Iron- and Ruthenium-Catalyzed C–N Bond Formation Reactions. Reactive Metal Imido/Nitrene Intermediates

Access to β-Lactams via Iron-Catalyzed Olefin Oxyamidation Enabled by the π-Accepting Phthalocyanine Ligand

(2022) Jeonguk Kweon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer

(2021) Yang Yang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source

(2021) Seung Youn Hong et al.   ACCOUNTS OF CHEMICAL RESEARCH

RuV‐Acylimido Intermediate in [RuIV(Por)Cl2]‐Catalyzed C–N Bond Formation. Spectroscopic Characterization, Reactivity, and Catalytic Reactions

(2021) Danyan Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereogenic-at-Iron Catalysts with a Chiral Tripodal Pentadentate Ligand

(2021) Philipp S. Steinlandt et al.   ACS Catalysis

Electron-Transfer and Redox Reactivity of High-Valent Iron Imido and Oxo Complexes with the Formal Oxidation States of Five and Six

(2020) Xiaoyan Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxazolones: Stable Substrates for the Catalytic Transfer of Acyl Nitrenes

(2020) Kaj M. van Vliet et al.   ACS Catalysis

Fe-catalyzed aziridination is governed by the electron affinity of the active imido-iron species

(2020) Guillaume Coin et al.   ACS Catalysis

Iron-Catalyzed Amination of Strong Aliphatic C(sp3)–H Bonds

(2020) Sandip Kumar Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst

(2020) Lucie Jarrige et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Robust Iron Catalyst System for Intramolecular C(sp 3 )−H Amidation Leading to γ‐Lactams

(2020) Jeonguk Kweon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular C(sp3)–H Bond Amination Strategies for the Synthesis of Saturated N-containing Heterocycles

(2020) Jiayu Zhang et al.   CHIMIA

An Effective [FeIII(TF4DMAP)Cl] Catalyst for C–H Bond Amination with Aryl and Alkyl Azides

(2019) Yi-Dan Du et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed Enantioselective γ-Lactams Formation by Intramolecular C–H Amidation of 1,4,2-Dioxazol-5-ones

(2019) Qi Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indoles from Alkynes and Aryl Azides: Scope and Theoretical Assessment of Ruthenium Porphyrin‐Catalyzed Reactions

(2019) Daniela Intrieri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nitrene Transfer Catalyzed by a Non-Heme Iron Enzyme and Enhanced by Non-Native Small-Molecule Ligands

(2019) Nathaniel W. Goldberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese-catalysed benzylic C(sp3)–H amination for late-stage functionalization

(2018) Joseph R. Clark et al.   Nature Chemistry

N-Heterocyclic Carbene Iron(III) Porphyrin-Catalyzed Intramolecular C(sp3 )-H Amination of Alkyl Azides

(2018) Ka-Pan Shing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Intramolecular C(sp3 )−H Amination of 2-Azidoacetamides

(2018) Zijun Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Iron-Catalyzed C-H Bond Amination via Iron Imido Intermediate

(2018) Peng Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Achieving One-Electron Oxidation of a Mononuclear Nonheme Iron(V)-Imido Complex

(2017) Seungwoo Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mononuclear Nonheme Iron(V)-Imido Complex

(2017) Seungwoo Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Spin Iron Imido Complexes Competent for C–H Bond Amination

(2017) Matthew J. T. Wilding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

(2017) Bidraha Bagh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective, intermolecular benzylic C–H amination catalysed by an engineered iron-haem enzyme

(2017) Christopher K. Prier et al.   Nature Chemistry

Catalytic C–H amination at its limits: challenges and solutions

(2017) Damien Hazelard et al.   Organic Chemistry Frontiers

Cutting-Edge and Time-Honored Strategies for Stereoselective Construction of C–N Bonds in Total Synthesis

(2016) Artur K. Mailyan et al.   CHEMICAL REVIEWS

Synthesis and catalytic activity of μ-oxo ruthenium(IV) porphyrin species to promote amination reactions

(2016) Paolo Zardi et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Characterization of Iron-Imido Species Relevant for N-Group Transfer Chemistry

(2016) Diana A. Iovan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile hydrogen atom transfer to iron(iii) imido radical complexes supported by a dianionic pentadentate ligand

(2016) Denis M. Spasyuk et al.   Chemical Science

Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

(2016) Alois Fürstner   ACS Central Science

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

A mechanistic investigation of the ruthenium porphyrin catalysed aziridination of olefins by aryl azides

(2015) P. Zardi et al.   DALTON TRANSACTIONS

Comparative Study of the Catalytic Amination of Benzylic C-H Bonds Promoted by Ru(TPP)(py)2and Ru(TPP)(CO)

(2015) Gabriele Manca et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Glycoporphyrin Catalysts for Efficient C–H Bond Aminations by Organic Azides

(2015) Giorgio Tseberlidis et al.   ORGANOMETALLICS

Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

(2015) Jiao Jiao et al.   ACS Catalysis

Elevated Catalytic Activity of Ruthenium(II)-Porphyrin-Catalyzed Carbene/Nitrene Transfer and Insertion Reactions with N-Heterocyclic Carbene Ligands

(2014) Ka-Ho Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium porphyrin catalyzed diimination of indoles with aryl azides as the nitrene source

(2014) Jinhu Wei et al.   CHEMICAL COMMUNICATIONS

Organic azides: “energetic reagents” for the intermolecular amination of C–H bonds

(2014) Daniela Intrieri et al.   CHEMICAL COMMUNICATIONS

Asymmetric Nitrene Transfer Reactions: Sulfimidation, Aziridination and C-H Amination Using Azide Compounds as Nitrene Precursors

(2014) Tatsuya Uchida et al.   CHEMICAL RECORD

Ruthenium Porphyrins with Axial π-Conjugated Arylamide and Arylimide Ligands

(2014) Siu-Man Law et al.   CHEMISTRY-A EUROPEAN JOURNAL

[Fe(F20TPP)Cl]-Catalyzed Amination with Arylamines and {[Fe(F20TPP)(NAr)](PhINAr)} + . Intermediate Assessed by High-Resolution ESI-MS and DFT Calculations

(2014) Yungen Liu et al.   Chemistry-An Asian Journal

Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals

(2014) Edon Vitaku et al.   JOURNAL OF MEDICINAL CHEMISTRY

Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination

(2014) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Biologically Relevant Compounds by Ruthenium Porphyrin Catalyzed Amination of Benzylic C–H Bonds

(2014) Paolo Zardi et al.   ORGANOMETALLICS

Indoles Rather than Triazoles from the Ruthenium Porphyrin-Catalyzed Reaction of Alkynes with Aryl Azides

(2014) Paolo Zardi et al.   ACS Catalysis

DFT Mechanistic Proposal of the Ruthenium Porphyrin-Catalyzed Allylic Amination by Organic Azides

(2014) Gabriele Manca et al.   ACS Catalysis

Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source

(2014) Haiyu Wang et al.   RSC Advances

Enantioselective Intramolecular CH Amination Catalyzed by Engineered Cytochrome P450 Enzymes In Vitro and In Vivo

(2013) John A. McIntosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparison of the Reactivity of Nonheme Iron(IV)-Oxo versus Iron(IV)-Imido Complexes: Which is the Better Oxidant?

(2013) Anil Kumar Vardhaman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

(2013) Wenbo Xiao et al.   CHEMICAL COMMUNICATIONS

C–N bond forming cross-coupling reactions: an overview

(2013) Jitender Bariwal et al.   CHEMICAL SOCIETY REVIEWS

Bis(sulfonylimide)ruthenium(VI) Porphyrins: X-ray Crystal Structure and Mechanism of CH Bond Amination by Density Functional Theory Calculations

(2013) Zhen Guo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Generation of a High-Valent Iron Imido Corrolazine Complex and NR Group Transfer Reactivity

(2013) Pannee Leeladee et al.   INORGANIC CHEMISTRY

Nonheme Iron-Mediated Amination of C(sp3)–H Bonds. Quinquepyridine-Supported Iron-Imide/Nitrene Intermediates by Experimental Studies and DFT Calculations

(2013) Yungen Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into C–H Amination via Dicopper Nitrenes

(2013) Mae Joanne B. Aguila et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

(2012) Geoffroy Dequirez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(iv) porphyrin catalyzed phosphoramidation of aldehydes with phosphoryl azides as a nitrene source

(2012) Wenbo Xiao et al.   CHEMICAL COMMUNICATIONS

[Ru(TPP)CO]-Catalysed Intramolecular Benzylic CH Bond Amination, Affording Phenanthridine and Dihydrophenanthridine Derivatives

(2012) Daniela Intrieri et al.   CHEMISTRY-A EUROPEAN JOURNAL

C-H bond amination by iron-imido/nitrene species

(2012) Long Zhang et al.   CHINESE SCIENCE BULLETIN

Iron-Catalyzed Intramolecular Allylic C–H Amination

(2012) Shauna M. Paradine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Half-Sandwich Scorpionates as Nitrene Transfer Catalysts

(2012) Shengwen Liang et al.   ORGANOMETALLICS

Practical iron-catalyzed atom/group transfer and insertion reactions

(2012) Toby Wai-Shan Chow et al.   PURE AND APPLIED CHEMISTRY

Transition-metal-catalyzed aminations and aziridinations of CH and CC bonds with iminoiodinanes

(2011) Joyce Wei Wei Chang et al.   CHEMICAL RECORD

Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

(2011) Chi-Ming Che et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

(2011) Thomas A. Ramirez et al.   CHEMICAL SOCIETY REVIEWS

High-valent iron and manganese complexes of corrole and porphyrin in atom transfer and dioxygen evolving catalysis

(2011) Mahdi M. Abu-Omar   DALTON TRANSACTIONS

Insights into the Mechanism of the Ruthenium-Porphyrin-Catalysed Allylic Amination of Olefins by Aryl Azides

(2011) Daniela Intrieri et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex

(2011) Ryan E. Cowley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C–H Amination. An Enabling Method for Chemical Synthesis

(2011) J. Du Bois   ORGANIC PROCESS RESEARCH & DEVELOPMENT

[Fe(F20TPP)Cl] catalyzed intramolecular C–N bond formation for alkaloid synthesis using aryl azides as nitrogen source

(2010) Yungen Liu et al.   CHEMICAL COMMUNICATIONS

Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions

(2010) Hongjian Lu et al.   CHEMICAL SOCIETY REVIEWS

[FeIII(F20-tpp)Cl] Is an Effective Catalyst for Nitrene Transfer Reactions and Amination of Saturated Hydrocarbons with Sulfonyl and Aryl Azides as Nitrogen Source under Thermal and Microwave-Assisted Conditions

(2010) Yungen Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium porphyrins-catalyzed atom-efficient amination of C-H bonds by arylazides

(2010) Daniela Intrieri et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

(2010) Tom G. Driver   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic C–H amination: recent progress and future directions

(2009) Florence Collet et al.   CHEMICAL COMMUNICATIONS

The key intermediate in the amination of saturated C–H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)2 (Ar = 3,5-(CF3)2C6H3)

(2009) Simone Fantauzzi et al.   CHEMICAL COMMUNICATIONS

Ruthenium Porphyrin-Catalyzed Aerobic Oxidation of Terminal Aryl Alkenes to Aldehydes by a Tandem Epoxidation-Isomerization Pathway

(2008) Gaoxi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Highly Efficient Alkene Epoxidation and Aziridination Catalyzed by Iron(II) Salt + 4,4′,4′′-Trichloro-2,2′:6′,2′′-terpyridine/4,4′′-Dichloro-4′-O-PEG-OCH3-2,2′:6′,2′′-terpyridine

(2008) Peng Liu et al.   ORGANIC LETTERS

Efficient Intermolecular Iron-Catalyzed Amidation of C−H Bonds in the Presence ofN-Bromosuccinimide

(2008) Zhe Wang et al.   ORGANIC LETTERS

β-Fluorinated Porphyrins and Related Compounds: An Overview

(2007) Jacques Leroy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY