Mechanistic Details of Asymmetric Bromocyclization with BINAP Monoxide: Identification of Chiral Proton-Bridged Bisphosphine Oxide Complex and Its Application to Parallel Kinetic Resolution

Phosphorus-Based Catalysis

(2021) Changmin Xie et al.   ACS Central Science

A Catalyst-Controlled Enantiodivergent Bromolactonization

(2021) Yuk-Cheung Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Uniting Amide Synthesis and Activation by PIII/PV–Catalyzed Serial Condensation: Three-Component Assembly of 2-Amidopyridines

(2021) Jeffrey M. Lipshultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

PIII/PV═O-Catalyzed Intermolecular N–N Bond Formation: Cross-Selective Reductive Coupling of Nitroarenes and Anilines

(2021) Gen Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Urea group-directed organocatalytic asymmetric versatile dihalogenation of alkenes and alkynes

(2021) San Wu et al.   Nature Catalysis

Structure Dependence in Asymmetric Deprotonative Fluorination and Fluorocyclization Reactions of Allylamine Derivatives with Linked Binaphthyl Dicarboxylate Phase-Transfer Catalyst

(2021) Tomoki Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to Chiral Bisphenol Ligands (BPOL) through Desymmetrizing Asymmetric Ortho-Selective Halogenation

(2020) Xiaodong Xiong et al.   Chem

Asymmetric Dearomative Fluorination of 2‐Naphthols with Dicarboxylate Phase‐Transfer Catalyst

(2020) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Iodoesterification of Simple Alkenes

(2020) Takayoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorofunctionalizations of C–C Multiple Bonds and C–H Bonds

(2020) Hiromichi Egami   CHEMICAL & PHARMACEUTICAL BULLETIN

Mechanistic Insights into the Origin of Stereoselectivity in an Asymmetric Chlorolactonization Catalyzed by (DHQD)2PHAL

(2020) Roozbeh Yousefi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Improved PIII/PV═O-Catalyzed Reductive C–N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps

(2020) Gen Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Secondary Phosphine Oxides: Bifunctional Ligands in Catalysis

(2020) Piet W. N. M. Leeuwen et al.   ChemCatChem

Halogen-Bonding Interaction between I2 and N-Iodosuccinimide in Lewis Base-Catalyzed Iodolactonization

(2020) Takahiro Horibe et al.   ORGANIC LETTERS

Asymmetric Dearomatizing Fluoroamidation of Indole Derivatives with Dianionic Phase-Transfer Catalyst

(2020) Hiromichi Egami et al.   ORGANIC LETTERS

Di(hydroperoxy)cycloalkane Adducts of Triarylphosphine Oxides: A Comprehensive Study Including Solid-State Structures and Association in Solution

(2020) Fabian F. Arp et al.   INORGANIC CHEMISTRY

Driving Recursive Dehydration by PIII/PV Catalysis: Annulation of Amines and Carboxylic Acids by Sequential C–N and C–C Bond Formation

(2019) Morgan Lecomte et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Parallel Kinetic Resolution of Unsymmetrical Acyclic Aliphatic syn-1,3-Diols

(2019) Hui Yang et al.   ORGANIC LETTERS

Enantioselective 5-exo-Fluorocyclization of Ene-Oximes

(2019) Taiki Rouno et al.   MOLECULES

Redox-neutral organocatalytic Mitsunobu reactions

(2019) Rhydian H. Beddoe et al.   SCIENCE

Enantioselective reactions catalyzed by phosphine oxides

(2019) Tahar Ayad et al.   TETRAHEDRON

Phosphetane Oxides as Redox Cycling Catalysts in the Catalytic Wittig Reaction at Room Temperature

(2019) Lars Longwitz et al.   ACS Catalysis

Recent advances in asymmetric phosphine oxide catalysis

(2019) Shunsuke Kotani et al.   TETRAHEDRON LETTERS

Reduction of Activated Alkenes by PIII /PV Redox Cycling Catalysis

(2019) Lars Longwitz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective C−H Olefination of Diaryl Sulfoxides through Parallel Kinetic Resolution and Desymmetrization

(2018) Yu-Chao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Nelfinavir via Asymmetric Bromocyclization of Bisallylic Amide

(2018) Yoshihiro Nagao et al.   JOURNAL OF ORGANIC CHEMISTRY

Dianionic Phase-Transfer Catalyst for Asymmetric Fluoro-cyclization

(2018) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Halo-oxy- and Halo-azacyclizations Induced by Chiral Amidophosphate Catalysts and Halo-Lewis Acids

(2018) Yanhui Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of (+)-Disparlure via Enantioselective Iodolactonization

(2018) Daniel W. Klosowski et al.   ORGANIC LETTERS

A Catalytic Enantioselective Iodocyclization Route to Dihydrooxazines

(2018) Rahul Suresh et al.   ORGANIC LETTERS

Dehydration of Amides to Nitriles under Conditions of a Catalytic Appel Reaction

(2018) Sergei A. Shipilovskikh et al.   ORGANIC LETTERS

Enantioselective Bromocyclization of Allylic Amides Mediated by Phosphorus Catalysis

(2018) Yoshitaka Hamashima et al.   SYNLETT

Thiourea–I2 as Lewis Base–Lewis Acid Cooperative Catalysts for Iodochlorination of Alkene with In Situ-Generated I–Cl

(2018) Takahiro Horibe et al.   ACS Catalysis

Silicon-based Bulky Group−Tuned Parallel Kinetic Resolution in Copper-Catalyzed 1,3-Dipolar Additions

(2018) Yang Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Enantioenriched Bromohydrins via Divergent Reactions of Racemic Intermediates from Anchimeric Oxygen Borrowing

(2018) Yi-Ming Cao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Aldol Reactions of Unprotected Carboxylic Acids under Phosphine Oxide Catalysis

(2018) Shunsuke Kotani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Fluorination of Cyclic Tetrasubstituted Alkenes with a Pendant Amide Groups under Dianionic Phase-Transfer Catalysis

(2018) Tomoki Niwa et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Asymmetric Catalytic Halofunctionalization of α,β-Unsaturated Carbonyl Compounds

(2018) Yunfei Cai et al.   JOURNAL OF ORGANIC CHEMISTRY

NMR Quantification of Hydrogen-Bond-Activating Effects for Organocatalysts including Boronic Acids

(2018) Kayla M. Diemoz et al.   JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Reductive C–N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis

(2018) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Organocatalytic Amine-Isocyanate Capture-Cyclization: Regioselective Alkene Iodoamination for the Synthesis of Chiral Cyclic Ureas

(2018) Thomas J. Struble et al.   ACS Catalysis

Highly Regio- and Enantioselective Vicinal Dihalogenation of Allyl Amides

(2017) Bardia Soltanzadeh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Bromocyclization of Polyenes

(2017) Ramesh C. Samanta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Asymmetric Haloazidation of α,β-Unsaturated Ketones: Construction of Organic Azides with Two Vicinal Stereocenters

(2017) Pengfei Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biphilic Phosphetane Catalyzes N–N Bond-Forming Cadogan Heterocyclization via PIII/PV═O Redox Cycling

(2017) Trevor V. Nykaza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrative glycosylation with cyclic phosphonium anhydrides

(2017) Rajendar Dyapa et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed Asymmetric Cycloisomerization and Parallel Kinetic Resolution of Racemic Oxabicycles

(2016) Charles C. J. Loh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Bromocyclization of Allylic Amides with a P/P=O Double-Site Lewis Base Catalyst

(2016) Yuji Kawato et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Synthesis of Multisubstituted Benzimidazoles via Sequential Ugi and Catalytic Aza-Wittig Reaction Starting from 2-Aminobenzoyl Azides

(2016) Yan-Mei Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Difunctionalization of Alkenes Using 1-Chloro-1,2-benziodoxol-3-(1H)-one

(2016) Hiromichi Egami et al.   JOURNAL OF ORGANIC CHEMISTRY

Iodoaminations of Alkenes

(2016) Thomas Wirth et al.   SYNTHESIS-STUTTGART

Highly Stereoselective Intermolecular Haloetherification and Haloesterification of Allyl Amides

(2015) Bardia Soltanzadeh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Iodocyclization ofN-Tosyl Alkenamides using Aminoiminophenoxy Copper Carboxylate: A Concise Synthesis of Chiral 8-Oxa-6-Azabicyclo[3.2.1]octanes

(2015) Takayoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbamate-Catalyzed Enantioselective Bromolactamization

(2015) Yi An Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recyclable Poly-Zn3(OAc)4-3,3′-Bis(aminoimino)binaphthoxide Catalyst for Asymmetric Iodolactonization

(2015) Takayoshi Arai et al.   ChemCatChem

Bromination of Olefins with HBr and DMSO

(2015) Megha Karki et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Small Molecule Synthesis by Carbon Dioxide Fixation using a Dual Brønsted Acid/Base Organocatalyst

(2015) Brandon A. Vara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Fluorolactonization with a Bifunctional Hydroxyl Carboxylate Catalyst

(2015) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Bromocyclization of Allylic Amides Catalyzed by BINAP Derivatives

(2015) Yuji Kawato et al.   ORGANIC LETTERS

Cooperative Activation with Chiral Nucleophilic Catalysts andN-Haloimides: Enantioselective Iodolactonization of 4-Arylmethyl-4-pentenoic Acids

(2014) Hidefumi Nakatsuji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A trinuclear Zn3(OAc)4-3,3′-bis(aminoimino)binaphthoxide complex for highly efficient catalytic asymmetric iodolactonization

(2014) Takayoshi Arai et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Stereoselective Iodoamination of Alkenes

(2014) Pushpak Mizar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Characterisation, and Organocatalytic Activity of Chiral Tetrathiahelicene Diphosphine Oxides

(2014) Silvia Cauteruccio et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regiodivergent Kinetic Resolution of Terminal and Internal rac-Aziridines with Malonates under Dinuclear Schiff Base Catalysis

(2014) Yingjie Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid Catalyzed Phosphoramidic Acid Additions to Alkenes: Diastereo- and Enantioselective Halogenative Cyclizations for the Synthesis of C- and P-Chiral Phosphoramidates

(2014) Yasunori Toda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Bromoetherification and Desymmetrization of Olefinic 1,3-Diols with C2-Symmetric Sulfides

(2014) Zhihai Ke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in asymmetric intra- and intermolecular halofunctionalizations of alkenes

(2014) Yi An Cheng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent Progress in the Asymmetric Intermolecular Halogenation of Alkenes

(2014) Ling Zhou et al.   SYNTHESIS-STUTTGART

Organic reactions mediated by tetrachlorosilane

(2014) Sergio Rossi et al.   TETRAHEDRON

Spiro[4,4]-1,6-Nonadiene-Based Diphosphine Oxides in Lewis Base Catalyzed Asymmetric Double-Aldol Reactions

(2013) Panke Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Multiple Stereocenters by Using a Double Aldol Reaction

(2013) Yasushi Shimoda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Iodoetherification of Oximes

(2013) Chandra Bhushan Tripathi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Bromocyclization of Tryptamines and Its Application in the Synthesis of (−)-Chimonanthine

(2013) Weiqing Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atropisomeric Chiral Dienes in Asymmetric Catalysis:C2-Symmetric (Z,Z)-2,3-Bis[1-(diphenylphosphinyl)ethylidene]tetralin as a Highly Active Lewis Base Organocatalyst

(2013) Masamichi Ogasawara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in stereoselective bromofunctionalization of alkenes using N-bromoamide reagents

(2013) Chong Kiat Tan et al.   CHEMICAL COMMUNICATIONS

An Unusual Triphenylphosphine Oxide Catalyzed Stereoselective 1,3-Dichlorination of Unsaturated Ketoesters

(2013) Tian-Yang Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organophosphorus Catalysis to Bypass Phosphine Oxide Waste

(2013) Henri A. van Kalkeren et al.   ChemSusChem

Enantiomerically Pure Bithiophene Diphosphine Oxides as Catalysts for Direct Double Aldol Reactions

(2013) Andrea Genoni et al.   CHIRALITY

Stereoselective Bromofunctionalization of Alkenes

(2013) Chong Kiat Tan et al.   CHIRALITY

Stereocontrolled Total Synthesis of Sphingofungin E

(2013) Kazutada Ikeuchi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Progress in Organocatalytic Asymmetric Halocyclization

(2013) Hiromichi Fujioka et al.   HETEROCYCLES

Enantioselective, Desymmetrizing Bromolactonization of Alkynes

(2013) Michael Wilking et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Resolution of Unsaturated Amides in a Chlorocyclization Reaction: Concomitant Enantiomer Differentiation and Face Selective Alkene Chlorination by a Single Catalyst

(2013) Arvind Jaganathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Relationship between Chemical Structure and Supramolecular Effective Molarity for Formation of Intramolecular H-Bonds

(2013) Hongmei Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Bromolactonization Using anS-Alkyl Thiocarbamate Catalyst

(2012) Xiaojian Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Asymmetric Halofunctionalization of Alkenes-A Critical Perspective

(2012) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Catalytic Approaches towards the Enantioselective Halogenation of Alkenes

(2012) Ulrich Hennecke   Chemistry-An Asian Journal

Switching between halogen- and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide

(2012) Se Ye Oh et al.   CRYSTENGCOMM

Enantioselective Halocyclization Using Reagents Tailored for Chiral Anion Phase-Transfer Catalysis

(2012) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional Catalyst Promotes Highly Enantioselective Bromolactonizations To Generate Stereogenic C–Br Bonds

(2012) Daniel H. Paull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Achiral Counterion Control of Enantioselectivity in a Brønsted Acid-Catalyzed Iodolactonization

(2012) Mark C. Dobish et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Iodolactonization Utilizing Chiral Squaramides

(2012) Jørn E. Tungen et al.   ORGANIC LETTERS

Catalytic Desymmetrization of Cyclohexadienes by Asymmetric Bromolactonization

(2012) Kazutada Ikeuchi et al.   ORGANIC LETTERS

Thermodynamic and hydrogen-bond basicity of phosphine oxides: Effect of the ring strain

(2012) Cristina Trujillo et al.   Computational and Theoretical Chemistry

A Catalytic Asymmetric Chlorocyclization of Unsaturated Amides

(2011) Arvind Jaganathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent reactions on racemic mixtures

(2011) Laura C. Miller et al.   CHEMICAL SOCIETY REVIEWS

Current Methods for Asymmetric Halogenation of Olefins

(2011) Alejandro Castellanos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Phosphorus(V)-Mediated Nucleophilic Substitution Reactions: Development of a Catalytic Appel Reaction

(2011) Ross M. Denton et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Bromoaminocyclization Using Amino–Thiocarbamate Catalysts

(2011) Ling Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Halolactonizations: Strategies of Halogen Activation

(2011) Ying-Yeung Yeung et al.   SYNLETT

Asymmetric Bromolactonization Catalyzed by a C3-Symmetric Chiral Trisimidazoline

(2010) Kenichi Murai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tertiary Aminourea-Catalyzed Enantioselective Iodolactonization

(2010) Gemma E. Veitch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Halocyclization Reactions for the Synthesis of Chiral Cyclic Compounds

(2010) Guofei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Absolute Configurational Stability of Bromonium and Chloronium Ions

(2010) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones via Soft Lewis Acid/Hard Brønsted Base/Hard Lewis Base Catalysis

(2010) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Organocatalytic Asymmetric Chlorolactonization

(2010) Daniel C. Whitehead et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Bromolactonization of Conjugated (Z)-Enynes

(2010) Wei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral phosphine oxides in present-day organocatalysis

(2010) Maurizio Benaglia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalysis of Phosphorus(V)-Mediated Transformations: Dichlorination Reactions of Epoxides Under Appel Conditions

(2010) Ross M. Denton et al.   ORGANIC LETTERS

Recycling the Waste: The Development of a Catalytic Wittig Reaction

(2009) Christopher J. O'Brien et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenes in Asymmetric Catalysis: Asymmetric Ring Opening ofmeso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides

(2009) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiodivergent Ring Opening of Chiral Aziridines

(2009) B. Wu et al.   SCIENCE

Enantioselective Iodolactonizations of 4-Pentenoic Acid Derivatives Mediated by Chiral Salen-Co(II) Complex

(2009) Lianxun Gao et al.   SYNLETT

Novel Chiral Biheteroaromatic Diphosphine Oxides for Lewis Base Activation of Lewis Acids in Enantioselective Allylation and Epoxide Opening

(2008) Valentina Simonini et al.   ADVANCED SYNTHESIS & CATALYSIS

Cinchona Alkaloid Catalyzed Enantioselective Fluorination of Allyl Silanes, Silyl Enol Ethers, and Oxindoles

(2008) Takehisa Ishimaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Catalysis in Organic Synthesis

(2008) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic aza-Wittig Cyclizations for Heteroaromatic Synthesis

(2008) Stephen P. Marsden et al.   ORGANIC LETTERS