Highly Robust Iron Catalyst System for Intramolecular C(sp 3 )−H Amidation Leading to γ‐Lactams

New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

(2020) Aaron Trowbridge et al.   CHEMICAL REVIEWS

Dioxazolones: Stable Substrates for the Catalytic Transfer of Acyl Nitrenes

(2020) Kaj M. van Vliet et al.   ACS Catalysis

Versatile Cp*Co(III)(LX) Catalyst System for Selective Intramolecular C–H Amidation Reactions

(2020) Jia Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe-catalyzed aziridination is governed by the electron affinity of the active imido-iron species

(2020) Guillaume Coin et al.   ACS Catalysis

Iron and manganese oxo complexes, oxo wall and beyond

(2020) Virginia A. Larson et al.   Nature Reviews Chemistry

Iron-Catalyzed Amination of Strong Aliphatic C(sp3)–H Bonds

(2020) Sandip Kumar Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Introduction: First Row Metals and Catalysis

(2019) Matthias Beller   CHEMICAL REVIEWS

Iron(II)-Based Metalloradical Activation: Switch from Traditional Click Chemistry to Denitrogenative Annulation

(2019) Satyajit Roy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Engineering Chemoselectivity in Hemoprotein-Catalyzed Indole Amidation

(2019) Oliver F. Brandenberg et al.   ACS Catalysis

Non-C2-Symmetric Chiral-at-Ruthenium Catalyst for Highly Efficient Enantioselective Intramolecular C(sp3)–H Amidation

(2019) Zijun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An enzymatic platform for the asymmetric amination of primary, secondary and tertiary C(sp3)–H bonds

(2019) Yang Yang et al.   Nature Chemistry

The Tpx M Core in Csp 3 -H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag)

(2019) M. Mar Díaz-Requejo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Intermolecular sp3-C–H Amination for the Synthesis of Saturated Azacycles

(2019) Kerry N. Betz et al.   ORGANIC LETTERS

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Electrocatalytic C–H Activation

(2018) Nicolas Sauermann et al.   ACS Catalysis

Revisiting Arene C(sp2 )−H Amidation by Intramolecular Transfer of Iridium Nitrenoids: Evidence for a Spirocyclization Pathway

(2018) Yeongyu Hwang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Iron(III) Porphyrin-Catalyzed Intramolecular C(sp3 )-H Amination of Alkyl Azides

(2018) Ka-Pan Shing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective C–H halogenation over hydroxylation by non-heme iron(iv)-oxo

(2018) Sujoy Rana et al.   Chemical Science

Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions

(2018) Mian Guo et al.   ACS Central Science

Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand

(2017) Bidraha Bagh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote, Late-Stage Oxidation of Aliphatic C–H Bonds in Amide-Containing Molecules

(2017) Takeshi Nanjo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative catalytic evolution of redox- and spin-states of a Fe-phthalocyanine studied by EPR

(2016) Eleni Bletsa et al.   CHEMICAL PHYSICS LETTERS

Oxidative diversification of amino acids and peptides by small-molecule iron catalysis

(2016) Thomas J. Osberger et al.   NATURE

Curtius-like Rearrangement of an Iron–Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes

(2016) Dashan Li et al.   ORGANIC LETTERS

Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts

(2015) Patrick L. Holland   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt-Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents

(2015) Juhyeon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?

(2015) Dean G. Brown et al.   JOURNAL OF MEDICINAL CHEMISTRY

Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

(2015) Monalisa Goswami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Oxidation of Aliphatic C–H Bonds in Nitrogen-Containing Molecules

(2015) Jennifer M. Howell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective formation of an iron(iv)–oxo species at the more electron-rich iron atom of heteroleptic μ-nitrido diiron phthalocyanines

(2015) Ümit İşci et al.   Chemical Science

Enzymatic C(sp3)-H Amination: P450-Catalyzed Conversion of Carbonazidates into Oxazolidinones

(2015) Ritesh Singh et al.   ACS Catalysis

Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

(2015) Jiao Jiao et al.   ACS Catalysis

Synthesis of Carbazoles by Copper-Catalyzed Intramolecular C–H/N–H Coupling

(2014) Kazutaka Takamatsu et al.   ORGANIC LETTERS

C–N bond forming cross-coupling reactions: an overview

(2013) Jitender Bariwal et al.   CHEMICAL SOCIETY REVIEWS

Oxidative C–H amination reactions

(2013) Marie-Laure Louillat et al.   CHEMICAL SOCIETY REVIEWS

Nonheme Iron-Mediated Amination of C(sp3)–H Bonds. Quinquepyridine-Supported Iron-Imide/Nitrene Intermediates by Experimental Studies and DFT Calculations

(2013) Yungen Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Aliphatic C–H Oxidations with a Predictive Model for Site-Selectivity

(2013) Paul E. Gormisky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

(2013) E. T. Hennessy et al.   SCIENCE

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

(2012) Geoffroy Dequirez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Directed Metal (Oxo) Aliphatic C–H Hydroxylations: Overriding Substrate Bias

(2012) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Intramolecular Allylic C–H Amination

(2012) Shauna M. Paradine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II) Bromide-Catalyzed Intramolecular C–H Bond Amination [1,2]-Shift Tandem Reactions of Aryl Azides

(2012) Quyen Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cafestol to Tricalysiolide B and Oxidized Analogues: Biosynthetic and Derivatization Studies Using Non-heme Iron Catalyst Fe(PDP)

(2012) K. Houk et al.   SYNLETT

The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes

(2012) Johannes Hohenberger et al.   Nature Communications

Catalytic C–H amination: the stereoselectivity issue

(2011) Florence Collet et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

(2011) Thomas A. Ramirez et al.   CHEMICAL SOCIETY REVIEWS

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes

(2011) Evan R. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions

(2010) Hongjian Lu et al.   CHEMICAL SOCIETY REVIEWS

A seven-coordinate iron platform and its oxo and nitrene reactivity

(2010) Han Sen Soo et al.   INORGANICA CHIMICA ACTA

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines

(2008) Gordon Brasche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions

(2008) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature

(2008) James A. Jordan-Hore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol

(2008) Nicolaas A. Vermeulen et al.   TETRAHEDRON