Intermolecular Metal‐Free Cyclopropanation and Aziridination of Alkenes with XH 2 (X=N, C) by Thianthrenation**

Organoelectrocatalysis Enables Direct Cyclopropanation of Methylene Compounds

(2022) Liang-Hua Jie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A combined experimental and theoretical study on the reactivity of nitrenes and nitrene radical anions

(2022) Yujing Guo et al.   Nature Communications

Sustainable Thioetherification via Electron Donor–Acceptor Photoactivation Using Thianthrenium Salts

(2022) María Jesús Cabrera‐Afonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical Aziridination of Internal Alkenes with Primary Amines

(2021) Maksim Ošeka et al.   Chem

Late‐Stage Heteroarylation of Hetero(aryl)sulfonium Salts Activated by α‐Amino Alkyl Radicals

(2021) Eva Maria Alvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enabling the Use of Alkyl Thianthrenium Salts in Cross‐Coupling Reactions by Copper Catalysis

(2021) Cheng Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C–H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence

(2021) Beatrice Lansbergen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C–H Thianthrenation

(2021) Fabio Juliá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vinyl Thianthrenium Tetrafluoroborate: A Practical and Versatile Vinylating Reagent Made from Ethylene

(2021) Fabio Juliá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aziridine synthesis by coupling amines and alkenes via an electrogenerated dication

(2021) Dylan E. Holst et al.   NATURE

Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation

(2021) Cheng Chen et al.   Nature Communications

Electrochemical Synthesis of Allylic Amines from Terminal Alkenes and Secondary Amines

(2021) Diana J. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(II)-Catalyzed Intermolecular N-Aryl Aziridination of Olefins Using Nonactivated N Atom Precursors

(2021) Tianning Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tritiation of aryl thianthrenium salts with a molecular palladium catalyst

(2021) Da Zhao et al.   NATURE

Construction of α-Amino Azines via Thianthrenation-Enabled Photocatalyzed Hydroarylation of Azine-Substituted Enamides with Arenes

(2021) Yu-Lan Zhang et al.   ORGANIC LETTERS

Metal-free allylic C–H nitrogenation, oxygenation, and carbonation of alkenes by thianthrenation

(2021) Ming-Shang Liu et al.   Chemical Science

Catalytic Enantioselective Ring-Opening Reactions of Cyclopropanes

(2020) Vincent Pirenne et al.   CHEMICAL REVIEWS

Pd‐Catalyzed Site‐Selective Borylation of Simple Arenes via Thianthrenation

(2020) Xiao‐Yue Chen et al.   CHINESE JOURNAL OF CHEMISTRY

Site-Selective C–H Functionalization–Sulfination Sequence to Access Aryl Sulfonamides

(2020) Eva Maria Alvarez et al.   ORGANIC LETTERS

Site-Selective Silylation of Arenes Mediated by Thianthrene S-Oxide

(2020) Yichen Wu et al.   ORGANIC LETTERS

Allylic Amination of Alkenes with Iminothianthrenes to Afford Alkyl Allylamines

(2020) Qiang Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thianthrenation-Enabled α-Arylation of Carbonyl Compounds with Arenes

(2020) Xiao-Xue Nie et al.   ORGANIC LETTERS

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts

(2019) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective C−H Oxygenation via Aryl Sulfonium Salts

(2019) Ruocheng Sang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereoselective Thianthrenation of Olefins to Access Versatile Alkenyl Electrophiles

(2019) Tobias Ritter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox catalysis with aryl sulfonium salts enables site-selective late-stage fluorination

(2019) Jiakun Li et al.   Nature Chemistry

Para-selective borylation of monosubstituted benzenes using a transient mediator

(2019) Jie Wu et al.   Science China-Chemistry

Electrochemical Aziridination by Alkene Activation Using a Sulfamate as the Nitrogen Source

(2018) Jin Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc triflate-mediated cyclopropanation of oxindoles with vinyl diphenyl sulfonium triflate: a mild reaction with broad functional group compatibility

(2017) Mingwei Zhou et al.   RSC Advances

New Approaches to the Synthesis of Metal Carbenes

(2016) Minqiang Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The “Cyclopropyl Fragment” is a Versatile Player that Frequently Appears in Preclinical/Clinical Drug Molecules

(2016) Tanaji T. Talele   JOURNAL OF MEDICINAL CHEMISTRY

Synthetic Aziridines in Medicinal Chemistry: A Mini-Review

(2016) Girija S. Singh   MINI-REVIEWS IN MEDICINAL CHEMISTRY

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Electrocatalytic Aziridination of Alkenes Mediated by n-Bu4NI: A Radical Pathway

(2015) Jie Chen et al.   ORGANIC LETTERS

Recent Advances in the Stereoselective Synthesis of Aziridines

(2014) Leonardo Degennaro et al.   CHEMICAL REVIEWS

Recent advances in the total synthesis of cyclopropane-containing natural products

(2012) David Y.-K. Chen et al.   CHEMICAL SOCIETY REVIEWS

Enzymatic Chemistry of Cyclopropane, Epoxide, and Aziridine Biosynthesis

(2011) Christopher J. Thibodeaux et al.   CHEMICAL REVIEWS

Aziridinyl Anions: Generation, Reactivity, and Use in Modern Synthetic Chemistry

(2010) Saverio Florio et al.   CHEMICAL REVIEWS