The Origins of Enantioselectivity in Rh-Diene Complex Catalysed Arylation of Cyclohex-2-enones

The origin of regio- and enantioselectivity in the Rh/chiral 1,4-diene-catalyzed addition of phenylboronic acid to enones: insights from DFT

(2011) Eric Assen B. Kantchev   CHEMICAL COMMUNICATIONS

Mechanism of the Palladium-Catalyzed Addition of Arylboronic Acids to Enones: A Computational Study

(2011) Yu Lan et al.   JOURNAL OF ORGANIC CHEMISTRY

α,β-Divinyl Tetrahydropyrroles as Chiral Chain Diene Ligands in Rhodium(I)-Catalyzed Enantioselective Conjugated Additions

(2011) Qian Li et al.   ORGANIC LETTERS

One Step Synthesis of Chiral OlefinsviaAsymmetric Diamination and their Applications as Ligands for Rhodium(I)-Catalyzed 1,4-Additions

(2010) Xichao Hu et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemoenzymatic Synthesis and Application of Bicyclo[2.2.2]octadiene Ligands: Increased Efficiency in Rhodium-Catalyzed Asymmetric Conjugate Additions by Electronic Tuning

(2010) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands

(2010) Zhi-Qian Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes

(2010) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to β,β-Disubstituted α,β-Unsaturated Ketones

(2010) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic applications of rhodium catalysed conjugate addition

(2010) Hannah J. Edwards et al.   CHEMICAL SOCIETY REVIEWS

Cobalt-Mediated, Enantioselective Synthesis ofC2andC1Dienes

(2010) W. Christopher Boyd et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes

(2010) Graham Pattison et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation ofN,N-Dimethylsulfamoyl-Protected Aldimines

(2010) Ziping Cao et al.   ORGANIC LETTERS

Neutralcis-Alkyl Olefin Rhodium(I) Complexes: Models of Intermediates in Late Transition Metal Olefin Polymerization with Surprising Structure†

(2010) Heiko Urtel et al.   ORGANOMETALLICS

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

(2009) Kazuhiro Okamoto et al.   CHEMICAL COMMUNICATIONS

Asymmetric Epoxidation Catalyzed by α,α-Dimethylmorpholinone Ketone. Methyl Group Effect on Spiro and Planar Transition States

(2009) O. Andrea Wong et al.   JOURNAL OF ORGANIC CHEMISTRY

Simple Chiral Chain Dienes as Ligands for Rh(I)-Catalyzed Conjugated Additions

(2009) Xichao Hu et al.   ORGANIC LETTERS

Catalytic Enantioselective Formation of Chiral-Bridged Dienes Which Are Themselves Ligands for Enantioselective Catalysis

(2009) M. Kevin Brown et al.   ORGANIC LETTERS

Chiral Olefins as Steering Ligands in Asymmetric Catalysis

(2008) Christian Defieber et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation

(2008) Tharmalingam Punniyamurthy et al.   CHEMICAL COMMUNICATIONS

Easily AccessibleC2-Symmetric Chiral Bicyclo[3.3.0] Dienes as Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition

(2008) Chen-Guo Feng et al.   Chemistry-An Asian Journal

Tuning the Chiral Environment ofC2-Symmetric Diene Ligands: Development of 3,7-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes

(2008) Ryo Shintani et al.   JOURNAL OF ORGANIC CHEMISTRY

Access to Enantioenriched α-Amino Esters via Rhodium-Catalyzed 1,4-Addition/Enantioselective Protonation

(2008) Laure Navarre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions

(2008) Kazuhiro Okamoto et al.   ORGANIC LETTERS

Synthesis and rhodium complexation of enantiomerically enriched bicyclo[3.3.1]nona-2,6-diene

(2008) Monika Mayr et al.   TETRAHEDRON-ASYMMETRY