Chiral Diene Ligands in Asymmetric Catalysis

Platinum‐catalyzed α,β‐Desaturation of Cyclic Ketones through Direct Metal‐enolate Formation

(2021) Ming Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of 1-Aryl Tetrahydroisoquinolines by the Rhodium-Catalyzed Reaction of 3,4-Dihydroisoquinolinium Tetraarylborates

(2021) Wei-Sian Li et al.   ORGANIC LETTERS

Enantioselective Hydroarylation or Hydroalkenylation of Benzo[b]thiophene 1,1-Dioxides with Organoboranes

(2021) Fangdong Hu et al.   ORGANIC LETTERS

Hierarchical silica inverse opals as a catalyst support for asymmetric molecular heterogeneous catalysis with chiral Rh‑diene complexes

(2021) Max Deimling et al.   ChemCatChem

Regiospecific and Enantioselective Arylvinylcarbene Insertion of a C–H Bond of Aniline Derivatives Enabled by a Rh(I)-Diene Catalyst

(2021) Dong-Xing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient and Spatially Controlled Functionalization of SBA‐15 and Initial Results in Asymmetric Rh‐Catalyzed 1,2‐Additions under Confinement

(2021) Ann‐Katrin Beurer et al.   ChemCatChem

Enantio‐ and Diastereodivergent Sequential Catalysis Featuring Two Transition‐Metal‐Catalyzed Asymmetric Reactions

(2021) Jeanne Masson‐Makdissi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E−H Bonds

(2021) Nikita M. Ankudinov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Fluorinated Allenes by Rhodium‐Catalyzed Enantioselective Alkylation/Defluorination of Propargyl Difluorides with Alkylzincs

(2021) Jia Sheng Ng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium‐Catalyzed Hydroarylation via C−H Bond Activation

(2021) Takahiro Nishimura   CHEMICAL RECORD

Stereodivergent Synthesis of Enantioenriched 2,3-Disubstituted Dihydrobenzofurans via a One-Pot C–H Functionalization/Oxa-Michael Addition Cascade

(2021) Dong-Xing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo-, Enantio-, and Z-Selective α,δ-Difunctionalization of Electron-Deficient Dienes Initiated by Rh-Catalyzed Conjugate Addition

(2021) Christopher J. C. Cooze et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Chiral Bicyclo[2.2.1]hepta-2,5-diene Ligands through Rhodium-Catalyzed Asymmetric Arylative Bis-cyclization of a 1,6-Enyne

(2021) Chao Sun et al.   ORGANIC LETTERS

Cross-Dimerization of 2,5-Dihydrofuran with Conjugated Dienes Catalyzed by (Chiral Diene)ruthenium(0) Complexes and Origins of the Enantioselectivity

(2021) Masafumi Hirano et al.   ORGANOMETALLICS

Chiral Dienes: From Ligands to FLP Catalysts

(2021) Xiangqing Feng et al.   CHINESE JOURNAL OF CHEMISTRY

Catalytic Enantioselective Synthesis of Axially Chiral Polycyclic Aromatic Hydrocarbons (PAHs) via Regioselective C–C Bond Activation of Biphenylenes

(2020) Hideaki Takano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective and Atom-Economic Alkenyl C–H Allylation/Alkenylation in Aqueous Media by Iridium Catalysis

(2020) Yinhua Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Construction of 1-Tetralols Bearing Two Contiguous Quaternary Chiral Centers through a Rhodium-Catalyzed Enantioselective Desymmetrization Cascade Reaction

(2020) Aymane Selmani et al.   ORGANIC LETTERS

Rhodium‐Catalysed Asymmetric Synthesis of 4‐Alkyl‐4 H ‐Chromenes

(2020) Zhiqian Chang et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of Alkylzincs by Rhodium‐Catalyzed Enantioselective Arylative Cyclization of 1,6‐Enynes with Arylzincs

(2020) Jiahua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Allylation of Aliphatic Imines: Synthesis of Chiral C-Aliphatic Homoallylic Amines

(2020) Wei-Sian Li et al.   ORGANIC LETTERS

Highly Enantioselective Synthesis of Monofluoroalkenes by Rhodium-Catalyzed Asymmetric Arylation/Defluorination of Allyl Difluorides

(2020) Yuhang Pan et al.   ORGANIC LETTERS

Experimental and Theoretical Study on the Role of Monomeric vs Dimeric Rhodium Oxazolidinone Norbornadiene Complexes in Catalytic Asymmetric 1,2- and 1,4-Additions

(2020) Manuel Kirchhof et al.   ORGANOMETALLICS

Chiral Rhodium Nanoparticle-Catalyzed Asymmetric Arylation Reactions

(2020) Tomohiro Yasukawa et al.   ACCOUNTS OF CHEMICAL RESEARCH

Low‐Temperature Intramolecular [4+2] Cycloaddition of Allenes with Arenes for the Synthesis of Diene Ligands

(2020) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Water as a Direct Proton Source for Asymmetric Hydroarylation Catalyzed by a Rh(I)–Diene: Access to Nonproteinogenic β2/γ2/δ2-Amino Acid Derivatives

(2020) Jian-Ping Chen et al.   ORGANIC LETTERS

From Tetrahydrofurans to Tetrahydrobenzo[d]oxepines via a Regioselective Control of Alkyne Insertion in Rhodium-Catalyzed Arylative Cyclization

(2019) Aymane Selmani et al.   JOURNAL OF ORGANIC CHEMISTRY

Heterogeneous Chiral Diene‐Rh Complexes for Asymmetric Arylation of α,β‐Unsaturated Carbonyl Compounds, Nitroalkenes, and Imines

(2019) Shu Kobayashi et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Catalysis in Liquid Confinement: Probing the Performance of Novel Chiral Rhodium Diene Complexes in Microemulsions and Conventional Solvents

(2019) Max Deimling et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Bicyclo[2.2.2]octa-2,5-dienyltrifluoroborate Derivative as a Useful and Stable Precursor of C1-Symmetric Chiral Dienes

(2019) Aymane Selmani et al.   ORGANIC LETTERS

Asymmetric Synthesis of β-Aryl β-Imido Sulfones Using Rhodium Catalysts with Chiral Diene Ligands: Synthesis of Apremilast

(2019) Jin-Fong Syu et al.   ORGANIC LETTERS

Recent advances of achiral and chiral diene ligands in transition-metal catalyses

(2019) Masafumi Hirano et al.   TETRAHEDRON LETTERS

Enantioselective Conjugate Addition of Aryl Halides and Triflates to Electron-Deficient Olefins via Nickel- and Rhodium-Catalyzed Sequential Relay Reactions

(2019) Chenrui Fan et al.   ORGANIC LETTERS

Asymmetric Synthesis of Functionalized Phenylalanine Derivatives via Rh-Catalyzed Conjugate Addition and Enantioselective Protonation Cascade

(2019) Jia-Hong Jian et al.   ORGANIC LETTERS

Asymmetric 1,4‐Addition of Arylboronic Acids to β,γ‐Unsaturated α‐Ketoesters using Heterogeneous Chiral Metal Nanoparticle Systems

(2019) Hiroyuki Miyamura et al.   ADVANCED SYNTHESIS & CATALYSIS

C–H Functionalization Approach for the Synthesis of Chiral C2-Symmetric 1,5-Cyclooctadiene Ligands

(2019) Bowen Zhang et al.   ORGANIC LETTERS

Asymmetric Synthesis of Axially Chiral 2-Aminobiaryls by Rhodium-Catalyzed Benzannulation of 1-Arylalkynes with 2-(Cyanomethyl)phenylboronates

(2018) Fei Xue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Chiral HWE Reagents by Rhodium-Catalyzed Asymmetric Arylation of γ,δ-Unsaturated β-Ketophosphonates

(2018) Long Yin et al.   JOURNAL OF ORGANIC CHEMISTRY

Aqueous Asymmetric 1,4-Addition of Arylboronic Acids to Enones Catalyzed by an Amphiphilic Resin-Supported Chiral Diene Rhodium Complex under Batch and Continuous-Flow Conditions

(2018) Guanshuo Shen et al.   JOURNAL OF ORGANIC CHEMISTRY

Ligand-Controlled Rhodium-Catalyzed Site-Selective Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Cyclic N-Sulfonyl Ketimines

(2018) Chun-Yan Wu et al.   ORGANIC LETTERS

Efficient and Enantioselective Rhodium(I)-Catalyzed Arylation of α-Ketoesters: Synthesis of (S )-Flutriafol

(2018) Chiung-An Chang et al.   ADVANCED SYNTHESIS & CATALYSIS

Access to β2-Amino Acids via Enantioselective 1,4-Arylation of β-Nitroacrylates Catalyzed by Chiral Rhodium Catalysts

(2018) Jia-Hong Jian et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Tandem Addition–Cyclization–Rearrangement of Alkynylhydrazones with Organoboronic Acids

(2018) Kyoungmin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Highly Enantioenriched Propelladienes and their Application as Ligands in Asymmetric Rh-Catalyzed 1,4-Additions

(2018) Tommaso Pecchioli et al.   ORGANIC LETTERS

Asymmetric Rh(I)-Catalyzed Functionalization of the 3-C(sp3)–H Bond of Benzofuranones with α-Diazoesters

(2018) Yuanhong Liu et al.   ORGANIC LETTERS

Rhodium-Catalyzed Enantioselective Defluorinative α-Arylation of Secondary Amides

(2018) Young Jin Jang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Supramolecular U-Shaped Catalysts Induce the Multiselective Diels–Alder Reaction of Propargyl Aldehyde

(2018) Manabu Hatano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Conjugate Arylation of γ,δ-Unsaturated β-Dicarbonyl Compounds

(2018) Jian Yao et al.   ORGANIC LETTERS

Role of Regioisomeric Bicyclo[3.3.0]octa-2,5-diene Ligands in Rh Catalysis: Synthesis, Structural Analysis, Theoretical Study, and Application in Asymmetric 1,2- and 1,4-Additions

(2017) Tina Mühlhäuser et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Complex Tertiary Glycolates by Enantioconvergent Arylation of Stereochemically Labile α-Keto Esters

(2017) Samuel L. Bartlett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Rapid Synthesis of Chiral Allylic Amines via Microwave-assisted Asymmetric Alkenylation of N -Tosyl Aldimines Catalyzed by Rhodium/Chiral Diene Complexes

(2017) Balraj Gopula et al.   JOURNAL OF THE CHINESE CHEMICAL SOCIETY

Construction of Chiral Tricyclic Indoles through a Rhodium-Catalyzed Asymmetric Arylation Protocol

(2017) Chun-Yan Wu et al.   ORGANIC LETTERS

Rh-Catalyzed Enantioselective Allylation of N-Tosyl- and N-Nosylaldimines: Total Synthesis of (−)-Crispine A

(2017) Pei-Fen Chiang et al.   ORGANIC LETTERS

Enantioselective Rhodium-Catalyzed Alkenylation of Aliphatic Imines

(2017) Xue-Wei Qian et al.   ORGANIC LETTERS

Enantioselective Access to Bicyclo[3.2.1]octadienone Skeleton: Total Syntheses of (+)-Engelharquinone and Its Epoxide

(2017) Takumi Fukazawa et al.   ORGANIC LETTERS

Enantioselective Synthesis of 1,2-Diamines Containing Tertiary and Quaternary Centers through Rhodium-Catalyzed DYKAT of Racemic Allylic Trichloroacetimidates

(2017) Edward T. Mwenda et al.   ORGANIC LETTERS

Kinetic Resolution of Planar-Chiral (η5-Bromocyclopentadienyl)manganese(I) Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis

(2017) Masamichi Ogasawara et al.   ORGANOMETALLICS

Rhodium-catalyzed asymmetric 1,4-addition reactions of aryl boronic acids with nitroalkenes: reaction mechanism and development of homogeneous and heterogeneous catalysts

(2017) Hiroyuki Miyamura et al.   Chemical Science

Sequential catalysis: exploiting a single rhodium(i) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence

(2017) Maitane Fernández et al.   Chemical Science

A DFT calculation-inspired Rh(i)-catalyzed reaction via suppression of α-H shift in α-alkyldiazoacetates

(2017) Shunying Liu et al.   Chemical Science

Employing Pd-Catalyzed C–H Arylation in Multicomponent-Multicatalyst Reactions (MC)2R: One-Pot Synthesis of Dihydrobenzoquinolines

(2017) Fabian Lied et al.   ACS Catalysis

Asymmetric Synthesis of Allylic Fluorides via Fluorination of Racemic Allylic Trichloroacetimidates Catalyzed by a Chiral Diene-Iridium Complex

(2017) Jason C. Mixdorf et al.   ACS Catalysis

Iridium/Chiral Diene-Catalyzed Enantioselective (3+2) Annulation of Aromatic Ketimines with 1,3-Enynes via C−H Activation

(2017) Midori Nagamoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Base-Free Conditions for Rhodium-Catalyzed Asymmetric Arylation To Produce Stereochemically Labile α-Aryl Ketones

(2016) Xiaowei Dou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Nanoparticles/Lewis Acids as Cooperative Catalysts for Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Amides

(2016) Tomohiro Yasukawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes

(2016) Yinhua Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C–H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

(2016) Miyuki Hatano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

(2016) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A nordehydroabietyl amide-containing chiral diene for rhodium-catalysed asymmetric arylation to nitroolefins

(2016) Ruikun Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Arylation of Imines Catalyzed by Heterogeneous Chiral Rhodium Nanoparticles

(2016) Tomohiro Yasukawa et al.   ORGANIC LETTERS

Asymmetric Cyclization of N-Sulfonyl Alkenyl Amides Catalyzed by Iridium/Chiral Diene Complexes

(2016) Midori Nagamoto et al.   ORGANIC LETTERS

Aryloxymethyltrifluoroborates for Rhodium-Catalyzed Asymmetric Conjugate Arylation. o-Methoxyarylation through 1,4-Rhodium Shift

(2016) Jialin Ming et al.   ORGANIC LETTERS

Construction of Cyclic Sulfamidates Bearing Two gem-Diaryl Stereocenters through a Rhodium-Catalyzed Stepwise Asymmetric Arylation Protocol

(2016) Yu-Fang Zhang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Enantioselective Addition of Tricyclopropylboroxin to N-Sulfonylimines

(2016) Takahiro Nishimura et al.   SYNTHESIS-STUTTGART

Rh-catalyzed asymmetric 1,4-addition reactions to α,β-unsaturated carbonyl and related compounds: an update

(2016) Majid M. Heravi et al.   TETRAHEDRON-ASYMMETRY

Asymmetric Transformations under Iridium/Chiral Diene Catalysis

(2016) Midori Nagamoto et al.   ACS Catalysis

Rhodium-Catalyzed Enantioselective Arylation of N -Substituted α,β-Unsaturated γ-Lactams: Preparation of Chiral 4-Aryl-2-Pyrrolidones

(2016) Jo-Hsuan Fang et al.   Asian Journal of Organic Chemistry

Enantioselective Addition of Heteroarylboronates to Arylimines Catalyzed by a Rhodium-Diene Complex

(2015) Ya-Jing Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Conjugate Alkynylation of Cyclic α,β-Unsaturated Carbonyl Compounds with a Chiral Diene Rhodium Catalyst

(2015) Xiaowei Dou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Enantioenriched 5,6-Dihydrophenanthridine Derivatives through retro-Carbopalladation of Chiralo-Bromobenzylamines

(2015) Juntao Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chain Walking of Allylrhodium Species Towards Esters During Rhodium-Catalyzed Nucleophilic Allylations of Imines

(2015) Jose I. Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α-Oxo- and Iminocarboxamides with 1,3-Dienes

(2015) Miyuki Hatano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective hydroacylation of bicyclic alkenes with 2-hydroxybenzaldehydes catalyzed by hydroxoiridium/diene complexes

(2015) Midori Nagamoto et al.   CHEMICAL COMMUNICATIONS

Synthesis of chiral cyclobutanes via rhodium/diene-catalyzed asymmetric 1,4-addition: a dramatic ligand effect on the diastereoselectivity

(2015) Ya-Jing Chen et al.   CHEMICAL COMMUNICATIONS

Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes

(2015) Ryosuke Takechi et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of planar-chiral benzosiloloferrocenes by Rh-catalyzed intramolecular C–H silylation

(2015) Takanori Shibata et al.   CHEMICAL COMMUNICATIONS

Enantioselective Arylation ofN-Tosylimines by Phenylboronic Acid Catalysed by a Rhodium/Diene Complex: Reaction Mechanism from Density Functional Theory

(2015) Nicolas Sieffert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Synthesis of Chiral 3-Arylsuccinimides by Rhodium-Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids to Maleimides

(2015) Balraj Gopula et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromones: A Highly Enantioselective Pathway for Accessing Chiral Flavanones

(2015) Qijie He et al.   Chemistry-An Asian Journal

Application of Chiral Olefin Ligands in Asymmetric Catalysis

(2015) Xiangqing Feng et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

4,8-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes as Chiral Ligands for Rh-Catalyzed Asymmetric 1,4-Addition Reactions

(2015) Renaldas Rimkus et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Asymmetric Arylation of Allyl Sulfones under the Conditions of Isomerization into Alkenyl Sulfones

(2015) Kelvin Meng-Hui Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes

(2015) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Metal Nanoparticle Systems as Heterogeneous Catalysts beyond Homogeneous Metal Complex Catalysts for Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds

(2015) Tomohiro Yasukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines

(2015) Yinhua Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Enantioselective Fluorination of Racemic, Secondary Allylic Trichloroacetimidates

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Strategy of total synthesis based on the use of Rh-catalyzed stereoselective 1,4-addition

(2015) M. Jean et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-catalyzed asymmetric addition of arylboronic acids to cyclic N-sulfonyl ketimines towards the synthesis of α,α-diaryl-α-amino acid derivatives

(2015) Ryosuke Takechi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cycloalkene Carbonitriles in Rhodium-Catalyzed 1,4-Addition and Formal Synthesis of Vabicaserin

(2015) Wojciech J. Dziechciejewski et al.   ORGANIC LETTERS

Rhodium/Chiral Diene Complexes in the Catalytic Asymmetric Arylation of β-Pyrazol-1-yl Acrylates

(2015) Balraj Gopula et al.   ORGANIC LETTERS

Access to Polyfunctionalized Chiral Piperidines through Enantioselective Addition–Carbocyclization Cascade Reaction Catalyzed by a Rhodium(I)–Diene Complex

(2015) Fabien Serpier et al.   ORGANIC LETTERS

Cellulose-supported chiral rhodium nanoparticles as sustainable heterogeneous catalysts for asymmetric carbon–carbon bond-forming reactions

(2015) Tomohiro Yasukawa et al.   Chemical Science

The first chiral diene-based metal–organic frameworks for highly enantioselective carbon–carbon bond formation reactions

(2015) Takahiro Sawano et al.   Chemical Science

Computational modelling of the enantioselectivity in the asymmetric 1,4-addition of phenylboronic acid to a bulky, doubly pro-chiral maleimide catalyzed by a Rh/chiral diene complex

(2015) Hua-Li Qin et al.   RSC Advances

A chiral bicyclo[2.2.2]octa-2,5-diene ligand substituted with the ferrocenyl group and its use for rhodium-catalyzed asymmetric 1,4-addition reactions

(2015) Bo Zhou et al.   Organic Chemistry Frontiers

Recent applications of chiral N-tert-butanesulfinyl imines, chiral diene ligands and chiral sulfur–olefin ligands in asymmetric synthesis

(2015) Han-Qing Dong et al.   Organic Chemistry Frontiers

The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines

(2014) Hamish B. Hepburn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Ylide Transformation of Rhodium(I) Carbene: Enantioselective Three-Component Reaction through Trapping of Rhodium(I)-Associated Ammonium Ylides by β-Nitroacrylates

(2014) Xiaochu Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sequential Rhodium/Palladium Catalysis: Enantioselective Formation of Dihydroquinolinones in the Presence of Achiral and Chiral Ligands

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Sequential Allylic Amination and Olefin Hydroacylation Reactions: Enantioselective Synthesis of Seven-Membered Nitrogen Heterocycles

(2014) Jeffrey S. Arnold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Enantioselective CH Alkylation of Ferrocenes with Alkenes Using Chiral Diene Ligands

(2014) Takanori Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A second-generation ligand for the enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylazaarenes

(2014) Iain D. Roy et al.   CHEMICAL COMMUNICATIONS

A First-Principles Examination of the Asymmetric Induction Model in the Binap/RhI-Catalysed 1,4-Addition of Phenylboronic Acid to Cyclic Enones by Density Functional Theory Calculations

(2014) Hua-Li Qin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Arylative Cyclization for the Enantioselective Synthesis of (Trifluoromethyl)cyclobutanols

(2014) Thomas Johnson et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Challenge of Linear (E)-Enones in the Rh-Catalyzed, Asymmetric 1,4-Addition Reaction of Phenylboronic Acid: A DFT Computational Analysis

(2014) Hua-Li Qin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Allylic Substitutions of Trichloroacetimidates

(2014) Jeffrey S. Arnold et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective and Rapid Rh-Catalyzed Arylation of N-Tosyl- and N-Nosylaldimines in Methanol

(2014) Chun-Chih Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Annulation of Salicylimines with 1,3-Dienes

(2014) Yusuke Ebe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Arylation of Cyclic N-Sulfamidate Alkylketimines: A New Access to Chiral β-Alkyl-β-aryl Amino Alcohols

(2014) Ya-Jing Chen et al.   ORGANIC LETTERS

Enantioselective Alkenylation of Aldimines Catalyzed by a Rhodium–Diene Complex

(2014) Zhe Cui et al.   ORGANIC LETTERS

A Palladium-Catalyzed Three-Component-Coupling Strategy for the Differential Vicinal Diarylation of Terminal 1,3-Dienes

(2014) Benjamin J. Stokes et al.   ORGANIC LETTERS

Regio- and Enantioselective Linear Cross-Dimerizations between Conjugated Dienes and Acrylates Catalyzed by New Ru(0) Complexes

(2014) Yuki Hiroi et al.   ORGANOMETALLICS

Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Ene-ynamides

(2013) Takahiro Nishimura et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3-Aryl-3-hydroxyisoindolin-1-ones

(2013) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza-Dihydrodibenzoxepines

(2013) Adam A. Friedman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric synthesis of gem-diaryl substituted cyclic sulfamidates and sulfamides by rhodium-catalyzed arylation of cyclic ketimines

(2013) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Iridium-Catalyzed [3 + 2] Annulation of Cyclic N-Sulfonyl Ketimines with 1,3-Dienes via C–H Activation

(2013) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Cross-Dimerization between Methyl Methacrylate and Substituted Alkene by Ru(0)–Bicyclononadiene Complex

(2013) Yuki Hiroi et al.   ORGANIC LETTERS

Gold Meets Rhodium: Tandem One-Pot Synthesis of β-Disubstituted Ketones via Meyer–Schuster Rearrangement and Asymmetric 1,4-Addition

(2013) Max M. Hansmann et al.   ORGANIC LETTERS

Enantioselective Rh-Catalyzed Domino Transformations of Alkynylcyclohexadienones with Organoboron Reagents

(2013) Juliane Keilitz et al.   ORGANIC LETTERS

Simple Oxazolidine Chiral Diene Ligands for Enantioselective Rh-Catalyzed Conjugate Additions

(2013) David Carbery et al.   SYNLETT

Enantioselective Rhodium-Catalyzed Allylation of Cyclic Imines with Potassium Allyltrifluoroborates

(2013) Hon Lam et al.   SYNTHESIS-STUTTGART

Rhodium-Catalyzed Asymmetric Amination of Allylic Trichloroacetimidates

(2013) Hien Nguyen et al.   SYNTHESIS-STUTTGART

Cooperativity between steric repulsion and crossed diene coordination governs the enantioselectivity in rhodium(i)/chiral, 1,4- and 1,5-diene-catalysed 1,4-addition reaction: a DFT study

(2013) Eric Assen B. Kantchev   Chemical Science

Enantioselective [3 + 2] annulation via C–H activation between cyclic N-acyl ketimines and 1,3-dienes catalyzed by iridium/chiral diene complexes

(2013) Takahiro Nishimura et al.   Chemical Science

Enantioselective Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents

(2012) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic Imines

(2012) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium and copper-catalyzed asymmetric conjugate addition of alkenyl nucleophiles

(2012) Daniel Müller et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed regio- and enantioselective amination of racemic secondary allylic trichloroacetimidates with N-methyl anilines

(2012) Jeffrey S. Arnold et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Alkenylation of Cyclic α,β-Unsaturated Carbonyl Compounds as Catalyzed by a Rhodium-Diene Complex: Application to the Synthesis of (S)-Pregabalin and (−)-α-Kainic Acid

(2012) Hong-Jie Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Design and Synthesis of Polymeric Chiral Bicyclo[3.3.0] Diene as Reusable Ligand for Rhodium-Catalyzed Asymmetric 1,4-Addition

(2012) Hongyu Yang et al.   CHINESE JOURNAL OF CHEMISTRY

Expanding the C1-Symmetric Bicyclo[2.2.1]heptadiene Ligand Family: Highly Enantioselective Synthesis of Cyclic β-Aryl-Substituted Carbonyl Compounds

(2012) Chia-Chen Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

C1-Symmetric Bicyclo[2.2.2]octa-2,5-diene (bod*) Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Enones and 1,2-Addition toN-[(4-Nitrophenyl)sulfonyl]imines

(2012) Rebecca Brönnimann et al.   HELVETICA CHIMICA ACTA

Scalable Synthesis of Enantiomerically Pure Bicyclo[2.2.2]octadiene Ligands

(2012) Stefan Abele et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Tertiary Allylic Trichloroacetimidates with Anilines

(2012) Jeffrey S. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polymer-Incarcerated Chiral Rh/Ag Nanoparticles for Asymmetric 1,4-Addition Reactions of Arylboronic Acids to Enones: Remarkable Effects of Bimetallic Structure on Activity and Metal Leaching

(2012) Tomohiro Yasukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Chiral Diene Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to α,β-Unsaturated Sulfonyl Compounds

(2012) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of (Triaryl)methylamines by Rhodium-Catalyzed Addition of Arylboroxines to Cyclic N-Sulfonyl Ketimines

(2012) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Chiral 3-Arylpyrrolidines via the Enantioselective 1,4-Addition of Arylboronic Acids to Fumaric Esters Catalyzed by Rh(I)/Chiral Diene Complexes

(2012) Yu-Chiang et al.   ORGANIC LETTERS

Rhodium(I)/Diene-Catalyzed Addition Reactions of Arylborons with Ketones

(2012) Yuan-Xi Liao et al.   ORGANIC LETTERS

Mechanistic Investigations of a Palladium-Diene Catalyzed Suzuki–Miyaura Cross-Coupling Reaction

(2012) Xiaoshuang He et al.   ORGANOMETALLICS

Rhodium/diene-catalyzed asymmetric arylation of N-Boc-protected α,β-unsaturated δ-lactam with arylboronic acids: enantioselective synthesis of 4-aryl-2-piperidinones

(2012) Zhi-Tao He et al.   TETRAHEDRON

Easily accessible chiral dicyclopentadiene ligands for rhodium-catalyzed enantioselective 1,4-addition reactions

(2012) Cheng Shao et al.   TETRAHEDRON LETTERS

Application of chiral tetrahydropentalene ligands in rhodium-catalyzed 1,4-addition of (E)-2-phenylethenyl- and (Z)-propenylboronic acids to enones

(2012) Sarah Helbig et al.   TETRAHEDRON LETTERS

Rhodium/chiral diene-catalyzed asymmetric methylation of N-sulfonylarylimines with trimethylboroxine

(2012) Takahiro Nishimura et al.   TETRAHEDRON-ASYMMETRY

Asymmetric conjugate addition of cis-2-arylethenylboronic acids catalyzed by chiral diene/rhodium complexes: 1,4-rhodium shift from alkenylrhodium to arylrhodium intermediates

(2012) Keigo Sasaki et al.   TETRAHEDRON-ASYMMETRY

Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis

(2012) Keigo Sasaki et al.   Chemical Science

Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis

(2012) Xiangqing Feng et al.   Asian Journal of Organic Chemistry

Bis-Sulfamyl Imines: Potent Substrates for Asymmetric Additions of Arylboroxines under Rhodium Catalysis

(2011) Rosemary Crampton et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-catalyzed asymmetric addition of arylboroxines to β-alkoxyacrylate esters

(2011) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

The origin of regio- and enantioselectivity in the Rh/chiral 1,4-diene-catalyzed addition of phenylboronic acid to enones: insights from DFT

(2011) Eric Assen B. Kantchev   CHEMICAL COMMUNICATIONS

Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones

(2011) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

The Origins of Enantioselectivity in Rh-Diene Complex Catalysed Arylation of Cyclohex-2-enones

(2011) Silvia Gosiewska et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions of Arylboronic Acids to Acyclic α,β-Unsaturated Compounds: The Formal Synthesis of (−)-Indatraline

(2011) Wei-Ting Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Arylation ofN-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes

(2011) Zhe Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis-Based and Protecting-Group-Free Total Syntheses of the Marine Oxylipins Hybridalactone and the Ecklonialactones A, B, and C

(2011) Volker Hickmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed enantioselective synthesis of 4-arylchroman-2-ones

(2011) Joseph C. Allen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Readily Accessible Chiral Diene Ligands for Rh-Catalyzed Enantioselective Conjugate Additions of Boronic Acids

(2011) Barry M. Trost et al.   ORGANIC LETTERS

Chiral Diene-Phosphine Tridentate Ligands for Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes

(2011) Takahiro Nishimura et al.   ORGANIC LETTERS

α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselective Conjugated Additions

(2011) Qian Li et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Addition of Potassium Organotrifluoroborates toN-Sulfonyl Ketimines

(2011) Ryo Shintani et al.   ORGANIC LETTERS

Asymmetric Synthesis of β-Substituted γ-Lactams via Rhodium/Diene-Catalyzed 1,4-Additions: Application to the Synthesis of (R)-Baclofen and (R)-Rolipram

(2011) Cheng Shao et al.   ORGANIC LETTERS

Rhodium/Chiral Diene-Catalyzed Asymmetric Cyclopolymerization of Achiral 1,8-Diynes

(2011) Yoshitaka Ichikawa et al.   ORGANOMETALLICS

Development of Bicyclo[3.3.0]octadiene- or Dicyclopentadiene-Based Chiral Diene Ligands for Transition-Metal-Catalyzed Reactions

(2011) Guo-Qiang Lin et al.   SYNLETT

Enantioselective rhodium-catalyzed arylation of electron-deficient alkenylarenes

(2011) Aakarsh Saxena et al.   Chemical Science

One Step Synthesis of Chiral OlefinsviaAsymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions

(2010) Xichao Hu et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene-Rhodium Complexes

(2010) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoenzymatic Synthesis and Application of Bicyclo[2.2.2]octadiene Ligands: Increased Efficiency in Rhodium-Catalyzed Asymmetric Conjugate Additions by Electronic Tuning

(2010) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium-Catalyzed Asymmetric Cycloisomerization of Oxygen- and Nitrogen-Bridged 1,6-Enynes

(2010) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands

(2010) Zhi-Qian Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes

(2010) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to β,β-Disubstituted α,β-Unsaturated Ketones

(2010) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium/diene-catalyzed asymmetric arylation of N-sulfonyl indolylimines: a new access to highly optically active α-aryl 3-indolyl-methanamines

(2010) Hong-Yu Yang et al.   CHEMICAL COMMUNICATIONS

A Practical Chemo-enzymatic Synthesis of Homochiral Bicyclo[2.2.2]octane-2,5-dione

(2010) Yunfei Luo et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Asymmetric Arylation ofN-Tosyl Ketimines

(2010) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to α,β,γ,δ-Unsaturated Carbonyl Compounds

(2010) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes

(2010) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

(2010) Graham Pattison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation ofN,N-Dimethylsulfamoyl-Protected Aldimines

(2010) Ziping Cao et al.   ORGANIC LETTERS

Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki−Miyaura Coupling Reaction

(2010) Shu-Sheng Zhang et al.   ORGANIC LETTERS

C1-Symmetric Dicyclopentadienes as New Chiral Diene Ligands for Asymmetric Rhodium-Catalyzed Arylation ofN-Tosylarylimines

(2010) Cheng Shao et al.   ORGANIC LETTERS

Vicinal-Diamine-Based Chiral Chain Dienes as Ligands for Rhodium(I)-Catalyzed Highly Enantioselective Conjugated Additions

(2010) Yazhou Wang et al.   ORGANIC LETTERS

Synthesis of the Indolizino[7,6-c]quinoline Alkaloid Isaindigotidione

(2010) Malik Hellal et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Arylation of Azomethine Imines

(2010) Ryo Shintani et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to β,β-Disubstituted α,β-Unsaturated Esters

(2010) Ryo Shintani et al.   ORGANIC LETTERS

Exploring Rhodium-Catalysed Conjugate Addition of Chiral Alkenylboronates Using Chiral Olefin Ligands

(2010) Christopher Frost et al.   SYNTHESIS-STUTTGART

Novel Olefin-Phosphorus Hybrid and Diene Ligands Derived from Carbohydrates

(2010) Mike Boysen et al.   SYNTHESIS-STUTTGART

Allylic Amination by a DNA-Diene-Iridium(I) Hybrid Catalyst

(2009) Pierre Fournier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

(2009) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

(2009) Kazuhiro Okamoto et al.   CHEMICAL COMMUNICATIONS

Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to β,β-Disubstituted α,β-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters

(2009) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthaliminoacrylate Esters toward the Synthesis of β-Amino Acids

(2009) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Chiral Chain Dienes as Ligands for Rh(I)-Catalyzed Conjugated Additions

(2009) Xichao Hu et al.   ORGANIC LETTERS

Rhodium-Catalyzed 1,4-Additions to Enantiopure Acceptors: Asymmetric Synthesis of Functionalized Pyrrolizidinones

(2009) Ludivine Zoute et al.   ORGANIC LETTERS

Room-Temperature Rhodium-Catalyzed Asymmetric 1,4-Addition of Potassium Trifluoro(organo)borates

(2009) Thomas Gendrineau et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones with Alkynylsilanols

(2009) Takahiro Nishimura et al.   ORGANIC LETTERS

Asymmetric Addition of Alkenylstannanes to Alkylidene Meldrum’s Acids

(2009) Stuart J. Mahoney et al.   ORGANIC LETTERS

Rhodium-Catalyzed Functionalization of Sterically Hindered Alkenes

(2009) Thomas Gendrineau et al.   ORGANIC LETTERS

Catalytic Enantioselective Formation of Chiral-Bridged Dienes Which Are Themselves Ligands for Enantioselective Catalysis

(2009) M. Kevin Brown et al.   ORGANIC LETTERS

Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with aC2-Symmetric Tetrafluorobenzobarrelene Ligand

(2009) Takahiro Nishimura et al.   ORGANOMETALLICS

C1-Symmetric Monosubstituted Chiral Diene Ligands in Asymmetric Rhodium-Catalyzed 1,4-Addition Reactions

(2008) Thomas Gendrineau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Axial chirality control of tropos BIPHEP–Rh complexes by chiral dienes: synergy effect in catalytic asymmetric hydrogenation

(2008) Kohsuke Aikawa et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines

(2008) Yoshiaki Nakao et al.   CHEMISTRY LETTERS

Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids

(2008) Takahiro Nishimura et al.   CHEMISTRY LETTERS

Easily AccessibleC2-Symmetric Chiral Bicyclo[3.3.0] Dienes as Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition

(2008) Chen-Guo Feng et al.   Chemistry-An Asian Journal

Tuning the Chiral Environment ofC2-Symmetric Diene Ligands: Development of 3,7-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes

(2008) Ryo Shintani et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation

(2008) Haifeng Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Practical Catalytic Asymmetric 1,4-Addition of Arylboronic Acids in Water Using New Hydrophilic Chiral Bicyclo[3.3.0] Diene Ligands

(2008) Chen-Guo Feng et al.   ORGANIC LETTERS

Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Arylmethylene Cyanoacetates

(2008) Sebastian Sörgel et al.   ORGANIC LETTERS

Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions

(2008) Kazuhiro Okamoto et al.   ORGANIC LETTERS

Synthesis and rhodium complexation of enantiomerically enriched bicyclo[3.3.1]nona-2,6-diene

(2008) Monika Mayr et al.   TETRAHEDRON-ASYMMETRY

C2-Symmetric tetrafluorobenzobarrelenes as highly efficient ligands for the iridium-catalyzed asymmetric annulation of 1,3-dienes with 2-formylphenylboron reagents

(2008) Takahiro Nishimura et al.   TETRAHEDRON-ASYMMETRY