Hydrocarbon Soluble Alkali‐Metal‐Aluminium Hydride Surrog[ATES]

Rubidium and caesium aluminyls: synthesis, structures and reactivity in C–H bond activation of benzene

(2022) Thomas X. Gentner et al.   CHEMICAL COMMUNICATIONS

Inhibition of Alkali Metal Reduction of 1‐Adamantanol by London Dispersion Effects

(2022) Kristian L. Mears et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective cross‐coupling of unsaturated substrates on Al(I)

(2021) Anton Dmitrienko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structurally Defined Ring‐Opening and Insertion of Pinacolborane into Aluminium‐Nitrogen Bonds of Sterically Demanding Dialkylaluminium Amides

(2021) Victoria A. Pollard et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation of Alkenes

(2021) Robert E. Mulvey et al.   ChemCatChem

Activation of Nitrogen-Rich Substrates by Low-Valent, Redox-Active Aluminum Species

(2021) Weixing Chen et al.   ORGANOMETALLICS

Facilitating Ferration of Aromatic Substrates Through Intramolecular Sodium Mediation

(2021) Lewis Maddock et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Strongly reducing magnesium(0) complexes

(2021) B. Rösch et al.   NATURE

Molecular Main Group Metal Hydrides

(2021) Matthew M. D. Roy et al.   CHEMICAL REVIEWS

Factors Controlling the Aluminum(I)‐ meta ‐Selective C−H Activation in Arenes

(2021) Jorge Juan Cabrera‐Trujillo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Contrasting the Mechanism of H 2 Activation by Monomeric and Potassium‐Stabilized Dimeric Al I Complexes: Do Potassium Atoms Exert any Cooperative Effect?

(2021) Nery Villegas‐Escobar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isomers of Alkali Metal (Methylbenzyl)allylamides: A Theoretical Perspective

(2020) Luke Wylie et al.   ACS Omega

Arene C‐H activation at aluminium(I): meta selectivity driven by the electronics of SNAr chemistry

(2020) Jamie Hicks et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkali Metal Mediation: Diversity of Applications in Main Group Organometallic Chemistry

(2020) Robert E. Mulvey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insights in LiAlH4 Catalysed Imine Hydrogenation

(2020) Sjoerd Harder et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkali-Metal-Mediated Synergistic Effects in Polar Main Group Organometallic Chemistry

(2019) Stuart D. Robertson et al.   CHEMICAL REVIEWS

A generally applicable atomic-charge dependent London dispersion correction

(2019) Eike Caldeweyher et al.   JOURNAL OF CHEMICAL PHYSICS

Dehydrocyclization of diamine borane and amine-borane alcohol catalyzed by 1-lithio-2-alkyl-1,2-dihydropyridine and its Na & K analogues: A DFT analysis of the reaction mechanism

(2019) Avik Ghosh et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

LiAlH4 : From Stoichiometric Reduction to Imine Hydrogenation Catalysis

(2018) Holger Elsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

(2018) Victoria A. Pollard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The hetero-cubane structures of the heavy alkali metal tert-amyloxides [MOCMe2Et]4 (M = K, Rb, Cs)

(2018) Maximillian Kaiser et al.   DALTON TRANSACTIONS

Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion

(2018) Jamie Hicks et al.   NATURE

Low Valent Magnesium Chemistry with a Super Bulky β-Diketiminate Ligand

(2018) Thomas Xaver Gentner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Data

(2017) Lyudmila A. Lapkina et al.   INORGANIC CHEMISTRY

Extension of the D3 dispersion coefficient model

(2017) Eike Caldeweyher et al.   JOURNAL OF CHEMICAL PHYSICS

On the usefulness of useless knowledge

(2017) Helmut Schwarz   Nature Reviews Chemistry

London dispersion forces in sterically crowded inorganic and organometallic molecules

(2017) David J. Liptrot et al.   Nature Reviews Chemistry

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

(2016) Ross McLellan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accessible heavier s-block dihydropyridines: structural elucidation and reactivity of isolable molecular hydride sources

(2016) Samantha A. Orr et al.   DALTON TRANSACTIONS

Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes

(2016) Ana I. Ojeda-Amador et al.   INORGANIC CHEMISTRY

Alkali Metal Hydride Complexes: Well-Defined Molecular Species of Saline Hydrides*

(2015) Lea Fohlmeister et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Facile synthesis of a genuinely alkane-soluble but isolable lithium hydride transfer reagent

(2015) Stuart D. Robertson et al.   CHEMICAL COMMUNICATIONS

A pyrazolate-stabilized sodium hydride complex

(2015) Andreas Stasch   CHEMICAL COMMUNICATIONS

Developing Lithium Chemistry of 1,2-Dihydropyridines: From Kinetic Intermediates to Isolable Characterized Compounds

(2015) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal Synergistic Syntheses

(2015) William Clegg et al.   ORGANOMETALLICS

Reactivity studies of a soluble LiH-complex and non-spectator behaviour of its stabilising phosphinoamide ligand

(2014) Andreas Stasch   DALTON TRANSACTIONS

Mononuclear Three-Coordinate Magnesium Complexes of a Highly Sterically Encumbered β-Diketiminate Ligand

(2014) Merle Arrowsmith et al.   INORGANIC CHEMISTRY

Neutron Diffraction Characterization of C–H···Li Interactions in a Lithium Aluminate Polymer

(2014) Jacqueline M. Cole et al.   ORGANOMETALLICS

TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation–alkylaluminium-trapping reagents?

(2014) David R. Armstrong et al.   Chemical Science

catena-Poly[[(tetrahydrofuran-κO)potassium]-di-μ-dimethylamido-κ4N:N-aluminium-di-μ-dimethylamido-κ4N:N-potassium-di-μ-dimethylamido-κ4N:N-aluminium-di-μ-dimethylamido-κ4N:N]

(2013) Andrew Purdy et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Well-Defined, Nanometer-Sized LiH Cluster Compounds Stabilized by Pyrazolate Ligands

(2013) Andreas Stasch   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Hydrocarbon-Soluble Lithium Hydride Complex

(2012) Andreas Stasch   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

(2012) Ben Conway et al.   CHEMICAL COMMUNICATIONS

Molecular early main group metal hydrides: synthetic challenge, structures and applications

(2012) Sjoerd Harder   CHEMICAL COMMUNICATIONS

Adding Rubidium and Cesium to the Homologous Series of Alkali Metal Compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides

(2012) William Clegg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Chemistry of Soluble β-Diketiminatoalkaline-Earth Metal Complexes with M−X Bonds (M = Mg, Ca, Sr; X = OH, Halides, H)

(2011) Sankaranarayana Pillai Sarish et al.   ACCOUNTS OF CHEMICAL RESEARCH

Exploiting σ/π Coordination Isomerism to Prepare Homologous Organoalkali Metal (Li, Na, K) Monomers with Identical Ligand Sets

(2011) Matthew G. Davidson et al.   CHEMISTRY-A EUROPEAN JOURNAL

The chemistry of univalent metal β-diketiminates

(2011) Yi-Chou Tsai   COORDINATION CHEMISTRY REVIEWS

Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or four pyrrolyl ligands

(2011) Jennifer A. Garden et al.   DALTON TRANSACTIONS

Stable dimeric magnesium(i) compounds: from chemical landmarks to versatile reagents

(2011) Andreas Stasch et al.   DALTON TRANSACTIONS

Structurally Powered Synergic 2,2,6,6-Tetramethylpiperidine Bimetallics: New Reflections through Lithium-MediatedOrthoAluminations

(2011) Robert E. Mulvey et al.   INORGANIC CHEMISTRY

NCIPLOT: A Program for Plotting Noncovalent Interaction Regions

(2011) Julia Contreras-García et al.   Journal of Chemical Theory and Computation

Structurally Stimulated Deprotonation/Alumination of the TMP Anion

(2010) Ben Conway et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Revealing Noncovalent Interactions

(2010) Erin R. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural insights into mono-amido tris-alkyl potassium aluminates

(2010) Ben Conway et al.   NEW JOURNAL OF CHEMISTRY

β-Diketiminate-Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies

(2009) Simon J. Bonyhady et al.   CHEMISTRY-A EUROPEAN JOURNAL

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

(2009) Ben Conway et al.   ORGANOMETALLICS

Mixed Alkylamido Aluminate as a Kinetically Controlled Base

(2008) Hiroshi Naka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY