Diastereo-, Enantio-, and Z-Selective α,δ-Difunctionalization of Electron-Deficient Dienes Initiated by Rh-Catalyzed Conjugate Addition

Synthesis of Proline Analogues via Rh-Catalyzed Asymmetric Conjugate Addition

(2021) Emma K. Edelstein et al.   ACS Catalysis

Enantioselective Radical Carbocyanation of 1,3-Dienes via Photocatalytic Generation of Allylcopper Complexes

(2021) Fu-Dong Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis-Acid-Promoted Ligand-Controlled Regiodivergent Cycloaddition of Pd-Oxyallyl with 1,3-Dienes: Reaction Development and Origins of Selectivities

(2021) Weiwei Chai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Regioselective Asymmetric Addition of 1,4-Pentadiene to Ketones

(2021) Feng Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multicatalytic Approach to One-Pot Stereoselective Synthesis of Secondary Benzylic Alcohols

(2021) Alessandra Casnati et al.   ORGANIC LETTERS

Highly Diastereo‐ and Enantioselective Syntheses of 3,6’‐Bisboryl‐anti‐1,2‐oxaborinan‐3‐enes: An Entry to Chiral Homoallylic Alcohols with A Stereodefined Trisubstituted Alkene

(2020) Jichao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C2-Symmetric Dinickel Catalysts for Enantioselective [4 + 1]-Cycloadditions

(2020) Michael J. Behlen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Racemic Vinylallenes in Catalytic Enantioselective Multicomponent Processes. Rapid Generation of Complexity through 1,6-Conjugate Additions

(2019) Amir H. Hoveyda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Transition-Metal Catalysis in the Formation and Functionalization of Metal Enolates

(2019) Denisa Vargová et al.   ACS Catalysis

Nucleophile-Dependent Z/E- and Regioselectivity in the Palladium-Catalyzed Asymmetric Allylic C–H Alkylation of 1,4-Dienes

(2019) Hua-Chen Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enantioenriched Vicinal Tertiary and Quaternary Carbon Stereogenic Centers Within an Acyclic Chain

(2019) Ilan Marek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Formic Acid Mediated Z -Selective Reductive Coupling of Dienes and Aldehydes

(2019) Christopher Cooze et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Functionalized Phenylalanine Derivatives via Rh-Catalyzed Conjugate Addition and Enantioselective Protonation Cascade

(2019) Jia-Hong Jian et al.   ORGANIC LETTERS

Rh(I)–Diene-Catalyzed Addition of (Hetero)aryl Functionality to 1,3-Dienylsulfonyl Fluorides Achieving Exclusive Regioselectivity and High Enantioselectivity: Generality and Mechanism

(2019) Balakrishna Moku et al.   ACS Catalysis

Rhodium-Catalyzed Tandem Isomerization–Allylation: From Diallyl Carbonates to α-Quaternary Aldehydes

(2019) Jeanne Masson-Makdissi et al.   ACS Catalysis

Remote Nucleophilic Allylation by Allylrhodium Chain Walking

(2018) Alistair Groves et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective 1,2-Difunctionalization of 1,3-Butadiene by Sequential Alkylation and Carbonyl Allylation

(2018) Yang Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Regio- and Enantioselective Alkylation of Conjugated Dienyl Amides

(2018) Yafei Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Metal-Catalyzed Asymmetric 1,4-Conjugate Addition (ACA) of Nonorganometallic Nucleophiles

(2018) Ke Zheng et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Enantioselective Isomerization of Secondary Allylic Alcohols

(2017) Tang-Lin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of Styrenes and 1,3-Dienes with CO2

(2017) Yong-Yuan Gui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of a Kilogram-Scale Process for the Enantioselective Synthesis of 3-Isopropenyl-cyclohexan-1-one via Rh/DTBM-SEGPHOS-Catalyzed Asymmetric Hayashi Addition Enabled by 1,3-Diol Additives

(2017) Eric M. Simmons et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Variable Time Normalization Analysis: General Graphical Elucidation of Reaction Orders from Concentration Profiles

(2016) Jordi Burés   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes

(2016) Zhong-Lin Tao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Asymmetric Michael Addition in Natural Product Synthesis

(2016) Chunngai Hui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups

(2016) Fanke Meng et al.   NATURE

Asymmetric Transformations under Iridium/Chiral Diene Catalysis

(2016) Midori Nagamoto et al.   ACS Catalysis

Chain Walking of Allylrhodium Species Towards Esters During Rhodium-Catalyzed Nucleophilic Allylations of Imines

(2015) Jose I. Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereocontrolled Formation of Several Carbon–Carbon Bonds in Acyclic Systems

(2015) Guillaume Eppe et al.   CHEMICAL REVIEWS

Enantioselective 1,2-Difunctionalization of Dienes Enabled by Chiral Palladium Complex-Catalyzed Cascade Arylation/Allylic Alkylation Reaction

(2015) Xiang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines

(2014) Hamish B. Hepburn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins

(2013) Matthieu Tissot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition

(2013) Magaly Magrez-Chiquet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Asymmetric 1,6-Addition of (Triisopropylsilyl)-acetylene to α,β,γ,δ-Unsaturated Carbonyl Compounds

(2012) Takahiro Sawano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric and Diastereoselective Conjugate Addition Reactions: C–C Bond Formation at Large Scale

(2012) Gareth P. Howell   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Nickel-Catalyzed Enantio- and Diastereoselective Three-Component Coupling of 1,3-Dienes, Aldehydes, and a Silylborane Leading to α-Chiral Allylsilanes

(2011) Nozomi Saito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones

(2011) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Highly Diastereo- and Enantioselective Tandem Reaction toward Functionalized Pyrrolidines with Multiple Stereocenters

(2011) Shengmei Guo et al.   ORGANIC LETTERS

Diastereo- and Enantioselective Catalytic Tandem Michael Addition/Mannich Reaction: Access to Chiral Isoindolinones and Azetidines with Multiple Stereocenters

(2010) Shengmei Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugate addition reactions of carbon nucleophiles to electron-deficient dienes

(2010) Aurelio G. Csákÿ et al.   CHEMICAL SOCIETY REVIEWS

Synthetic applications of rhodium catalysed conjugate addition

(2010) Hannah J. Edwards et al.   CHEMICAL SOCIETY REVIEWS

Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to α,β,γ,δ-Unsaturated Carbonyl Compounds

(2010) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

(2009) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Recent advances in enantioselective copper-catalyzed 1,4-addition

(2009) Thomas Jerphagnon et al.   CHEMICAL SOCIETY REVIEWS

Iron-Catalyst-Switched Selective Conjugate Addition of Grignard Reagents: α,β,γ,δ-Unsaturated Amides as Versatile Templates for Asymmetric Three-Component Coupling Processes

(2008) Satoshi Okada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective 1,6-Conjugate Addition of Grignard Reagents to Linear Dienoates

(2007) Tim den Hartog et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION