Coupling for Kinetic Resolution of Thioanilide Atropisomers

(2021) Hua‐Jie Jiang et al.   CHINESE JOURNAL OF CHEMISTRY

Anionic Chiral Co(III) Complexes Mediated Asymmetric Halocyclization─Synthesis of 5-Halomethyl Pyrazolines and Isoxazolines

(2021) Xiao-Bao Wu et al.   ORGANIC LETTERS

The applications of catalytic asymmetric halocyclization in natural product synthesis

(2021) Jiahang Yan et al.   Organic Chemistry Frontiers

Chiral-Phosphoric-Acid-Catalyzed Atroposelective C-H Amination of Arenes

(2020) Bin Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Synthesis of Axially Chiral 3-Arylindoles by Copper-Catalyzed Asymmetric Cross-Coupling of Indoles with Quinones and Naphthoquinones

(2020) Chao-Chao Xi et al.   ORGANIC LETTERS

Design and Atroposelective Construction of IAN analogues by Organocatalytic Asymmetric Heteroannulation of Alkynes

(2020) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Naphthyl-C2-Indole as Scaffold for Phosphine Organocatalysis: Application in Asymmetric Formal [4 + 2] Cycloaddition Reactions

(2020) Tingting He et al.   ORGANIC LETTERS

Atropselective Dibrominations of a 1,1’-Disubstituted 2,2’-Biindolyl With Diverging Point-to-Axial Asymmetric Inductions. Deriving Diphosphane Ligands for Asymmetric Catalysis

(2019) Reinhard Brückner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of N–C Axial Chirality through Atroposelective C–H Olefination of N-Arylindoles by Palladium/Amino Acid Cooperative Catalysis

(2019) Jitan Zhang et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Annulation of ortho -Alkynylanilines: Synthesis of Axially Chiral Naphthyl-C2-indoles

(2019) Lei Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Synthesis of Indole-Based Chiral Heterocycles: Strategies, Reactions, and Outreach

(2019) Yu-Chen Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Enantioselective Cacchi Reaction: Asymmetric Synthesis of Axially Chiral 2,3-Disubstituted Indoles

(2019) Yu-Ping He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Bromocyclization of Tryptamines Induced by Chiral Co(III)-Complex-Templated Brønsted Acids under an Air Atmosphere

(2018) Kun Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Enantioselective Construction of Axially Chiral Sulfone-Containing Styrenes

(2018) Shiqi Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalysis with octahedral stereogenic-at-metal complexes featuring chiral ligands

(2018) Thomas Cruchter et al.   COORDINATION CHEMISTRY REVIEWS

Enantioselective intermolecular iodoacetalization of enol ethers catalyzed by chiral Co(III)-complex-templated Brønsted acids

(2018) Na Li et al.   TETRAHEDRON LETTERS

Asymmetric Catalytic Halofunctionalization of α,β-Unsaturated Carbonyl Compounds

(2018) Yunfei Cai et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic asymmetric arylation of indoles enabled by azo groups

(2017) Liang-Wen Qi et al.   Nature Chemistry

Enantioselective Synthesis of Indole-Based Biaryl Atropisomers via Palladium-Catalyzed Dynamic Kinetic Intramolecular C–H Cyclization

(2017) Congfa He et al.   ACS Catalysis

Design and Enantioselective Construction of Axially Chiral Naphthyl-Indole Skeletons

(2016) Hong-Hao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monomeric Cinchona Alkaloid-Based Catalysts for Highly Enantioselective Bromolactonisation of Alkynes

(2016) Michael Wilking et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sodium Salts of Anionic Chiral Cobalt(III) Complexes as Catalysts of the Enantioselective Povarov Reaction

(2015) Jie Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral ion-pair organocatalyst promotes highly enantioselective 3-exo iodo-cycloetherification of allyl alcohols

(2015) Zhigao Shen et al.   Chemical Science

Asymmetric Catalysis Mediated by the Ligand Sphere of Octahedral Chiral-at-Metal Complexes

(2014) Lei Gong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Chlorocyclization of Indole-3-yl-benzamides for the Construction of Fused Indolines

(2014) Qin Yin et al.   ORGANIC LETTERS

Recent advances in stereoselective bromofunctionalization of alkenes using N-bromoamide reagents

(2013) Chong Kiat Tan et al.   CHEMICAL COMMUNICATIONS

Enantioselective, Desymmetrizing Bromolactonization of Alkynes

(2013) Michael Wilking et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aza-Diels–Alder reaction catalyzed by novel chiral metalocomplex Brønsted acids

(2013) Victor I. Maleev et al.   TETRAHEDRON-ASYMMETRY

Catalytic Aminohalogenation of Alkenes and Alkynes

(2013) Sherry R. Chemler et al.   ACS Catalysis

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Asymmetric Halofunctionalization of Alkenes-A Critical Perspective

(2012) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral-at-metal complexes and their catalytic applications in organic synthesis

(2012) Eike B. Bauer   CHEMICAL SOCIETY REVIEWS

New Catalytic Approaches towards the Enantioselective Halogenation of Alkenes

(2012) Ulrich Hennecke   Chemistry-An Asian Journal

N-N-Coupled Indolo-sesquiterpene Atropo-Diastereomers from a Marine-Derived Actinomycete

(2012) Qingbo Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Synthesis of Heterocycles via Electrophilic Cyclization of Alkynes Containing Heteroatom

(2011) Benhur Godoi et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Synthesis of Atropisomeric Indoles with an NC Chiral Axis

(2010) Nobutaka Ototake et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Bromolactonization of Conjugated (Z)-Enynes

(2010) Wei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral anion-mediated asymmetric ion pairing chemistry

(2009) Jérôme Lacour et al.   CHEMICAL COMMUNICATIONS

Potassium and silver chiral cobaltate(III) complexes as precatalysts for asymmetric C–C bond formation

(2008) Yuri N. Belokon et al.   TETRAHEDRON-ASYMMETRY