Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 26, Pages 8800-8803Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04695
Keywords
-
Categories
Funding
- NRF of Korea through CRI [NRF-2012R1A3A2048842]
- NRF of Korea through GRL [NRF-2010-00353]
- NRF of Korea through MSIP [NRF-2017R1C1B2002037]
- Sookmyung Women's University [1-1603-2054]
- NIH [GM-40392]
- JSPS [15H00960]
- U.S. DOE [DE-AC02-76SF00515]
- Grants-in-Aid for Scientific Research [16K05850, 15H00960] Funding Source: KAKEN
Ask authors/readers for more resources
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
