Synthesis of Rhodium Complexes with Chiral Diene Ligands via Diastereoselective Coordination and Their Application in the Asymmetric Insertion of Diazo Compounds into E−H Bonds

Catalytic Asymmetric Carbene Insertion Reactions into B−H Bonds Using a Ru(II)‐Pheox Complex

(2021) Nansalmaa Otog et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Ring-Closing C–H Amination of Urea Derivatives

(2020) Zijun Zhou et al.   Chem

Highly Enantioselective Synthesis of Monofluoroalkenes by Rhodium-Catalyzed Asymmetric Arylation/Defluorination of Allyl Difluorides

(2020) Yuhang Pan et al.   ORGANIC LETTERS

Chiral Rhodium Nanoparticle-Catalyzed Asymmetric Arylation Reactions

(2020) Tomohiro Yasukawa et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Allylic Amination of Morita–Baylis–Hillman Adducts with Simple Aromatic Amines by Nucleophilic Amine Catalysis

(2019) Xin Chen et al.   SYNLETT

Strategies for the Synthesis of Chiral Carbon‐Bridged Group IV ansa‐Metallocenes

(2019) Michael Andreas Bau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent advances of achiral and chiral diene ligands in transition-metal catalyses

(2019) Masafumi Hirano et al.   TETRAHEDRON LETTERS

Towards the online computer-aided design of catalytic pockets

(2019) Laura Falivene et al.   Nature Chemistry

Preparation of chiral-at-metal catalysts and their use in asymmetric photoredox chemistry

(2018) Jiajia Ma et al.   Nature Protocols

Chiral proton-transfer shuttle catalysts for carbene insertion reactions

(2018) Yuan-Yuan Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed B–H Bond Insertion Reactions of Unstabilized Diazo Compounds Generated in Situ from Tosylhydrazones

(2018) Yue Pang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Genetically programmed chiral organoborane synthesis

(2017) S. B. Jennifer Kan et al.   NATURE

Recent progress in the catalytic carbene insertion reactions into the silicon–hydrogen bond

(2017) Hoda Keipour et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Insertion into Heteroatom-Hydrogen Bonds with Trifluorodiazoalkanes

(2016) Stephen Hyde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Arylation/Defluorination of 1-(Trifluoromethyl)alkenes Forming Enantioenriched 1,1-Difluoroalkenes

(2016) Yinhua Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis

(2016) Christophe Werlé et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

(2016) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-catalyzed asymmetric 1,4-addition reactions to α,β-unsaturated carbonyl and related compounds: an update

(2016) Majid M. Heravi et al.   TETRAHEDRON-ASYMMETRY

Enantioselective 1,4-addition of cyclopropylboronic acid catalyzed by rhodium/chiral diene complexes

(2015) Ryosuke Takechi et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Asymmetric Arylation of Allyl Sulfones under the Conditions of Isomerization into Alkenyl Sulfones

(2015) Kelvin Meng-Hui Lim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes

(2015) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines

(2015) Yinhua Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral-Auxiliary-Mediated Asymmetric Synthesis of Ruthenium Polypyridyl Complexes

(2013) Lei Gong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Insertion of Reactive Rhodium Carbenes into Boron–Hydrogen Bonds of Stable N-Heterocyclic Carbene Boranes

(2013) Xiben Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts

(2013) Qing-Qing Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assessing the Accuracy of M06-L Organometallic Thermochemistry

(2013) Dmitry G. Gusev   ORGANOMETALLICS

Scalable Synthesis of Enantiomerically Pure Bicyclo[2.2.2]octadiene Ligands

(2012) Stefan Abele et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids

(2011) Bin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic tuning of chiral diene ligands in iridium-catalyzed asymmetric 1,6-addition of arylboroxines to δ-aryl-α,β,γ,δ-unsaturated ketones

(2011) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Synthesis of Octahedral Coordination Complexes

(2011) Eric Meggers   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reactions of Alkynes with [RuCl(cyclopentadienyl)] Complexes: The Important First Steps

(2010) Barnali Dutta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes

(2010) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The concise synthesis of chiral tfb ligands and their application to the rhodium-catalyzed asymmetric arylation of aldehydes

(2009) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Chiral Auxiliaries as Emerging Tools for the Asymmetric Synthesis of Octahedral Metal Complexes

(2009) Eric Meggers   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Polymerization of Achiral Arylacetylenes Giving Helical Polyacetylenes in the Presence of a Rhodium Catalyst with aC2-Symmetric Tetrafluorobenzobarrelene Ligand

(2009) Takahiro Nishimura et al.   ORGANOMETALLICS

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

(2008) Tharmalingam Punniyamurthy et al.   CHEMICAL COMMUNICATIONS

Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids

(2008) Takahiro Nishimura et al.   CHEMISTRY LETTERS

Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions

(2008) Kazuhiro Okamoto et al.   ORGANIC LETTERS

Synthesis and rhodium complexation of enantiomerically enriched bicyclo[3.3.1]nona-2,6-diene

(2008) Monika Mayr et al.   TETRAHEDRON-ASYMMETRY