Aroyl Fluorides as Bifunctional Reagents for Dearomatizing Fluoroaroylation of Benzofurans

Introduction: Photochemical Catalytic Processes

(2022) Paolo Melchiorre   CHEMICAL REVIEWS

Recent Dearomatization Strategies of Benzofurans and Benzothiophenes

(2021) Beeraiah Baire et al.   Asian Journal of Organic Chemistry

Acridinium Salts and Cyanoarenes as Powerful Photocatalysts: Opportunities in Organic Synthesis

(2021) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis

(2021) Kun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzylic C−H acylation by cooperative NHC and photoredox catalysis

(2021) Qing-Yuan Meng et al.   Nature Communications

Bifunctional reagents in organic synthesis

(2021) Huan-Ming Huang et al.   Nature Reviews Chemistry

Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis

(2021) Spencer P. Pitre et al.   CHEMICAL REVIEWS

Synthesis of N-CF3 Alkynamides and Derivatives Enabled by Ni-Catalyzed Alkynylation of N-CF3 Carbamoyl Fluorides

(2021) Christian D.-T. Nielsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Photoredox and Carbene Catalysis for the Synthesis of γ‐Aryloxy Ketones

(2021) Pengzhi Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Cooperative NHC/Photoredox Catalyzed Ring‐Opening of Aryl Cyclopropanes to 1‐Aroyloxylated‐3‐Acylated Alkanes

(2021) Zhijun Zuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The advent and development of organophotoredox catalysis

(2021) Tommaso Bortolato et al.   CHEMICAL COMMUNICATIONS

Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis

(2021) Amy Y. Chan et al.   CHEMICAL REVIEWS

Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis

(2021) Philip R. D. Murray et al.   CHEMICAL REVIEWS

Photocatalysis in the Life Science Industry

(2021) Lisa Candish et al.   CHEMICAL REVIEWS

Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis

(2021) Nicholas E. S. Tay et al.   CHEMICAL REVIEWS

Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids

(2020) Karl Scheidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Cyclobutane-Fused Tetracyclic Scaffolds via Visible-Light Photocatalysis for Building Molecular Complexity

(2020) Martins S. Oderinde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzoyl Fluorides as Fluorination Reagents: Reconstruction of Acyl Fluorides via Reversible Acyl C–F Bond Cleavage/Formation in Palladium Catalysis

(2020) Yohei Ogiwara et al.   ORGANOMETALLICS

Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis

(2020) Xiao-Ye Yu et al.   CHEMICAL REVIEWS

Recent Advances in Synthetic Strategies to 2,3-Dihydrobenzofurans

(2020) Paolo Lupattelli et al.   SYNTHESIS-STUTTGART

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

(2020) Qing-Yuan Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Dearomatization of Naphthalene Derivatives by Photoredox‐Catalyzed 1,2‐Hydroalkylation

(2020) Yuan‐Zheng Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single Electron Transfer Reactions Enabled by N‐Heterocyclic Carbene Organocatalysis

(2020) Qing-Zhu Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphine-Catalyzed Intermolecular Acylfluorination of Alkynes via a P(V) Intermediate

(2020) Hayato Fujimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

19F- and 18F-arene deoxyfluorination via organic photoredox-catalysed polarity-reversed nucleophilic aromatic substitution

(2020) Nicholas E. S. Tay et al.   Nature Catalysis

Photoredox-Catalyzed Intermolecular Hydroalkylative Dearomatization of Electron-Deficient Indole Derivatives

(2020) Xu-Lun Huang et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox‐Neutral Decarbonylative Cross‐Couplings Coming of Age

(2019) Qun Zhao et al.   ChemSusChem

Acyl Fluorides in Late Transition-Metal Catalysis

(2019) Yohei Ogiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biocatalytic strategy for highly diastereo- and enantioselective synthesis of 2,3-dihydrobenzofuran based tricyclic scaffolds

(2019) Rudi Fasan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acid Fluorides in Transition-Metal Catalysis: A Good Balance between Stability and Reactivity

(2019) Nicolas Blanchard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Persistent Radical Effect in Organic Synthesis

(2019) Dirk Leifert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Annulation Reactions of Carbenes with 2-Iminyl- or 2-Acyl-Substituted Phenols: Convenient Access to Enantioenriched 2,3-Dihydrobenzofurans

(2019) Xin-Shen Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct arene C–H fluorination with 18F− via organic photoredox catalysis

(2019) Wei Chen et al.   SCIENCE

Combined Photoredox/Enzymatic C−H Benzylic Hydroxylations

(2019) Rick C. Betori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective Alkoxylation of Benzylic C−H Bonds by Photoredox Catalysis

(2019) Byung Joo Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Dearomatization of Indole Derivatives with N-Hydroxycarbamates Enabled by Photoredox Catalysis

(2019) Yuan-Zheng Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Driven N-Heterocyclic Carbene Catalyzed γ- and ϵ -Alkylation with Alkyl Radicals

(2019) Lei Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Late-stage trifluoromethylthiolation of benzylic C-H bonds

(2019) Wentao Xu et al.   Nature Communications

Palladium-Catalyzed Enantioselective Reductive Heck Reactions: Convenient Access to 3,3-Disubstituted 2,3-Dihydrobenzofuran

(2018) Zhan-Ming Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides

(2018) Sinead T. Keaveney et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Promoted Intermolecular Oxidative Dearomatization of β-Naphthols with N-Hydroxycarbamates

(2018) Shuli You et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic asymmetric brominative dearomatization reaction of benzofurans

(2018) Xiao-Wei Liang et al.   CHINESE CHEMICAL LETTERS

Chemoselective Peptide Modification via Photocatalytic Tryptophan β-Position Conjugation

(2018) Younong Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhancing the potential of enantioselective organocatalysis with light

(2018) Mattia Silvi et al.   NATURE

Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides

(2018) Christian A. Malapit et al.   NATURE

Phosphoric Acid Catalyzed [4 + 1]-Cycloannulation Reaction of ortho-Quinone Methides and Diazoketones: Catalytic, Enantioselective Access toward cis-2,3-Dihydrobenzofurans

(2018) Arun Suneja et al.   ORGANIC LETTERS

Dearomatizing Radical Cyclizations and Cyclization Cascades Triggered by Electron-Transfer Reduction of Amide-Type Carbonyls

(2017) Huan-Ming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C–H Cyanation of Arenes via Organic Photoredox Catalysis

(2017) Joshua B. McManus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cation Radical Accelerated Nucleophilic Aromatic Substitution via Organic Photoredox Catalysis

(2017) Nicholas E. S. Tay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

External oxidant-free electrooxidative [3 + 2] annulation between phenol and indole derivatives

(2017) Kun Liu et al.   Nature Communications

Diversity-Oriented Synthesis of Libraries Based on Benzofuran and 2,3-Dihydrobenzofuran Scaffolds

(2017) Liena Qin et al.   ACS Combinatorial Science

Palladium-Catalyzed Highly Stereoselective Dearomative [3 + 2] Cycloaddition of Nitrobenzofurans

(2017) Qiang Cheng et al.   Chem

Synthetic Applications of Proton-Coupled Electron Transfer

(2016) Emily C. Gentry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

(2016) Takashi Koike et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Asymmetric Chlorinative Dearomatization Reaction of Benzofurans

(2016) Xiao-Wei Liang et al.   ADVANCED SYNTHESIS & CATALYSIS

N-Heterocyclic Carbene Catalyzed γ-Dihalomethylenation of Enals by Single-Electron Transfer

(2016) Wen Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Dearomatization through Halofunctionalization Reactions

(2016) Xiao-Wei Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Synthesis of Chiral Dihydrobenzofurans through a Formal [4+1] Annulation Reaction of Sulfur Ylides and In Situ Generatedortho-Quinone Methides

(2016) Qing-Qing Yang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

(2016) Wen Zhang et al.   SCIENCE

Biological and medicinal significance of benzofuran

(2015) Reshma J. Nevagi et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Fluorination of 2-substituted benzo[b]furans with Selectfluor™

(2015) Mingliang Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Acyl Azolium Fluorides for Room Temperature Nucleophilic Aromatic Fluorination of Chloro- and Nitroarenes

(2015) Sarah J. Ryan et al.   ORGANIC LETTERS

Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids

(2014) Cristian Soldi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Enantioselective fluoride ring opening of aziridines enabled by cooperative Lewis acid catalysis

(2013) Julia A. Kalow et al.   TETRAHEDRON

Ruthenium NHC Catalyzed Highly Asymmetric Hydrogenation of Benzofurans

(2012) Nuria Ortega et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric α-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis

(2012) Daniel A. DiRocco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of Cooperative Catalysis in the Enantioselective Fluorination of Epoxides

(2011) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis

(2011) James A. Birrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Ring Opening of Epoxides by Fluoride Anion Promoted by a Cooperative Dual-Catalyst System

(2010) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Formation ofN-Acyl-oxazolidinone Derivatives Using Acid Fluorides

(2010) Corinna S. Schindler et al.   ORGANIC LETTERS

2,3-Dihydro-1-Benzofuran Derivatives as a Series of Potent Selective Cannabinoid Receptor 2 Agonists: Design, Synthesis, and Binding Mode Prediction through Ligand-Steered Modeling

(2009) Philippe Diaz et al.   ChemMedChem

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS