Adding Rubidium and Cesium to the Homologous Series of Alkali Metal Compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethylpiperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and Sodium/Potassium TMP Compounds

(2011) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Structures of [(Trimethylsilyl)methyl]sodium and -potassium with Bi- and Tridentate N-Donor Ligands

(2011) William Clegg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Controlled Anion Migrations with a Mixed Metal Li/K-TMP Amide: General Application to Benzylic Metalations

(2011) Patricia Fleming et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Avant-Garde Metalating Agents: Structural Basis of Alkali-Metal-Mediated Metalation

(2009) Robert E. Mulvey   ACCOUNTS OF CHEMICAL RESEARCH

Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R=Et,iPr,tBu, Ph, and Me2N) by Using Dialkyl-TMP-Zincate Bases

(2009) William Clegg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structural Tracking of the Potassium-Mediated Magnesiation of Anisole

(2009) William Clegg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heavy Alkali Metal Amides: Role of Secondary Interactions in Metal Stabilization

(2009) Ana Torvisco et al.   INORGANIC CHEMISTRY

Selective Vinyl C−H Lithiation ofcis-Stilbenes

(2009) Thomas Tricotet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Contacted Ion-Pair Lithium Alkylamidoaluminates: Intramolecular Alumination (Al−H Exchange) Traps for TMEDA and PMDETA

(2009) Ben Conway et al.   ORGANOMETALLICS

Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

(2009) A. R. Kennedy et al.   SCIENCE

Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines

(2008) Ben Conway et al.   CHEMICAL COMMUNICATIONS

A Structural and Computational Study of Synthetically Important Alkali-Metal/Tetramethylpiperidide (TMP) Amine Solvates

(2008) David R. Armstrong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lithiation of TMEDA and its Higher Homologous TEEDA: Understanding Observed α- and β-Deprotonation

(2008) Viktoria H. Gessner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Optimization of Organolithium Reactions

(2008) Terry ‘Li’ Rathman et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Alkyl and Aryl Derivatives of the Alkali Metals: Strong Bases and Reactive Nucleophiles. 2. Wilhelm Schlenk’s Organoalkali-Metal Chemistry. The Metal Displacement and the Transmetalation Reactions. Metalation of Weakly Acidic Hydrocarbons. Superbases

(2008) Dietmar Seyferth   ORGANOMETALLICS